Environmental and health risk assessment of potentially toxic trace elements in soils near uranium (U) mines: A global meta-analysis.

Soil pollution by potentially toxic trace elements (PTEs) near uranium (U) mines arouses a growing interest worldwide. However, nearly all studies have focused on a single site or only a few sites, which may not fully represent the soil pollution status at the global scale. In this study, data of U, Cd, Cr, Pb, Cu, Zn, As, Mn, and Ni contents in U mine-associated soils were collected and screened from published articles (2006-2021). Assessments of pollution levels, distributions, ecological, and human health risks of the nine PTEs were analysed. The results revealed that the average contents of the U, Cd, Cr, Pb, Cu, Zn, As, Mn, and Ni were 39.88-, 55.33-, 0.88-, 3.81-, 3.12-, 3.07-, 9.26-, 1.83-, and 1.17-fold greater than those in the upper continental crust, respectively. The pollution assessment showed that most of the studied soils were heavily polluted by U and Cd. Among them, the U mine-associated soils in France, Portugal, and Bulgaria exhibited significantly higher pollution levels of U and Cd when compared to other regions. The average potential ecological risk value for all PTEs was 3358.83, which indicated the presence of remarkably high risks. Among the PTEs, Cd and U contributed more to the potential ecological risk than the other elements. The health risk assessment showed that oral ingestion was the main exposure route for soil PTEs; and the hazard index (HI) values for children were higher than those for adult males and females. For adult males and females, all hazard index values for the noncarcinogenic risks were below the safe level of 1.00. For children, none of the HI values exceeded the safe level, with the exception of U (HI = 3.56) and As (HI = 1.83), but Cu presented unacceptable carcinogenic risks. This study provides a comprehensive analysis that demonstrates the urgent necessity for treating PTE pollution in U mine-associated soils worldwide.

U(VI) adsorption by green and facilely modified Ficus microcarpa aerial roots: Behavior and mechanism investigation.

Uranium (U)-containing wastewater poses serious pressure to human health and environmental safety. The treatment of U-bearing wastewater using green and facilely fabricated materials is considered a promising alternative. Herein, the raw and modified aerial roots of Ficus microcarpa (RARF and MARF, respectively) were prepared and applied to the treatment of synthesized U-containing wastewater. The results showed that the adsorption process was spontaneous and chemically controlled, which was in good accordance with the pseudo-second-order kinetic and the Redlich-Peterson isotherm adsorption model. The adsorption mechanisms were proposed to be the complexation between U(VI) and oxygen/phosphorus-containing functional groups on MARF.

Emergent thallium exposure from uranium mill tailings.

Thallium (Tl) pollution caused by the exploitation of uranium (U) mines has long been neglected due to its low crustal abundance. However, Tl may be enriched in minerals of U ore because Tl has both sulfurophile and lithophile properties. Herein, a semi-dynamic leaching experiment combined with statistical analysis, geochemical speciation and multi-characterization provided novel insight into the distinct features and mechanisms of Tl release from uranium mill tailings (UMT). The results showed that particle size effects prevail over the pH on Tl release, and surface dissolution is the pivotal mechanism controlling Tl release based on Fick's diffusion model. The study revealed that long-term leaching and weathering can lead to the increased acid-extractable and oxidizable fractions of Tl in UMT, and that the exposure and dissolution of Tl-containing sulfides would largely enhance the flux of Tl release. The findings indicate that UMT containing (abundant) pyrite should be paid particular attention due to Tl exposure. Besides, critical concern over the potential Tl pollution in universal U mining and hydrometallurgical areas likewise may need to be seriously reconsidered.

Facile modification of graphene oxide and its application for the aqueous uranyl ion sequestration: Insights on the mechanism.

Graphene oxide (GO) has been proved with favorable affinity to U(VI), while some drawbacks such as poor dispersity and low adsorption performance limit its application. Herein, cetyltrimethylammonium bromide (CTAB) modified graphene oxide (MGO) composites were successfully fabricated, characterized and compared with graphene oxide (GO) in the sequestration of U(VI) in aqueous solutions. The results showed that maximum adsorption rate of MGO (99.21%) was obviously higher than that of GO (66.51%) under the same initial condition. Simultaneous introduction of C-H and NO coupled with the enhanced dispersity of GO after modification were mainly responsible for the updated performance verified with multiple characterization techniques. Based on the results of kinetics and isotherms investigations, the experimental data were best described by Pseudo-first-order kinetic model and Redlich-Peterson isotherm model. The results of ΔH, ΔS and ΔG show that adsorptive behaviors of uranyl ion on MGO are endothermic and spontaneous. The study provides a feasible alternative to the chemical modification of GO and enhancing the performance towards uranyl ion removal from solution.

Chelant-enhanced washing of CCA-contaminated soil: Coupled with selective dissolution or soil stabilization.

Remediation of CCA-contaminated soil (Cr, Cu, and As) by biodegradable chelant-enhanced washing (EDDS, S,S-ethylene-diamine-disuccinic-acid) needs further enhancement. This study investigated the effectiveness of coupling with pre-treatment by selective dissolution and post-treatment by soil amendments, respectively. Three groups of reagents (reductants, alkaline solvents, and organic ligands) were adopted in the pre-treatment to dissolve the oxide minerals before EDDS extraction. In the post-treatment, soil amendments (coal fly ash (CFA), acid mine drainage sludge (AMDS), green waste compost (GWC)), and their mixtures) were used for a 2-month stabilization after 2-h EDDS washing. Multi-endpoint evaluation was performed by assessing the chemical state, leachability, mobility, bioaccessibility, and plant-availability of residual metal(loid)s as well as the cytotoxicity, enzyme activities, and available nutrients of the treated soils. Pre-treatment by dithionite-citrate-bicarbonate significantly enhanced extraction efficiency, but also increased the leachability of As and Cr and bioaccessibility of Cr in the treated soils. While sodium hydroxide removed the majority of As without increasing its leachability and bioaccessibility, it increased the cytotoxicity and inhibited the acid phosphatase activity. Post-treatment with AMDS and CFA effectively controlled the mobility and leachability of residual As and Cr after EDDS washing. However, destabilized Cu was only marginally immobilized by GWC due to strong Cu-EDDS complexation. The bioaccessibility and phytoavailability of Cu was primarily reduced by EDDS washing, while those of As and Cr could be attenuated by AMDS and CFA. This study indicates that coupling chemical extraction with subsequent soil amendment plays complementary roles in mitigating effects of residual metal(loid)s and improving environmental quality.

Arsenic-containing soil from geogenic source in Hong Kong: Leaching characteristics and stabilization/solidification.

Geogenic sources of arsenic (As) have aroused extensive environmental concerns in many countries. This study evaluated the vertical profiles, leaching characteristics, and surface characteristics of As-containing soils in Hong Kong. The results indicated that elevated levels of As (486-1985 mg kg-1) were mostly encountered in deeper layer (15-20 m below ground). Despite high concentrations, geogenic As displayed a high degree of chemical stability in the natural geochemical conditions, and there was minimal leaching of As in various leaching tests representing leachability, mobility, phytoavailability, and bioaccessibility. Microscopic/spectroscopic investigations suggested that As in the soils was predominantly present as As(V) in a coordination environment with Fe oxides. Sequential extraction indicated that the majority of As were strongly bound with crystalline Fe/Al oxides and residual phase. Yet, uncertainties may remain with potential As exposure through accidental ingestion and abiotic/biotic transformation due to changes in geochemical conditions. Hence, the effectiveness of stabilization/solidification (S/S) treatment was evaluated. Although the leached concentrations of As from the S/S treated soils increased to varying extent in different batch leaching tests due to the increase in alkalinity, the mobility of As was considered very low based on semi-dynamic leaching test. This suggested that As immobilization in the S/S treated soils was predominantly dependent on physical encapsulation by interlocking framework of hydration products, which could also prevent potential exposure and allow controlled utilization of S/S treated soils as monolithic materials. These results illustrate the importance of holistic assessment and treatment/management of As-containing soils for enabling flexible future land use.