RESUMEN
A novel one step route for the synthesis of tannic acid, lipoic acid and menthol functionalized polyvinyl chloride, PVC, (PVC-Tann, PVC-Lip, PVC-Mnt) and chlorinated polypropylene, PP-Cl, (PP-Mnt, PP-Lip) was applied imparting antioxidative properties to the newly-formed materials. The resulting modified polymers were characterized by stress-strain mechanical measurement, 1H NMR, gel permeation chromatography (GPC) and thermogravimetric (TGA) analysis. Linseed oil, owing to its high linolenic acid content, was used to track the autoxidation process. The chloride functional groups were reacted with the hydroxyl/carboxylic acid of the natural compounds in the presence of a base. Linseed oil was poured into the natural compound functionalized PVC covered Petri dish to undergo autoxidation under white light. Each of the PVC- and PP-Cl-based polymers was active in delaying autoxidation. The PP-Mnt series and PP-Lip polymers all delayed autoxidation by 8 days over the PP-Cl precursor material. The autoxidation process was further confirmed by monitoring peroxide formation in the exposed linseed oil samples through differential scanning calorimeter (DSC) analysis.
Asunto(s)
Ácido Tióctico , Cloruro de Vinilo , Cloruro de Polivinilo/química , Polipropilenos , Mentol , Taninos , Aceite de Linaza , Polímeros/químicaRESUMEN
This work focuses on the synthesis of novel tannin-functionalized polypropylene copolymers that are designed to inhibit the oxidation of vegetable oils for potential use as packaging materials. An empty glass Petri dish (control), a chlorinated polypropylene-coated glass Petri dish (control) and a series of the tannin-functionalized polypropylene coated glass Petri dishes overlaid with linseed oil were exposed to air and additional white light. Oligomerization of the oxidized linseed oil was assessed by measuring the flow properties of the exposed oil using a viscometer. The antioxidant effect of the tannic acid grafted polypropylene copolymers (PP-Tann) retarded oligomerization of the linseed oil. The molar mass of the linoleic acid overlaid onto the PP-Tann films was the lowest among the tested samples after each time period indicating that tannin-grafted polypropylene may be a promising packaging material for vegetable oils.
Asunto(s)
Antioxidantes/química , Embalaje de Alimentos , Polipropilenos/química , Polipropilenos/síntesis química , Taninos/química , Técnicas de Química Sintética , Oxidación-Reducción , Aceites de PlantasRESUMEN
Fatty acid esters were prepared by transesterification of soy oil with methanol (methyl-soyate, Me-Soy), ethanol (ethyl-soyate, Et-Soy) and propanol (propyl-soyate, Pro-Soy) and used with glycerol as fermentation substrates to enhance production of free-acid sophorolipids (SLs). Fed-batch fermentations of Candida bombicola resulted in SL yields of 46 +/- 4 g/l, 42 +/- 7 g/l and 18 +/- 6 g/l from Me-Soy, Et-Soy, and Pro-Soy, respectively. Liquid chromatography with atmospheric pressure ionization mass spectrometry (LC/API-MS) showed that Me-Soy resulted in 71% open-chain SLs with 59% of those molecules remaining esterified at the carboxyl end of the fatty acids. Et-Soy and Pro-Soy resulted in 43% and 80% open-chain free-acid SLs, respectively (containing linoleic acid and oleic acid as the principal fatty acid species linked to the sophorose sugar at the omega-1 position), with no evidence of residual esterification.