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J Pharm Biomed Anal ; 100: 138-144, 2014 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-25165009

RESUMEN

The ginkgo terpene lactones (GTL), mainly including bilobalide (BB), ginkgolide A (GA), ginkgolide B (GB) and ginkgolide C (GC) possess different biological activities such as peripheral vasoregulation, platelet-activating factor (PAF) receptor antagonism, neuroprotective properties and prevention of membrane damage caused by free radicals. To investigate the effects of food and gender on the bioavailability of BB, GA, GB and GC after oral administration of GTL extract, a rapid UPLC-MS/MS method was developed and validated. A reversed phase C18 column (100mm×2.1mm, i.d., 1.7µm) and a mobile phase consisted of methanol and 1mM ammonium acetate (70/30, v/v) were employed. Compared with the fasted group, the t1/2 values for BB, GA, GB and GC in fed were all increased (p<0.05), AUC0-t and AUC0-∞ values of BB, GA, GB and GC were all significantly increased (p<0.05), but the Cmax values of BB, GA, GB and GC were significantly decreased (p<0.05). In comparison with the male group, all of the t1/2 values and AUC0-t values for BB, GA, GB and GC in female were higher (p<0.05), but no statistical difference in Tmax values for BB, GA, GB and GC between these two groups. Food and gender factor showed significant effects on the pharmacokinetics of BB, GA, GB, and GC. The results suggested that oral doses of GTL should be lowered for fasted and female subjects, compared with the fed and male subjects, respectively.


Asunto(s)
Interacciones Alimento-Droga , Ginkgo biloba , Ginkgólidos/administración & dosificación , Ginkgólidos/farmacocinética , Lactonas/administración & dosificación , Lactonas/farmacocinética , Extractos Vegetales/administración & dosificación , Extractos Vegetales/farmacocinética , Administración Oral , Animales , Área Bajo la Curva , Disponibilidad Biológica , Cromatografía de Fase Inversa/métodos , Estabilidad de Medicamentos , Ayuno/sangre , Femenino , Ginkgo biloba/química , Ginkgólidos/sangre , Ginkgólidos/aislamiento & purificación , Semivida , Lactonas/sangre , Lactonas/aislamiento & purificación , Masculino , Extractos Vegetales/sangre , Extractos Vegetales/aislamiento & purificación , Periodo Posprandial , Ratas Sprague-Dawley , Reproducibilidad de los Resultados , Factores Sexuales , Espectrometría de Masa por Ionización de Electrospray , Espectrometría de Masas en Tándem
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