1.
Nat Prod Commun
; 11(8): 1067-1070, 2016 Aug.
Artículo
en Inglés
| MEDLINE
| ID: mdl-30725557
RESUMEN
Monocyclic compounds bearing ketone and enone moieties in the same molecule can be cyclized to bicyclic compounds initiated by samarium diiodide. The stereochemistry of the products depended on the reaction conditions and also the protecting group of the hydroxy group existed in the molecule. A cyclization mechanism-is discussed.
Asunto(s)
Indanos/síntesis química , Yoduros/química , Samario/química , Botrytis/química , Botrytis/metabolismo , Catálisis , Estructura Molecular
2.
Nat Prod Commun
; 10(4): 551-5, 2015 Apr.
Artículo
en Inglés
| MEDLINE
| ID: mdl-25973473
RESUMEN
A cyclohexane derivative with three chiral centers, a key intermediate for the synthesis of a diterpene verticillol, was prepared starting from (+)-dihydrocarvone. A further challenge to cyclize to a 12-membered carbocycle was attempted, although the products were dimeric derivatives presumably due to an undesirable conformation of the substrate.