Removal of emerging contaminants from wastewater during chemically enhanced primary sedimentation and acidogenic sludge fermentation.

A novel wastewater treatment process, which couples chemically enhanced primary sedimentation (CEPS) of sewage with acidogenic fermentation of sludge in tandem, has recently been developed to improve the removal of pollutants and nutrients, and recover valuable resources such as phosphorus and organics. This study represented the first laboratory-based examination on the level and removal of the emerging contaminants, including retinoids (i.e., retinoic acids (RAs) and their metabolites) and oestrogenic endocrine disrupting chemicals (EDCs; e.g., 4-nonylphenol, bisphenol A, etc.), in sewage, sludge and its supernatant during this novel wastewater treatment process. The results showed that 65% of retinoids and 73% of EDCs were removed from sewage after aluminum (Al) based CEPS, while 80% of retinoids and 72% of EDCs were removed after iron (Fe) based CEPS. After acidogenic fermentation of the CEPS sludge, 50% and 58% of retinoids, and 50% and 47% of EDCs were further removed in the supernatants of Al-sludge and Fe-sludge, respectively. While there were comparable removals for these two classes of emerging contaminants during Al- and Fe-based CEPS and sludge fermentation, Fe-based CEPS of sewage and sludge fermentation should be preferentially considered, given the relatively lower production of Fe-sludge and lower accumulation of retinoids in Fe-sludge. The levels of retinoids and EDCs in the supernatant and sludge changed during acidogenic fermentation of Fe-sludge. The removals of at-4-oxo-RA (i.e., the dominant retinoid) and bisphenol A (i.e., the dominant EDC) in the supernatant followed the pseudo first-order reaction model, with a half-life of 1.62 days (in the first two days) and 1.55 days (in the whole experiment of seven days), respectively. The results demonstrated the effective removal of emerging contaminants from the sewage and the supernatant during the CEPS and acidogenic sludge fermentation.

[Enhanced nitrogen and phosphorus removal of wastewater by using sludge anaerobic fermentation liquid as carbon source in a pilot-scale system].

In order to explore the possibility of enhanced nitrogen and phosphorus removal in wastewater using sludge anaerobic fermentation liquid as external carbon source, the present study proposed an A2/O reactor system with a total effective volume of 4 660 L and real municipal wastewater for treatment. The results showed that under the conditions of the influent COD at 243.7 mg x L(-1), NH4(+) -N at 30. 9 mg x L(-1), TN at 42.9 mg'L- , TP at 2.8 mg x L(-1), the backflow ratio of nitrification liquid at 200% and recycle ratio of sludge at 100%, the addition of acetic acid into anoxic tank could enhance the removal efficiency of nitrogen and phosphorus, and the optimal influent quantity and SCOD incremental of carbon were 7 500 L x d(-1) and 50 mg L(-1), respectively. When the sludge fermentation liquid was used as external carbon source and the average effluent COD, NH4(+) -N, TN, TP removal efficiency were 81.60%, 88.91%, 64.86% and 87.61%, the effluent concentrations were 42.18, 2.77, 11.92 and 0.19 mg x L(-1), respectively, which met China's first Class (A) criteria specified in the Discharge Standard Urban Sewage Treatment Plant Pollutant (GB 18918-2002). The results of the present study demonstrated that the addition of sludge anaerobic fermented liquid as external carbon source was a feasible way to enhance the removal of nitrogen and phosphorous in municipal wastewater, providing a new feasible strategy for the reuse and recycle of sewage sludge in China.

Simultaneous removal of inorganic and organic compounds in wastewater by freshwater green microalgae.

Batch experiments were carried out for 7 days to investigate the simultaneous removal of various organic and inorganic contaminants including total nitrogen (TN), total phosphorus (TP), metals, pharmaceuticals and personal care products (PPCPs), endocrine disrupting chemicals (EDCs), and estrogenic activity in wastewater by four freshwater green microalgae species, Chlamydomonas reinhardtii, Scenedesmus obliquus, Chlorella pyrenoidosa and Chlorella vulgaris. After treatment for 7 days, 76.7-92.3% of TN, and 67.5-82.2% of TP were removed by these four algae species. The removal of metals from wastewater by the four algae species varied among the metal species. These four algae species could remove most of the metals efficiently (>40% removal), but showed low efficiencies in removing Pb, Ni and Co. The four algae species were also found to be efficient in removing most of the selected organic compounds with >50% removal, and the estrogenic activity with removal efficiencies ranging from 46.2 to 81.1% from the wastewater. Therefore, algae could be harnessed to simultaneously remove various contaminants in wastewater.