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1.
Food Chem ; 268: 264-270, 2018 Dec 01.
Artículo en Inglés | MEDLINE | ID: mdl-30064756

RESUMEN

The aim of this study was to determine the insecticide residue processing factor (PF) from plums to prunes and the effect of the industrial processing of prunes residue concentrations. Our results show an increase of insecticide concentrations during plum dehydration that is explained by fruit water loss; however, the normalized insecticide residue concentration, based on plum dry weights to compensate dehydration, was reduced. The water washing and tenderizing of prunes produced insecticide residue reductions of 22.9 ±â€¯4.5% and 21.9 ±â€¯4.2%, respectively. PF were: 1.157, 1.872, 1.316, 0.192, 2.198, 0.775 and 0.156 for buprofezin, l-cyhalothrin, spirodiclofen, indoxacarb, acetamiprid, imidacloprid and emamectin benzoate, respectively, being directly related to water solubility, aqueous hydrolysis and degradation point and inversely related to molecular mass and melting point. In plums for the dehydrated agroindustry the final product is prunes, therefore, it is crucial to consider the PF to determine the specific preharvest interval for this important agroindustry.


Asunto(s)
Cromatografía de Gases y Espectrometría de Masas , Residuos de Plaguicidas/análisis , Prunus domestica/química , Frutas/química , Frutas/metabolismo , Ivermectina/análogos & derivados , Ivermectina/análisis , Ivermectina/química , Ivermectina/aislamiento & purificación , Neonicotinoides/análisis , Neonicotinoides/química , Neonicotinoides/aislamiento & purificación , Nitrilos/análisis , Nitrilos/química , Nitrilos/aislamiento & purificación , Nitrocompuestos/análisis , Nitrocompuestos/química , Nitrocompuestos/aislamiento & purificación , Oxazinas/análisis , Oxazinas/química , Oxazinas/aislamiento & purificación , Oxidación-Reducción , Residuos de Plaguicidas/química , Residuos de Plaguicidas/aislamiento & purificación , Prunus domestica/metabolismo , Piretrinas/análisis , Piretrinas/química , Piretrinas/aislamiento & purificación , Extracción en Fase Sólida
3.
Food Chem ; 157: 246-51, 2014 Aug 15.
Artículo en Inglés | MEDLINE | ID: mdl-24679777

RESUMEN

Pulp (CP) and ultrafiltered (UF) cactus pear extracts were encapsulated with Capsul (C) by applying a central composite design (CP-C and UF-C systems) by spray-drying. To evaluate the effect of the extract, microparticles obtained under optimal conditions were characterised and stored at 60 °C. Betacyanin and betaxanthin encapsulation efficiency reached values above 98% for both systems studied. This efficiency was attributed to strong interactions between betalains and the polymer. Betalain degradation in CP-C and UF-C microparticles followed pseudo-first order kinetics. The betacyanin degradation rate constant was significantly higher for CP-C than for UF-C. These results suggested that the mucilage or higher sugar content of CP increased the hygroscopicity of the CP-C microparticles, leading to the degradation of betalain. The hydrolysis pathway was the main mechanism of betanin degradation during microparticle storage. These results demonstrate the potential utility of both CP-C and UF-C microparticles as natural colourants for healthy foods.


Asunto(s)
Betacianinas/química , Betalaínas/química , Opuntia/química , Extractos Vegetales/química , Almacenamiento de Alimentos , Frutas , Humanos , Ultrafiltración
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