Dynamic Variations of Soil-Formation Indicators in Bauxite Residue Driven by the Integration of Waste Solids and Microorganisms.

Soil-formation process is critical to ecological rehabilitation on bauxite residue disposal areas. In this study, a soil column experiment was taken to assess the dynamic variations of soil-formation indicators in bauxite residue driven by the integration of waste solids and microorganisms. Results showed that the combination of waste solids and microorganisms significantly decreased the alkalinity, accumulated organic carbon content, and improved aggregate stability of bauxite residue. Compared with waste solids treatments, the addition of acid-producing microorganisms enhanced the changes of soil-formation indicators. The integration of waste solids and microorganisms increased the content of aliphatic carbon, presenting low thermal stability in the residues. The integration of waste solids and microorganisms provides a potentially effective method for soil formation and ecological remediation on bauxite residue disposal areas.

Conversion of alkaline characteristics of bauxite residue by mechanical activated pretreatment: Implications for its dealkalization.

Following the strict environmental policies of various countries, the strong alkalinity of bauxite residue (BR) has become a worldwide problem limiting the sustainable development of the global alumina industry. Continuous conversion of solid-phase alkalinity to free alkali is a major challenge for BR dealkalization to reduce its environmental impact. This work aimed to investigate the effect of mechanical grinding pretreatment on the transformation mechanisms of alkaline solids to free alkali at the BR interface under acids leaching, by monitoring the morphology, phase, and speciation transformations of Al and Si using primarily cross-section scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS) elemental mapping, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS). The results indicated that particle grinding wrapped some of the alkaline minerals inside the particles to inhibit its release process. The leaching kinetics revealed the order of the buffering effect of minerals against acids leaching is firstly dissolved by minerals containing Na and Ca via the ion-exchange process, followed by Si and Al through the hydrolysis of the desilicated products. The mineral dissemination characteristics and surface compositions further confirmed the undissolved minerals block the interface reaction between embedded alkaline solids and acids to result in the difficult reaction dissolution of alkaline minerals, which is induced by ball milling. This novel approach provides new insight into the efficient dealkalization of BR on a large scale in the industry.