Transport and retention of nano emulsified vegetable oil in porous media: Effect of pore straining, roughness wedging, and interfacial effects.

Emulsified vegetable oil (EVO), as one of the novel green substrates, has been widely used in subsurface remediation. In these applications, the retention behavior of EVO presents a challenge to remediation efficiency as mechanism insights into the retention of EVO is limited. Herein, Brinell funnels experiments with X-ray microtomography (XMT) were conducted to examine the drainage and retention of nanoscale EVO in porous media, with a specific focus on investigating the impact of pore straining, grain surface roughness, and interfacial effects on Nano-EVO (NEVO) retention. This study demonstrated that the retention of NEVO in porous media is the synergistic result of pore straining, roughness wedging, and interface attachment. With the action of these effects, three residual states of NEVO, incorporating retention at porous ganglia, grain-grain contacts, and grain surface, were identified by XMT in porous media. After multiple periods of drainage and imbibition, the NEVO arrived at stable retention proportions of 46.3%, 72.2%, and 85.9% in three independent systems with coarse, medium, and fine sand as porous media, respectively. The interfacial effects, including the attachment of solid-phase and air-liquid interface, are confirmed as the dominant factors for the retention of NEVO in porous media, which contributed 35.63-47.33% of total retention for the conditions employed. Correspondingly, the contributions of pore straining and roughness wedging only ranged 3.78-24.06% and 3.87-9.94%, respectively. The consistency of the contributions between the actual measurement of XMT and computational evaluation further confirmed the rationality and reliability of the results. In such the dominant factor, interfacial tension, contact angle, and capillary radius play an essential role in NEVO retention, which could be reflected by capillary rise height. These findings advance our understanding on NEVO retention caused by substrate-media interaction and also offer a promising direction for subsurface remediation.

Pore-scale identification of residual morphology and genetic mechanisms of nano emulsified vegetable oil in porous media using 3D X-ray microtomography.

The application of emulsified vegetable oil (EVO) has attracted widespread attention in environmental remediation. Residual morphology is an important factor affecting its migration and mass transfer. However, proper identification of the EVO residual morphology at pore-scale has still remained a challenging task. Hence, this study aimed to identify the residual morphology of nanoscale EVO (NEVO) through developing a method combining natural breaks with 3D X-ray microtomography, then further explore the genetic mechanism of each residual morphology to verify the rationality of this method. The results showed that the natural breaks method can effectively classify the residual morphology of NEVO. Four morphologies including cluster, throat, corner, and membrane state were obtained from coarse, medium, and fine sands with a total proportion of 18.3%, 26.2%, and 30.8%. The cluster state was the main residual morphology, accounting for 10.0- 16.2%, then followed by corner-throat state and membrane state. Pore radius, throat radius, and length were confirmed providing sufficient evidences for cluster residues, because these factors determined the connectivity of porous media for the trapping of droplets. Comparison of the theoretical and actual results implied that capillarity coupling pore-throat shape jointly controlled corner and throat residues. Grain surface roughness and specific surface area were the main factors of membrane residue. The different residual morphologies of NEVO identified by the natural breaks method can reasonably explain their magnitude and controlling mechanisms, which in turn confirms the rationality of this method. Although the proportions of each form are related to the experimental conditions, the classification method and mechanism are of great significance for understanding NEVO residues.