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1.
Bioresour Technol ; 273: 297-304, 2019 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-30448681

RESUMEN

Approaches to improve wastewater treatment by microalgae have objectives of greater culture control, efficient nutrient removal and increased lipid content. This work designed a bio-photoelectrolysis cell (BPE) system to modulate wastewater treatment by electric current. The electric current had the capacity to enrich entrapped cell weight with a 0.72-fold increase, which resulted in high daily nutrient removal, with 6.78 mg/L/d for nitrogen and 2.14 mg/L/d for phosphorus at 0.6 A/m2. As the nutrient removal was mostly dependent on cell growth, the 1.17-fold increase of lipid productivity was achieved. The harvesting at 6 A/m2 required lower energy input of 1.77 KWh/kg. For the recyclability of treatment, BPE system could continuously treat the fresh wastewater for at least three cycles with biomass and lipid productivities of 68.67 and 22.04 mg/L/d, respectively. The nitrogen removal model of Cst = 45.52-5.52exp(0.45 t) and phosphorus removal model of Cst = 12.54-1.48exp(0.45 t) were established to evaluate the stability of BPE system.


Asunto(s)
Eliminación de Residuos Líquidos/economía , Aguas Residuales/química , Biomasa , Análisis Costo-Beneficio , Electrólisis , Lípidos/biosíntesis , Nitrógeno/metabolismo , Fósforo/metabolismo , Procesos Fotoquímicos , Aguas Residuales/economía
2.
Water Environ Res ; 90(9): 840-850, 2018 Sep 01.
Artículo en Inglés | MEDLINE | ID: mdl-30208999

RESUMEN

Unintentional phosphate precipitation at water resource recovery facilities (WRRFs) causes operation and maintenance challenges. With global phosphorus (P) scarcity looming and receiving water eutrophication caused by excess discharges of P, intentional P recovery at WRRFs has been gaining traction. To date, struvite recovery as slow release fertilizer has been the focus of P recovery. However, struvite recovery is not always the most cost-effective approach, especially when phosphate fertilizers cost considerably less than the cost to recover struvite as fertilizer. The aim of this state-of-an-art review paper is to discuss P recovery as calcium phosphate, which could be a fertilizer feedstock and incurs less chemical costs to produce. Calcium phosphate also offers broader applications for other industrial uses beyond fertilizers since the composition is close to mined phosphate rock. A strategic approach for a regional reclaimed phosphate reserve is proposed to secure the most economical future supply of P.


Asunto(s)
Precipitación Química , Fósforo/química , Estruvita/química , Eliminación de Residuos Líquidos/métodos , Concentración de Iones de Hidrógeno , Compuestos de Fósforo/economía , Instalaciones de Eliminación de Residuos , Eliminación de Residuos Líquidos/economía
3.
Water Sci Technol ; 77(9-10): 2369-2376, 2018 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-29893725

RESUMEN

The goal of making nutrient removal wastewater treatment energy self-sufficient or even energy producing has become a worldwide accepted goal of technology development. The latest upgrade of the Vienna Main Wastewater Treatment Plant (VMWWTP) with a design capacity of 4 million (M) population equivalent (PE) will produce about 20% more energy on a yearly basis than needed for operation due to a special process scheme. It consists of primary sedimentation, a special 2-stage activated sludge (AS) process configuration where excess sludge is only withdrawn from the first stage AS plant. Raw sludge is subject to mechanical thickening to ∼8% digested sludge (DS) for digestion at high solids concentration. The reject water after nitritation is used for denitritation in the first stage AS plant. This results in markedly reducing the energy requirement for aeration. The design of this last upgrade for energy optimization of sludge treatment is based on the long-term full-scale data from the existing plant, results of mid-term pilot investigations, sound theoretical mass balance calculations and an adapted dynamic model development. All this is presented in this paper. The full-scale upgrade is under construction and will start operating in 2020.


Asunto(s)
Conservación de los Recursos Energéticos , Instalaciones de Eliminación de Residuos/economía , Eliminación de Residuos Líquidos/métodos , Aguas Residuales/química , Austria , Reactores Biológicos , Aguas del Alcantarillado , Eliminación de Residuos Líquidos/economía
4.
Water Res ; 139: 144-157, 2018 08 01.
Artículo en Inglés | MEDLINE | ID: mdl-29635151

RESUMEN

A win-win strategy by the integration of wastewater treatment with value-added products production through a vertical-algal-biofilm enhanced raceway was investigated in the present study. Raceway pond was enhanced by vertically setting the biofilm in the system with a certain interval distance that could be adjusted for different light conditions and wastewater types. Two types of synthetic wastewater were treated with suitability-proven materials as biofilm carriers under four operation distances. Composition of the harvested algal biomass was analyzed. Coral velvet with 5-8 mm length villus was the optimal carrier, since it was durable and with high biomass productivity (6.95-8.11 g m-2·day-1). Nutrients in the wastewaters were efficiently removed with the COD, TN and TP reduction of over 86.61%, 73.68% and 89.85%, respectively. Wastewater with the low nutrients concentration experienced lower biomass and lipid productivity but larger biodiesel productivity and higher nutrient removal efficiency. In addition, as the operation distance increased, wastewater treatment efficiency was first increased but then decreased, while algal biomass footprint production was decreased. Differences in nutrients removal efficiencies were mainly due to the distance difference, which caused different biofilm culture surface areas and light regimes. The optimal operation distance as a function of the efficient nutrient removal and biodiesel production in this study was 6 cm.


Asunto(s)
Chlorophyta/metabolismo , Cianobacterias/metabolismo , Microalgas/metabolismo , Eliminación de Residuos Líquidos/métodos , Biopelículas , Biocombustibles , Biomasa , Chlorophyta/fisiología , Análisis Costo-Beneficio , Cianobacterias/fisiología , Metabolismo de los Lípidos , Microalgas/fisiología , Nitrógeno/metabolismo , Fósforo/metabolismo , Estanques , Eliminación de Residuos Líquidos/economía , Aguas Residuales , Contaminantes del Agua/metabolismo
5.
Water Res ; 132: 111-123, 2018 04 01.
Artículo en Inglés | MEDLINE | ID: mdl-29316514

RESUMEN

Waterborne outbreaks of gastrointestinal diseases can cause large costs to society. Risk management needs to be holistic and transparent in order to reduce these risks in an effective manner. Microbial risk mitigation measures in a drinking water system were investigated using a novel approach combining probabilistic risk assessment and cost-benefit analysis. Lake Vomb in Sweden was used to exemplify and illustrate the risk-based decision model. Four mitigation alternatives were compared, where the first three alternatives, A1-A3, represented connecting 25, 50 and 75%, respectively, of on-site wastewater treatment systems in the catchment to the municipal wastewater treatment plant. The fourth alternative, A4, represented installing a UV-disinfection unit in the drinking water treatment plant. Quantitative microbial risk assessment was used to estimate the positive health effects in terms of quality adjusted life years (QALYs), resulting from the four mitigation alternatives. The health benefits were monetised using a unit cost per QALY. For each mitigation alternative, the net present value of health and environmental benefits and investment, maintenance and running costs was calculated. The results showed that only A4 can reduce the risk (probability of infection) below the World Health Organization guidelines of 10-4 infections per person per year (looking at the 95th percentile). Furthermore, all alternatives resulted in a negative net present value. However, the net present value would be positive (looking at the 50th percentile using a 1% discount rate) if non-monetised benefits (e.g. increased property value divided evenly over the studied time horizon and reduced microbial risks posed to animals), estimated at 800-1200 SEK (€100-150) per connected on-site wastewater treatment system per year, were included. This risk-based decision model creates a robust and transparent decision support tool. It is flexible enough to be tailored and applied to local settings of drinking water systems. The model provides a clear and holistic structure for decisions related to microbial risk mitigation. To improve the decision model, we suggest to further develop the valuation and monetisation of health effects and to refine the propagation of uncertainties and variabilities between the included methods.


Asunto(s)
Técnicas de Apoyo para la Decisión , Agua Potable/microbiología , Purificación del Agua/economía , Análisis Costo-Beneficio , Desinfección , Humanos , Medición de Riesgo , Suecia , Rayos Ultravioleta , Eliminación de Residuos Líquidos/economía , Aguas Residuales
6.
Waste Manag ; 69: 508-517, 2017 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-28864310

RESUMEN

Wastes from concentrated animal feeding operations (CAFOs) are challenging to treat because they are high in organic matter and nutrients. Conventional swine waste treatment options in the U.S., such as uncovered anaerobic lagoons, result in poor effluent quality and greenhouse gas emissions, and implementation of advanced treatment introduces high costs. Therefore, the purpose of this paper is to evaluate the performance and life cycle costs of an alternative system for treating swine CAFO waste, which recovers valuable energy (as biogas) and nutrients (N, P, K+) as saleable fertilizers. The system uses in-vessel anaerobic digestion (AD) for methane production and solids stabilization, followed by struvite precipitation and ion exchange (IX) onto natural zeolites (chabazite or clinoptilolite) for nutrient recovery. An alternative approach that integrated struvite recovery and IX into a single reactor, termed STRIEX, was also investigated. Pilot- and bench-scale reactor experiments were used to evaluate the performance of each stage in the treatment train. Data from these studies were integrated into a life cycle cost analysis (LCCA) to assess the cost-effectiveness of various process alternatives. Significant improvement in water quality, high methane production, and high nutrient recovery (generally over 90%) were observed with both the AD-struvite-IX process and the AD-STRIEX process. The LCCA showed that the STRIEX system can provide considerable financial savings compared to conventional systems. AD, however, incurs high capital costs compared to conventional anaerobic lagoons and may require larger scales to become financially attractive.


Asunto(s)
Crianza de Animales Domésticos/métodos , Eliminación de Residuos Líquidos/métodos , Residuos , Anaerobiosis , Costos y Análisis de Costo , Metano , Nitrógeno/análisis , Fósforo/análisis , Eliminación de Residuos Líquidos/economía
7.
Water Res ; 125: 478-489, 2017 11 15.
Artículo en Inglés | MEDLINE | ID: mdl-28910743

RESUMEN

The environmental and economic benefits and burdens of including the first Short Cut Enhanced Nutrient Abatement (SCENA) into a real municipal wastewater treatment plant were evaluated using life cycle assessment (LCA) and life cycle cost (LCC). The implications of accomplishing nitrogen (N) removal and phosphorus (P) recovery via nitrite in the side stream were assessed taking into account the actual effluent quality improvement, the changes in the electricity and chemical consumption, N2O, CO2 and CH4 emissions and the effects of land application of biosolids, among others. In addition, a case-specific estimation of the P availability when sludge is applied to land, therefore replacing conventional fertilizer, was performed. Furthermore, to account for the variability in input parameters, and to address the related uncertainties, Monte Carlo simulation was applied. The analysis revealed that SCENA in the side stream is an economic and environmentally friendly solution compared to the traditional plant layout with no side-stream treatment, thanks to the reduction of energy and chemical use for the removal of N and P, respectively. The uncertainty analysis proved the validity of the LCA results for global warming potential and impact categories related to the consumption of fossil-based electricity and chemicals, while robust conclusions could not be drawn on freshwater eutrophication and toxicity-related impact categories. Furthermore, three optimization scenarios were also evaluated proving that the performance of the WWTP can be further improved by, for instance, substituting gravitational for mechanical thickening of the sludge or changing the operational strategy to the chemically enhanced primary treatment, although this second alternative will increase the operational cost by 5%. Finally, the outcomes show that shifting P removal from chemical precipitation in the main line to biologically enhanced uptake in the side stream is key to reducing chemicals use, thus the operational cost, and increasing the environmental benefit of synthetic fertilizers replacement.


Asunto(s)
Nitrógeno/aislamiento & purificación , Fósforo/aislamiento & purificación , Aguas del Alcantarillado/análisis , Eliminación de Residuos Líquidos/métodos , Aguas Residuales/análisis , Eutrofización , Fertilizantes , Calentamiento Global , Reciclaje , Eliminación de Residuos Líquidos/economía
8.
Rev Environ Health ; 32(1-2): 111-117, 2017 Mar 01.
Artículo en Inglés | MEDLINE | ID: mdl-28231068

RESUMEN

The constant growth in population worldwide over the past decades continues to put forward the need to provide access to safe, clean water to meet human needs. There is a need for cost-effective technologies for water and wastewater treatment that can meet the global demands and the rigorous water quality standards and at the same maximizing pollutant efficiency removal. Current remediation technologies have failed in keeping up with these factors without becoming cost-prohibitive. Most recently, nanotechnology has been sought as the best alternative to increase access to water supplies by remediating those already contaminated and offering ways to access unconventional sources. The use of iron oxide magnetic nanoparticles as nanoadsorbents has led way to a new class of magnetic separation strategies for water treatment. This review focuses on highlighting some of the most recent advances in core-shell iron oxide magnetic nanoparticles and nanocomposites containing iron oxide nanoparticles currently being developed for water and wastewater treatment of organic pollutants. We discuss the novelty of these novel materials and the insight gained from their advances that can help develop cost-effective reusable technologies for scale-up and commercial use.


Asunto(s)
Compuestos Férricos/química , Nanopartículas del Metal/química , Nanocompuestos/química , Eliminación de Residuos Líquidos/métodos , Contaminantes Químicos del Agua/química , Adsorción , Eliminación de Residuos Líquidos/economía
9.
J Environ Manage ; 183(Pt 3): 1009-1025, 2016 Dec 01.
Artículo en Inglés | MEDLINE | ID: mdl-27692514

RESUMEN

After a ban on the depositing of untreated sludge in landfills, the sludge from municipal and industrial water-treatment plants can be regarded as a problem. Waste products of the water treatment process can be a problem or an opportunity - a source for obtaining raw materials. In the European Union, raw sludge and fats, oil and grease (FOG) from municipal and industrial wastewater treatment plants (WWTP) cannot be deposited in any natural or controlled environment. For this reason, it must be processed (stabilized, dried) to be used later as a fertilizer, building material, or alternative fuel source suitable for co-incineration in high temperature furnaces (power plants or concrete plants). The processes of drying sludge, where heat and electricity are used, are energy consuming and economically unattractive. Beside energy efficiency, the main problem of sludge drying is in its variability of quality as a raw material. In addition to this, sludge can be contaminated by a number of organic and inorganic pollutants and organisms. Due to the presence or absence of pollutants, different end products can be economically interesting. For example, if the dried sludge contains coliform bacteria, viruses, helminths eggs or smaller quantities of heavy metals, it cannot be used as a fertilizer but can still be used as a fuel. The objectives of the current article is to present a batch-processing pilot device of sludge or digestate that allows the following: (1) low pressure and low temperature energy effective drying of from 10 to 40% remaining water content, (2) disinfection of pathogen (micro)organisms, (3) heavy metal reduction, (4) production of products of predetermined quality (e.g. containing different quantities of water; it can be used as a fertilizer, or if the percentage of water in the dry sludge is decreased to 10%, then the dried sludge can be used as a fuel with a calorific value similar to coal). An important feature is also the utilization of low-pressure technology to prevent odorous gasses from spreading into the environment. There are presented two new technologies: a) Sewage sludge or digestate drying in the vacuum chamber consumes approx. 1 kWh/dm3 of evaporated water and, therefore, reaches a price of 180-240 Euros/t Dry Matter (DM), and b) Heavy metals' reduction using adsorbing reaction with magnetite nanostructures can decrease the level of heavy metals in the sewage sludge or digestate up to 20% in one cycle, which can be repeated several times on the same sludge. The aim of the paper is to present a newly developed technology which can provide economic and safe use of moderate heavy metals polluted sewage sludge on agricultural lands as organic fertilizer and, therefore, returning the nutrients (nitrogen, phosphorous, potassium) back to the human food chain, instead of being incinerated or landfilled. The proposed drying technology is economically sustainable due to the low vacuum and temperature (35 °C-40 °C), that increases the efficiency of the heat pump (coefficient of performance 5-7,2) of the energy produced by the anaerobic digestion. Hence, the main emphasis is given to the development of: an efficient method for heavy metals' reduction in the sludge treatment chain by using chitosan covered magnetite nanoparticles, an efficient drying method in a vacuum with low temperature energy which can be exploited from sludge digestion to reduce organic matter, and an energy sustainable concept of sludge treatment, with the addition of fats, oil and grease (FOG) to produce enough biogas for sludge drying to produce fertilizer.


Asunto(s)
Fertilizantes , Aguas del Alcantarillado/química , Eliminación de Residuos Líquidos/métodos , Agricultura , Biocombustibles , Quitosano , Desecación , Fertilizantes/economía , Incineración , Nanopartículas de Magnetita , Metales Pesados/análisis , Metales Pesados/química , Metales Pesados/aislamiento & purificación , Nitrógeno/análisis , Fósforo , Potasio , Eliminación de Residuos Líquidos/economía , Eliminación de Residuos Líquidos/instrumentación , Aguas Residuales/química
10.
Bioresour Technol ; 222: 448-457, 2016 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-27756022

RESUMEN

Discharge of wastewater with high nitrogen and phosphorus content is a major cause of eutrophication. In this study, a microfiltration-based membrane photobioreactor (MPBR) and forward osmosis-based osmotic membrane photobioreactor (OMPBR) have been operated with Chlorella vulgaris for continuous tertiary wastewater treatment. Both the bioreactors exhibited good biomass accumulation (over 2g/L), although the OMPBR achieved better nutrients removal due to high rejection properties of the membranes. At 2days HRT, the OMPBR achieved nitrogen and phosphorus removal efficiencies of 86-99% and 100%, respectively, whereas the corresponding values in the MPBR were 48-97% and 46%, respectively. Based on the energy input, the total operating costs for OMPBR were 32-45% higher than that of the MPBR, and filtration cost for OMPBR was 3.5-4.5 folds higher than that of the MPBR. These results indicate that the integration of membrane filtration with photobioreactors is promising in microalgae-based tertiary wastewater treatment.


Asunto(s)
Chlorella vulgaris/crecimiento & desarrollo , Microalgas/crecimiento & desarrollo , Fotobiorreactores , Eliminación de Residuos Líquidos/instrumentación , Biomasa , Chlorella vulgaris/metabolismo , Costos y Análisis de Costo , Diseño de Equipo , Filtración/instrumentación , Filtración/métodos , Membranas Artificiales , Microalgas/metabolismo , Nitrógeno/aislamiento & purificación , Ósmosis , Fósforo/aislamiento & purificación , Fotobiorreactores/economía , Eliminación de Residuos Líquidos/economía , Eliminación de Residuos Líquidos/métodos , Aguas Residuales/química
11.
J Environ Sci (China) ; 48: 59-68, 2016 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-27745672

RESUMEN

Both internal carbon source and some external carbon sources were used to improve the nutrient removal in Anaerobic-Anoxic-Oxic-Membrane Bioreactor (A2/O-MBRs), and their technical and cost analysis was investigated. The experimental results showed that the nutrient removals were improved by all the carbon source additions. The total nitrogen and phosphorus removal efficiency were higher in the experiments with external carbon source additions than that with internal carbon source addition. It was found that pathways of nitrogen and phosphorus transform were different dependent on different carbon source additions by the mass balance analysis. With external carbon source addition, the simultaneous nitrification and denitrification occurred in aerobic zone, and the P-uptake in aerobic phase was evident. Therefore, with addition of C-MHP (internal carbon source produced from sludge pretreatment by microwave-H2O2 process), the denitrification and phosphorus-uptake in anoxic zone was notable. Cost analysis showed that the unit nitrogen removal costs were 57.13CNY/kg N of C-acetate addition and 54.48CNY/kgN of C-MHP addition, respectively. The results indicated that the C-MHP has a good technical and economic feasibility to substitute external carbon sources partially for nutrient removal.


Asunto(s)
Carbono/metabolismo , Nitrógeno/metabolismo , Fósforo/metabolismo , Eliminación de Residuos Líquidos/métodos , Contaminantes Químicos del Agua/metabolismo , Reactores Biológicos/microbiología , Desnitrificación , Nitrógeno/análisis , Fósforo/análisis , Eliminación de Residuos Líquidos/economía , Aguas Residuales/química , Aguas Residuales/microbiología , Contaminantes Químicos del Agua/análisis
12.
J Environ Sci Health B ; 51(12): 840-846, 2016 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-27494645

RESUMEN

A newly designed continuous-flow 915 MHz microwave wastewater treatment system was used to demonstrate the effectiveness of the microwave enhanced advanced oxidation process (MW/H2O2-AOP) for treating dairy manure. After the treatment, about 84% of total phosphorus and 45% of total chemical oxygen demand were solubilized with the highest H2O2 dosage (0.4% H2O2 per %TS). The reaction kinetics of soluble chemical oxygen demand revealed activation energy to be in the range of 5-22 kJ mole-1. The energy required by the processes was approximately 0.16 kWh per liter of dairy manure heated. A higher H2O2 dosage used in the system had a better process performance in terms of solids solubilization, reaction kinetics, and energy consumption. Cost-benefit analysis for a farm-scale MW/H2O2-AOP treatment system was also presented. The results obtained from this study would provide the basic knowledge for designing an effective farm-scale dairy manure treatment system.


Asunto(s)
Estiércol , Microondas , Eliminación de Residuos Líquidos/métodos , Animales , Análisis de la Demanda Biológica de Oxígeno , Colombia Británica , Bovinos , Análisis Costo-Beneficio , Industria Lechera , Femenino , Peróxido de Hidrógeno/química , Cinética , Estiércol/análisis , Oxidación-Reducción , Fósforo , Proyectos Piloto , Eliminación de Residuos Líquidos/economía , Eliminación de Residuos Líquidos/instrumentación
13.
Water Sci Technol ; 74(2): 359-66, 2016.
Artículo en Inglés | MEDLINE | ID: mdl-27438240

RESUMEN

Sulfide is an important pollutant in aqueous systems. Sulfide removal from polluted waters is required prior to discharge. Red mud (RM) is a solid waste of bauxite processing that is rich in reactive iron oxides and consequently has the potential to be used to remove sulfide from aqueous systems. A series of experiments was undertaken using raw and sintered RM to remove sulfide from waters. RM was highly efficient at sulfide removal (average 75% sulfide removal at initial concentration of ∼5 mg L(-1), with 500 mg L(-1) RM addition) due to both physical adsorption (high specific area) and chemical reaction (with amorphous Fe). Sintered RM, which has a lower surface area and lower mineral reactivity, was much less efficient at removing sulfide (∼20% removal under equivalent experimental conditions). Furthermore, concomitant metal release from raw RM was lower than for sintered RM during the sulfide removal process. The results showed that raw RM is a potentially suitable material for sulfide removal from polluted waters and consequently could be used as a low cost alternative treatment in certain engineering applications.


Asunto(s)
Óxido de Aluminio/química , Sulfuros/química , Eliminación de Residuos Líquidos/métodos , Contaminantes Químicos del Agua/química , Adsorción , Metales/química , Eliminación de Residuos Líquidos/economía
14.
Water Sci Technol ; 73(11): 2704-12, 2016.
Artículo en Inglés | MEDLINE | ID: mdl-27232407

RESUMEN

As the ponding system used to treat palm oil mill effluent (POME) frequently fails to satisfy the discharge standard in Malaysia, the present study aimed to resolve this problem using an optimized electrocoagulation process. Thus, a central composite design (CCD) module in response surface methodology was employed to optimize the interactions of process variables, namely current density, contact time and initial pH targeted on maximum removal of chemical oxygen demand (COD), colour and turbidity with satisfactory pH of discharge POME. The batch study was initially designed by CCD and statistical models of responses were subsequently derived to indicate the significant terms of interactive process variables. All models were verified by analysis of variance showing model significances with Prob > F < 0.01. The optimum performance was obtained at the current density of 56 mA/cm(2), contact time of 65 min and initial pH of 4.5, rendering complete removal of colour and turbidity with COD removal of 75.4%. The pH of post-treated POME of 7.6 was achieved, which is suitable for direct discharge. These predicted outputs were subsequently confirmed by insignificant standard deviation readings between predicted and actual values. This optimum condition also permitted the simultaneous removal of NH3-N, and various metal ions, signifying the superiority of the electrocoagulation process optimized by CCD.


Asunto(s)
Técnicas Electroquímicas , Aceites de Plantas/química , Eliminación de Residuos Líquidos/métodos , Análisis de la Demanda Biológica de Oxígeno , Residuos Industriales/análisis , Malasia , Modelos Estadísticos , Modelos Teóricos , Aceite de Palma , Estanques , Eliminación de Residuos Líquidos/economía
15.
Environ Technol ; 37(10): 1208-19, 2016.
Artículo en Inglés | MEDLINE | ID: mdl-26507382

RESUMEN

The utilization of Fenton's oxidation for the depuration of elderberry juice wastewater was studied. The aim was to select the adequate cost-effective operating conditions suitable to lead to an effluent within the legal thresholds to be discharged into the natural water courses. The treatment efficacy was assessed by chemical oxygen demand (COD), colour, phenolic content and total solids removal besides its ability to improve biodegradability (biochemical oxygen demand (BOD5)/COD). Moreover, the costs of the applied reactants were also considered. Fenton's reaction was able to abate at least 70% of COD (corresponding to a final value below 150 mg O2 L(-1)). Besides, total phenolic content degradation was always achieved. Within these conditions, the resulting effluent is able to be directly discharged into the natural hydric channels. Fenton oxidation could be successfully applied as a single treatment method with a reactant cost of 4.38 €â€…m(-3) ([Fe(2+)] = 20 mmol L(-1), [H2O2] = 100 mmol L(-1), pH = 3 and 4 h of oxidation procedure).


Asunto(s)
Peróxido de Hidrógeno/química , Hierro/química , Sambucus , Eliminación de Residuos Líquidos/métodos , Aguas Residuales/análisis , Purificación del Agua/métodos , Biodegradación Ambiental , Análisis de la Demanda Biológica de Oxígeno , Jugos de Frutas y Vegetales/análisis , Peróxido de Hidrógeno/economía , Hierro/economía , Oxidación-Reducción , Fenoles/análisis , Sambucus/química , Eliminación de Residuos Líquidos/economía , Aguas Residuales/economía , Contaminantes Químicos del Agua/análisis , Purificación del Agua/economía
16.
Water Res ; 88: 380-388, 2016 Jan 01.
Artículo en Inglés | MEDLINE | ID: mdl-26517789

RESUMEN

This study used a range of treated water treatment works sludge options for the removal of phosphorus (P) from primary wastewater. These options included the application of ultrafiltration for recovery of the coagulant from the sludge. The treatment performance and whole life cost (WLC) of the various recovered coagulant (RC) configurations have been considered in relation to fresh ferric sulphate (FFS). Pre-treatment of the sludge with acid followed by removal of organic and particulate contaminants using a 2kD ultrafiltration membrane resulted in a reusable coagulant that closely matched the performance FFS. Unacidified RC showed 53% of the phosphorus removal efficiency of FFS, at a dose of 20 mg/L as Fe and a contact time of 90 min. A longer contact time of 8 h improved performance to 85% of FFS. P removal at the shorter contact time improved to 88% relative to FFS by pre-acidifying the sludge to pH 2, using an acid molar ratio of 5.2:1 mol H(+):Fe. Analysis of the removal of P showed that rapid phosphate precipitation accounted for >65% of removal with FFS. However, for the acidified RC a slower adsorption mechanism dominated; this was accelerated at a lower pH. A cost-benefit analysis showed that relative to dosing FFS and disposing waterworks sludge to land, the 20 year WLC was halved by transporting acidified or unacidified sludge up to 80 km for reuse in wastewater treatment. A maximum inter-site distance was determined to be 240 km above the current disposal route at current prices. Further savings could be made if longer contact times were available to allow greater P removal with unacidified RC.


Asunto(s)
Fósforo/aislamiento & purificación , Ultrafiltración/métodos , Eliminación de Residuos Líquidos/métodos , Análisis Costo-Beneficio , Compuestos Férricos/química , Floculación , Fosfatos/química , Aguas del Alcantarillado , Eliminación de Residuos Líquidos/economía , Purificación del Agua/métodos
17.
Ying Yong Sheng Tai Xue Bao ; 26(8): 2482-92, 2015 Aug.
Artículo en Chino | MEDLINE | ID: mdl-26685613

RESUMEN

Sewage treatment, treated water treatment and sludge treatment are three basic units of an integrated sewage treatment system. This work assessed the influence of reusing or discharge of treated water and sludge landfill or compost on the sustainability of an integrated sewage treatment system using emergy analysis and newly proposed emergy indicators. This system's value included its environmental benefits and the products. Environmental benefits were the differences of the environmental service values before and after sewage treatment. Due to unavailability of data of the exchanged substance and energy in the internal system, products' values were attained by newly proposed substitution values. The results showed that the combination of sewage treatment, treated water reuse and sludge landfill had the strongest competitiveness, while the combination of sewage treatment, treated water reuse and earthworm compost was the most sustainable. Moreover, treated water reuse and earthworm compost were helpful for improving the sustainability of the integrated sewage treatment system. The quality of treated water and local conditions should be also considered when implementing the treated water reuse or discharge. The resources efficiency of earthworm compost unit needed to be further improved. Improved emergy indices were more suitable for integrated sewage treatment systems.


Asunto(s)
Conservación de los Recursos Energéticos , Aguas del Alcantarillado , Eliminación de Residuos Líquidos/economía , Ambiente , Suelo
18.
J Environ Manage ; 161: 317-324, 2015 Sep 15.
Artículo en Inglés | MEDLINE | ID: mdl-26197426

RESUMEN

This study aimed to develop a new, complex pig manure treatment and filtration process. The final scheme, called the AMAK process, comprised the following successive steps: mineralization with mineral acids, alkalization with lime milk, superphosphate addition, a second alkalization, thermal treatment, and pressure filtration. The proposed method produced a filtrate with 95%, 80%, and 96% reductions in chemical oxygen demand, nitrogen content, and phosphorus content, respectively. An advantage of the proposed method was that it incorporated a crystalline phase into the solid organic part of the manure, which enabled high filtration rates (>1000 kg m(-2) h(-1)) and efficient separation. The process also eliminated odor emissions from the filtrate and sediment. The treated filtrate could be used to irrigate crops or it could be further treated in conventional biological wastewater treatment plants. The sediment could be used for producing mineral-organic fertilizer. The AMAK process is inexpensive, and it requires low investment costs.


Asunto(s)
Filtración/métodos , Estiércol , Sus scrofa , Eliminación de Residuos Líquidos/métodos , Riego Agrícola , Animales , Análisis de la Demanda Biológica de Oxígeno , Productos Agrícolas , Difosfatos/química , Fertilizantes , Nitrógeno/análisis , Odorantes , Fósforo/análisis , Eliminación de Residuos Líquidos/economía
19.
Water Res ; 79: 88-103, 2015 Aug 01.
Artículo en Inglés | MEDLINE | ID: mdl-25973581

RESUMEN

Alternative approaches to wastewater management including urine source separation have the potential to simultaneously improve multiple aspects of wastewater treatment, including reduced use of potable water for waste conveyance and improved contaminant removal, especially nutrients. In order to pursue such radical changes, system-level evaluations of urine source separation in community contexts are required. The focus of this life cycle assessment (LCA) is managing nutrients from urine produced in a residential setting with urine source separation and struvite precipitation, as compared with a centralized wastewater treatment approach. The life cycle impacts evaluated in this study pertain to construction of the urine source separation system and operation of drinking water treatment, decentralized urine treatment, and centralized wastewater treatment. System boundaries include fertilizer offsets resulting from the production of urine based struvite fertilizer. As calculated by the Tool for the Reduction and Assessment of Chemical and Other Environmental Impacts (TRACI), urine source separation with MgO addition for subsequent struvite precipitation with high P recovery (Scenario B) has the smallest environmental cost relative to existing centralized wastewater treatment (Scenario A) and urine source separation with MgO and Na3PO4 addition for subsequent struvite precipitation with concurrent high P and N recovery (Scenario C). Preliminary economic evaluations show that the three urine management scenarios are relatively equal on a monetary basis (<13% difference). The impacts of each urine management scenario are most sensitive to the assumed urine composition, the selected urine storage time, and the assumed electricity required to treat influent urine and toilet water used to convey urine at the centralized wastewater treatment plant. The importance of full nutrient recovery from urine in combination with the substantial chemical inputs required for N recovery via struvite precipitation indicate the need for alternative methods of N recovery.


Asunto(s)
Compuestos de Magnesio/química , Fosfatos/química , Orina , Eliminación de Residuos Líquidos/métodos , Precipitación Química , Fertilizantes/economía , Compuestos de Magnesio/orina , Fosfatos/orina , Estruvita , Eliminación de Residuos Líquidos/economía , Aguas Residuales/química , Purificación del Agua/métodos
20.
Water Sci Technol ; 71(4): 495-502, 2015.
Artículo en Inglés | MEDLINE | ID: mdl-25746639

RESUMEN

One of the options to recycle phosphorus (P) in the wastewater sector is to recover it as struvite crystals from digested sludge. Measurements on a full-scale demonstration plant in Leuven, Belgium, yielded a first indication of the profitability of struvite recovery, in function of different variables such as incoming PO(4)(3-) concentration, MgCl2dosing, improved dewaterability, etc. An uncertainty and sensitivity analysis was carried out. Although possible improvement in sludge dewaterability when recovering struvite from digested sludge has a positive economic amortization effect, it is at the same time the largest source of financial risk. A theoretical exercise showed that for struvite recovery from centrate, uncertainty would be lower, and the largest sensitivity would be attributed to ingoing PO(4)(3-) concentration. Although struvite recovery from digested sludge is riskier, it is an investment with potentially a higher return than investment in struvite recovery from centrate. The article provides information for possible financial incentive schemes to support P-recovery.


Asunto(s)
Fósforo/química , Aguas del Alcantarillado/química , Eliminación de Residuos Líquidos/economía , Aguas Residuales/química , Purificación del Agua/economía , Bélgica , Reactores Biológicos , Eliminación de Residuos Líquidos/métodos , Contaminantes Químicos del Agua/química , Purificación del Agua/métodos
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