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Talanta ; 85(1): 310-6, 2011 Jul 15.
Artículo en Inglés | MEDLINE | ID: mdl-21645704

RESUMEN

A disposable electrochemical sensor for the determination of indole-3-acetic acid (IAA) based on nanocomposites of reduced graphene oxide (rGO) and poly(safranine T) (PST) was reported. The sensor was prepared by coating a rGO film on a pre-anodized graphite electrode (AGE) through dipping-drying and electrodepositing a uniform PST layer on the rGO film. Scanning electron microscopic (SEM) and infrared spectroscopic (IR) characterizations indicated that PST-rGO formed a rough and crumpled composite film on AGE, which exhibited high sensitive response for the oxidation of IAA with 147-fold enhancement of the current signal compared with bare AGE. The voltammetric current has a good linear relationship with IAA concentration in the range 1.0×10(-7)-7.0×10(-6)M, with a low detection limit of 5.0×10(-8)M. This sensor has been applied to the determination of IAA in the extract samples of several plant leaves and the recoveries varied in the range of 97.71-103.43%.


Asunto(s)
Técnicas Electroquímicas/métodos , Ácidos Indolacéticos/análisis , Nanocompuestos/química , Extractos Vegetales/química , Reguladores del Crecimiento de las Plantas/análisis , Electrodos , Grafito , Límite de Detección , Óxidos , Fenazinas , Hojas de la Planta , Polímeros
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