Trends in research on characterization, treatment and valorization of hazardous red mud: A systematic review.

Meta-analysis of red mud-related literature in English published from 1976 to 2022 and in Chinese from 1990 to 2022 was performed to support critical analysis and evaluation of the available literature based on the following aspects of red mud research: (a) characterization, (b) treatment for harmfulness minimization, (c) recovery of valuable metals, (d) environmental applications, and (e) uses as construction materials. It was found that (a) sinter red mud tended to contain more silica and calcium, and less iron, sodium and aluminium compared to Bayer red mud; (b) gypsum was the most frequently used agent for harmfulness reduction treatment of red mud, followed by flue gas/CO2; (c) the mean optimal pH for adsorption of major anionic pollutants was 8.42 ± 1.13 (arsenite), 3.73 ± 0.68 (arsenate), 3.50 ± 2.38 (phosphate), 4.43 ± 1.04 (fluoride) and 3.80 ± 1.54 (chromate); (d) wastewater treatment has attracted more attention compared to contaminated soils and waste gases; (e) recovery of iron and scandium has attracted more attention compared to other metals; (f) cement making has been the focus in construction uses. Most of the research findings were based on laboratory-scale experiments that focused on efficacy rather than efficiency. There was a lack of integrated approaches for research in red mud valorization.

Industrial waste-based adsorbents as a new trend for removal of water-borne emerging contaminants.

Emerging contaminants in wastewater are one of the growing concerns because of their adverse effects on human health and ecosystems. Adsorption technology offers superior performance due to its cost-effectiveness, stability, recyclability, and reliability in maintaining environmental and health standards for toxic pollutants. Despite extensive research on the use of traditional adsorbents to remove emerging contaminants, their expensiveness, lack of selectivity, and complexity of regeneration remain some of the challenges. Industrial wastes viz. blast furnace slag, red mud, and copper slag can be used to develop efficacious adsorbents for the treatment of emerging contaminants in water. Advantages of the use of such industrial wastes include resource utilization, availability, cost-effectiveness, and waste management. Nevertheless, little is known so far about their application, removal efficacy, adsorption mechanisms, and limitations in the treatment of emerging contaminants. A holistic understanding of the application of such unique industrial waste-derived adsorbents in removing emerging contaminants from water is need of the hour to transform this technology from bench-scale to pilot and large-scale applications. This review investigates different water treatment techniques associated with industrial waste-based adsorbents derived from blast furnace slag, red mud, and copper slag. Besides, this review provides important insights into the growing trends of utilizing such novel types of adsorbents to remove emerging contaminants from water with an emphasis on removal efficacy, controlling measures, adsorption mechanisms, advantages, and limitations. The present timely review brings the current state of knowledge into a single reference which could be a strong platform for future research in understanding the latest advancements, decision making, and financial management related to the treatment of wastewater using industrial waste-based adsorbents.

Strategies for cost-effective remediation of widespread oil-contaminated soils in Kuwait, an environmental legacy of the first Gulf War.

The Kuwaiti oil fire during the first Gulf War resulted in the formation of approximately 300 "oil lakes" of varying sizes that covered over 110 km2 of the desert land. This threatens the fragile desert ecosystems and human health. Following the award of over US$2 billion to the State of Kuwait by the United Nations, large-scale remediation of the oil-contaminated soils has now been on the agenda. However, how to implement the remediation program in a cost-effective way represents a major challenge. In this study, cost-effective remediation strategies were developed based on field and laboratory investigations in a typical oil lake area. Overall, most of the lighter petroleum hydrocarbons (PHCs) were lost due to evaporation. Long-chain aliphatic PHCs dominated the PHCs in the investigated oil lake area. This has implications for developing remediation strategies. Toxicity assessment results showed that the majority of soils pose a low environmental risk with a hazard index <1. Therefore, intensive treatment of these PHCs may not be necessary for these soils. Although active treatment methods are needed to remove the contaminants as soon as practical for the relatively small areas of high contamination, more cost-effective passive methods should be considered to minimize the remedial costs for the larger area of the non-hotspot areas. Given the extremely low risk in terms of groundwater contamination by the contaminated soils, it may not be necessary to remove the soils from the contaminated sites. A low-cost capping method should be sufficient to minimize human exposure to the PHC-contaminated soils.

Red mud-biochar composites (co-pyrolyzed red mud-plant materials): Characteristics and improved efficacy on the treatment of acidic mine water and trace element-contaminated soils.

The use of commercially sourced dopants for synthesizing biochar-based composites could be economically undesirable. The current work aimed to explore the possibility of making low-cost biochar-based composites using red mud (an industrial waste from alumina production) as dopants. Two types of red mud were used: one from a Bayer process and another from a sintering process. Different techniques (wet chemical, magnetic, SEM-EDS, FTIR, XPS and XRD analyses) were adopted to characterize the synthesized red mud-biochar composites, along with the pristine biochar. The composites were superior to the pristine biochar in terms of acid neutralizing capacity, specific surface area, and degree of magnetization. Two laboratory simulation experiments were conducted to assess the improved efficacy of the composites on the treatment of acidic mine water and mine water-contaminated soils. In general, application of the composites resulted in a significantly higher removal rate of mine water-borne trace elements compared to the pristine biochar treatment. The composites also had better effects on immobilizing the soil-borne trace elements and weakening the uptake of trace elements by the test vegetable plant species grown in the composite-treated soils, as compared to the pristine biochar-treated soil. By comparison, the sintering red mud-biochar composite had a generally better performance compared to the Bayer red mud-biochar composite.

Managing soils of environmental significance: A critical review.

Globally, environmentally significant soils (ESSs) mainly include acid sulfate, heavy metal(loid)-contaminated, petroleum hydrocarbon-contaminated, pesticide-contaminated, and radionuclide-contaminated soils. These soils are interrelated and have many common characteristics from an environmental management perspective. In this review, we critically evaluate the available literature on individual ESSs, aiming to identify common problems related to environmental quality/risk assessment, remediation approaches, and environmental regulation for these soils. Based on these findings, we highlight the challenges to, and possible solutions for sustainable ESS management. Contaminated land has been rapidly expanding since the first industrial revolution from the industrialized Western countries to the emerging industrialized Asia and other parts of the world. Clean-up of contaminated lands and slowdown of their expansion require concerted international efforts to develop advanced cleaner production and cost-effective soil remediation technologies in addition to improvement of environmental legislation, regulatory enforcement, financial instruments, and stakeholder involvement to create enabling environments. Two particular areas require further action and research efforts: developing a universal system for assessing ESS quality and improving the cost-effectiveness of remediation technologies. We propose an integrated framework for deriving ESS quality indicators and make suggestions for future research directions to improve the performance of soil remediation technologies.

Decomposition of long-chain petroleum hydrocarbons by Fenton-like processes: Effects of ferrous iron source, salinity and temperature.

Batch experiments were conducted to examine the effects of ferrous iron source, soil salinity and temperature on degradation of long-chain petroleum hydrocarbons by Fenton-like processes. The results show that over 70%, 50% and 25% of aliphatic C16-C21, C21-C35 and C35-C40, respectively, was eliminated at a H2O2 dose of 1.5%. The decomposition rate of petroleum hydrocarbons was similar to each other for ferrous sulfate and magnetite while the capacity of pyrite to trigger Fenton-driven decomposition of long-chain aliphatic petroleum hydrocarbons was weaker, as compared to ferrous sulfate and magnetite. The decomposition rate of aromatic hydrocarbons decreased with increasing length of carbon chain in the ferrous sulfate and magnetite systems, but the opposite was observed in the pyrite system. The effect of Fenton-like process on degradation of long-chain petroleum hydrocarbons was enhanced by increased temperature. At a temperature of 60 °C, the enhancement of Fenton process outweighed the adverse effects from potential loss of H2O2 due to elevated temperature. The use of magnetite as a source of ferrous iron was likely to prevent consumption of Fe2+ by complexation with chloride ion from occurring and consequently effectively eliminated the inhibitory effect of salinity on Fenton reaction.

Red mud as a carbon sink: variability, affecting factors and environmental significance.

The capacity of red mud to sequester CO(2) varied markedly due to differences in bauxite type, processing and disposal methods. Calcium carbonates were the dominant mineral phases responsible for the carbon sequestration in the investigated red mud types. The carbon sequestration capacity of red mud was not fully exploited due to shortages of soluble divalent cations for formation of stable carbonate minerals. Titanate and silicate ions were the two major oxyanions that appeared to strongly compete with carbonate ions for the available soluble Ca. Supply of additional soluble Ca and Mg could be a viable pathway for maximizing carbon sequestration in red mud and simultaneously reducing the causticity of red mud. It is roughly estimated that over 100 million tonnes of CO(2) have been unintentionally sequestered in red mud around the world to date through the natural weathering of historically produced red mud. Based on the current production rate of red mud, it is likely that some 6 million tonnes of CO(2) will be sequestered annually through atmospheric carbonation. If appropriate technologies are in place for incorporating binding cations into red mud, approximately 6 million tonnes of additional CO(2) can be captured and stored in the red mud while the hazardousness of red mud is simultaneously reduced.

Toxic effects of chlorate on three plant species inoculated with arbuscular mycorrhizal fungi.

Pot experiments were conducted to examine the toxic effects of chlorate on bermudagrass, bahiagrass, and longan seedling with a focus on arbuscular mycorrhizal fungi-plant associations. The results show that application of chlorate could cause slight soil acidification, but the resulting pH was still around 5.5, which is unlikely to adversely affect plant growth. Increase in the application rate of chlorate resulted in a decrease in colonization rate of arbuscular mycorrhizal fungi in plant roots, P uptake by the plants and plant biomass. This appears to suggest that the reduction in plant growth may be related to impeded uptake of P by the plants due to the failure of the plants to form sufficient mycorrhizal associations when chlorate is in sufficient amounts to cause toxicity to arbuscular mycorrhizal fungi. Under the experimental conditions set for this study, bermudagrass suffered from stronger chlorate stress than bahiagrass and longan seedling did in terms of plant-arbuscular mycorrhizal fungi (AMF) symbiosis development.

Characterization of red mud derived from a combined Bayer Process and bauxite calcination method.

Red mud can be derived from the processing of bauxite using different methods. The chemical and mineralogical composition of the combined Bayer Process and bauxite calcination red mud (BPBCRM) differs markedly from those of the pure Bayer Process red mud (PBPRM). In this study, red mud derived from a combined Bayer Process and bauxite calcination method was characterized. The results show that pH of the red mud decreased with increasing duration of storage time. Na dominated among the soluble cations, but the concentration of soluble Na decreased with increasing duration of storage time as a result of leaching. Cation exchange capacity also decreased with increasing duration of storage time, probably due to a decrease in pH causing a reduction in negatively charged sites on the red mud particles. Ca was the predominant exchangeable cation in the fresh red mud but the concentration of exchangeable Ca markedly decreased in the old red mud, which was dominated by exchangeable Na. The degree of crystallization and thermal stability of the red mud increased with increasing duration of storage. The acid neutralizing capacity of red mud obtained from this study was about 10 mol kg(-1), which is much greater than the reported values for the pure Bayer Process red mud. Column filtering experiment indicates that the red mud also had a very strong capacity to remove Cu, Zn and Cd from the filtering solution. It is conservatively estimated that the simultaneous removal rates of Cd, Zn and Cu by red mud are over 22,250 mg kg(-1), 22,500 mg kg(-1) and 25,000 mg kg(-1), respectively. The affinity of these metals to the red mud was in the following decreasing order: Cu>Zn>Cd. In general, the fresh red mud retained more heavy metals than the old red mud did.