Solar-powered simultaneous highly efficient seawater desalination and highly specific target extraction with smart DNA hydrogels.

Obtaining freshwater and important minerals from seawater with solar power facilitates the sustainable development of human society. Hydrogels have demonstrated great solar-powered water evaporation potential, but highly efficient and specific target extraction remains to be expanded. Here, we report the simultaneous highly efficient seawater desalination and specific extraction of uranium with smart DNA hydrogels. The DNA hydrogel greatly promoted the evaporation of water, with the water evaporation rate reached a high level of 3.54 kilograms per square meter per hour (1 kilowatt per square meter). Simultaneously, uranyl-specific DNA hydrogel exhibited a high capture capacity of 5.7 milligrams per gram for uranium from natural seawater due to the rapid ion transport driven by the solar powered interfacial evaporation and the high selectivity (10.4 times over vanadium). With programmable functions and easy-to-use devices, the system is expected to play a role in future seawater treatment.

Technical-economic and environmental protection performance evaluation of a novel hybrid solar-nuclear thermally coupled power and desalination plant.

Clean energy complementary system can reduce environmental pollution effectively and is considered as a future energy development direction. In this paper, an innovative solar-nuclear thermally coupled power and desalination plant for electricity and freshwater productions is proposed. As solar power and nuclear power are combined, this multi-energy system is a clean energy system and basically has no emissions of soot, sulfur oxides, carbon dioxide, and nitrogen oxides. The operating behavior assessment results of the multi-energy system show that the power generation and freshwater production systems can operate synergistically. The electric power and corresponding efficiency of the multi-energy system are 290.7 MW and 38.2%, in which the solar proportion is about 38.1%. The daily freshwater production of the multi-energy system is 3761.3 t. The economic assessment results reveal that the levelized costs of electricity and freshwater of the multi-energy system are 0.361 yuan/(kWh) and 1.645 yuan/t. The environmental protection analysis results show that in contrast with a coal-fired system, the annual emission reductions of soot, sulfur oxides, carbon dioxide, and nitrogen oxides of the multi-energy system are 7350.94 t, 12,634.42 t, 513,034.14 t, and 11,945.28 t, revealing a significant environmental protection performance.

"Photovoltaic response of Carissa spinarum berry extract in dye-sensitized solar cell".

The presented work deals with the titanium dioxide semiconductor-based dye-sensitized solar cell (DSSC) performance analysis. The DSSC is sensitized with natural dye extracted from Carissa spinarum fruit with iodide-Tri-iodide as an electrolyte and graphite coated transparent conducting oxide as back electrode. The dye characteristics were investigated by Fourier transform infrared, ultraviolet-visible, and photoluminescence spectroscopy to study the associated functional groups, optical band gap, and emission, respectively. The understudied dye showed an absorption edge at 530nm with an optical band gap around 2.2eV and a broad emission band from 630 to 820nm and with a sharp peak at 741nm. Cyclic voltammograms were employed to estimate the energy levels of the understudy sensitizer. This well-characterized dye has been successfully used in DSSC, and its photovoltaic response was studied under-stimulated AM 1.5 solar illumination using 100mWcm-2 light intensity. For this cell, the short circuit current density (JSC) was 4.17mAcm-2 and the open circuit voltage was 0.423V leading to the power conversion efficiency of 0.956%. Furthermore, this device was also subjected to an open-circuit voltage decay study. We also calculated the lifetime of decay, series resistance (RS), saturation current (IS), shunt resistance (RSh), and the ideality factor (n). Also, an in-depth investigation related to recombination phenomena and how these associated parameters influence the cell's photovoltaic (PV) properties was carried out. The PV performance was also tested in different wavelengths (red, green, blue, etc.) and various useful parameters were calculated.

A demonstration concentrating solar power plant in China: Carbon neutrality, energy renewability and policy perspectives.

Concentrating solar power (CSP) is considered as a promising renewable electricity source due to its superiority in providing dispatchable and base-load electricity. This study performs a systems process analysis to quantify the carbon emissions and nonrenewable energy costs induced by a state-of-art demonstration CSP plant located in the Tibetan plateau. Estimated to induce 111.2 g CO2 eq/kWh carbon emissions and 1.42 MJ/kWh non-renewable energy consumption, the CSP plant is considered to have extremely high carbon neutrality (88.8%) and energy renewability (86.4%). The prominent performance of carbon emissions reduction and energy conservation induced by the CSP plant shed light on its superiority of reliable power supply and environmental benefits. The plant is expected to cumulatively fulfill 3.4 million tons of carbon emissions reduction over its life cycle. In contrast to coal-based power and other renewable energy technologies, CSP technology is shown to be a promising solution to the low-carbon energy transition. Besides, a scenario analysis indicates that the incremental employment of CSP technologies will play a critical role in coping with climate change and energy security in China. Moreover, multiple policies to facilitate the development of the CSP system in China are elaborated, such as the promotion of integrated solar combined-cycle systems. The empirical finding draws a holistic picture of the carbon neutrality and energy sustainability performance of CSP technologies, and the systematic analysis in this study provides comprehensive policy perspectives for energy policy in the Tibetan region as well as in China in the context of global climate change.

The performance enhancement of solar cooker integrated with photovoltaic module and evacuated tubes using ZnO/Acalypha Indica leaf extract: response surface study analysis.

In this study, the effect of employing ZnO/Acalypha Indica leaf extract (ZAE) on the energy absorption of a coated portable solar cooker has been examined using an experimental setup. A prototypical model has been developed to corroborate in associating an investigative outcome per constituents of the experiments. The studied heat transfer process in ZAE is stable for harsh conditions. The design analysis and an estimation of the system performance were done given various parameters including the pressure of the vacuum envelope, bar plate coating digestion, emissivity, and solar rays. The fabricated solar was tested with and without ZAE to investigate the impact of this coating material on the solar cooker's thermal performance. To observe the performance of the new design, two figures of merit (F1 and F2) have been introduced. The factual food cooking assessments were for a family of four people, which operated in ZAE coating (0.8, 1.0, 1.2 µm) of the solar cooker. The values of F1 and F2 for the proposed cooker were obtained as 0.1520 and 0.4235, respectively, which is intact with the BIS values. The results revealed that employing ZAE instead of a thermal NHC-PV solar cooker reduced the time required to boil 2 L of water for about 47 min. The overall thermal energy productivity of the solar cooker with electrical backup was obtained as 42.65%, indicating that the ZAE coating can improve the thermal efficiency by 10.35%.

The asymmetric effect of temperature, exchange rate, metals, and investor sentiments on solar stock price performance in China: evidence from QARDL approach.

The study investigates the asymmetric effect of temperature, exchange rate, metals (rare metals and electrical conductors), and investor sentiments on solar stock price performance in China. The novel econometric techniques, i.e., QARDL (quantile autoregressive distributive lag) approach and Granger causality-in-quantiles to analyze the results. In both short- and long-run estimations, the findings suggest that rare metals (cadmium, germanium, indium, and selenium) and electrical conductors (silver, aluminum, and copper) have significant and positive linkage with solar energy stocks at different quantiles based on bullish, bearish, and normal market conditions. On the other hand, negative effects are found for temperature, RMB exchange rate, and investor sentiments in both the short- and long-run. In the short run, the effect of exchange rate varies across different quantiles but it confines to only lower quantiles (bearish market condition) in the longer run. Solar stocks are more prone to investor sentiments under higher quantiles (bullish market conditions). Lastly, we find that temperature is not merely a behavioral anomaly for the solar energy market as it spreads across middle quantiles (normal market conditions) in the longer run. The findings of Granger causality in quantiles further confirm the results of QARDL.

Efficient dye-sensitized solar cell fabricated using a less toxic alternative to electrolyte and charge collector.

The photovoltaic investigation of novel and efficient dye-sensitized solar cells is discussed in this paper. Ruthenium-based synthetic dye (N3) is used as a sensitizer. A less toxic alternative is suggested for toxic indium-based glass substrates by using aluminum-doped zinc oxide (AZO) and fluorine-doped tin oxide (FTO) as charge collectors. Moreover, the electrolyte used is a mixture of polymer (polyaniline) and an iodide-triiodide couple to go for the approach involving a lower amount of iodine. In the paper study, on the extent of light, absorption of dye is done by ultraviolet-visible (UV-vis) spectroscopy. The morphological study of sheets is done using scanning electron microscopic (SEM) images to understand the binding of titania on photoanode. Photovoltaic characteristics (I-V) and induced photon to current efficiency (IPCE) measurements, and light harvesting efficiency (LHE) are also investigated. The highest power conversion efficiency of 6.18% is observed in the suggested fabricated green solar cell. Hence, more efficient, indium-free, and novel cell is fabricated by the usage of different charge collector substrates and quasi solid-state electrolytes.

A sponge heated by electromagnetic induction and solar energy for quick, efficient, and safe cleanup of high-viscosity crude oil spills.

Frequent oil spills have caused severe environmental and ecological damage. Effective cleanup has become a complex challenge owing to the poor flowability of viscous crude oils. The current method of solar heating to reduce the viscosity of heavy oil is only suitable during sunny days, while the use of Joule heating is limited by the risk of direct exposure to high-voltage electricity. Herein, we demonstrate a noncontact electromagnetic induction and solar dual-heating sponge for the quick, safe, and energy-saving cleanup of ultrahigh-viscosity heavy oil. The resulting sponge with magnetic, conductive, and hydrophobic properties can be rapidly heated to absorb heavy oil under alternating magnetic fields, solar irradiation, or both of these conditions. By constructing theoretical models and fitting the actual data, an in-depth analysis of induction and solar heating processes is carried out. The sponge has excellent resilience and stability, indicating its reusability, fast and continuous adsorption (16.17 g in 10 s), and large capacity (75-81 g/g, the highest value ever) for soft asphalt (a highly viscous crude oil). This work provides a new noncontact dual-heating strategy for heavy oil cleanup, in which absorbents use induction heating during an emergency and then switch to partial or full solar heating to save energy in sunny conditions. ENVIRONMENTAL IMPLICATION: Heavy oils stranded on the beach or floating on water can kill underwater plants by blocking sunlight, or trap water birds and other animals. Heavy oil also contains aromatic substances that are toxic to aquatic organisms. Although oil spills near shallow water cannot be cleaned up by fences or other machinery, an oil adsorbent can deal with this problem. However, common adsorbents cannot effectively absorb high-viscosity oils, such as heavy oil. In this paper, an induction and solar dual-heating sponge is developed for the effective cleanup of high-viscosity oil.

Performance analysis of a solar dryer integrated with thermal energy storage using PCM-Al2O3 nanofluids.

Solar energy will assist in lowering the price of fossil fuels. The current research is based on a study of a solar dryer with thermal storage that uses water and waste engine oil as the working medium at flow rates of 0.035, 0.045, and 0.065 l/s. A parabolic trough collector was used to collect heat, which was then stored in a thermal energy storage device. The system consisted of rectangular boxes containing stearic acid phase change materials with 0.3vol % Al2O3 nanofluids, which stored heat for the waste engine oil medium is 0.33 times that of the water medium at a rate of flow of 0.035 l/s which was also higher than the flow rates of 0.045 and 0.065 l/s. The parabolic trough reflected solar radiation to the receiver, and the heat was collected in the storage medium before being forced into circulation and transferred to the solar dryer. At a flow rate of 0.035 l/s, the energy output of the solar dryer's waste engine oil medium and water was determined to be roughly 12.4, 14, and 15.1, and 9.8, 10.5, and 11.5 times lower than the crops output of groundnut, ginger, and turmeric, respectively. The energy output in the storage tank and the drying of groundnut, ginger, and turmeric crops with water and waste engine oil medium at varied flow rates of 0.035, 0.045, and 0.065 l/s were studied. Finally, depending on the findings of the tests, this research could be useful in agriculture, notably in the drying of vegetables.

Photothermal conversion of biodegradable fluids and carbon black nanofluids.

The paper is devoted to the topic of direct absorption solar collectors (DASCs). Various kinds of fluids can be used as heat transfer fluid in DASCs, and the main focus of our paper is on comparing nanofluids (water with carbon black nanoparticles, concentrations between 0.25 and 1.00% weight) and biodegradable coffee colloids. At first, these fluids were tested by exposing them to irradiation caused by artificial light in indoor experiments, and the corresponding temperature increase was recorded. The fluids were placed in a beaker with a relatively large size so that most of the fluid was not directly irradiated. In these experiments, the performance of the two studied fluids was similar: the resulting temperature increase varied between 46 and 50 °C. Our next experiments involved a smaller system subjected to irradiation obtained by using a solar collector. As a result, we detected an intense absorption on the nanoparticle surface so that the temperature rise in the nanofluid was higher than in the coffee colloids. Next, the process was analysed using a theoretical analysis that gave good correspondence with the experiments. Finally, we extended the theoretical analysis to a DASC with a flowing fluid. The model was validated against results from the literature, but it also supported our experimental findings.

A comprehensive review of dye-sensitized solar cell optimal fabrication conditions, natural dye selection, and application-based future perspectives.

Dye-sensitized solar cells (DSSC) constructed using natural dyes possess irreplaceable advantages in energy applications. The main reasons are its performance, environmentally benign dyes, impressible performance in low light, ecologically friendly energy production, and versatile solar product integration. Though DSSCs using natural dyes as sensitizers have many advantages, they suffer from poor efficiency compared to conventional silicon solar cells. Moreover, the difficulty in converting them to practical devices for the day-to-day energy needs has to be addressed. This review will outline the optimization of conditions to be followed for better efficiency in DSSCs using natural dyes as sensitizers. This review has taken into account the importance of the first step towards the fabrication of DSSC, i.e. the selection process. The selection of plant parts has a noticeable impact on the overall efficiency of the device. Accordingly, a proper study has been done to analyse the plant's parts that have shown better results in terms of device efficiency. In addition to this, a wide range of techniques and factors such as extraction methods, the solvent used, coating techniques, immersing time, and co-sensitization have been taken into consideration from the studies done over the period of 10 years to examine their influence on the overall performance of the DSSC device. These results have been addressed to stipulate the best suitable condition that will help supplement the efficiency of the device even further. Also, the future perspectives, such as the DSSCs use in wearable devices, incorporating various approaches to enhance the power conversion efficiency of DSSCs using natural dyes, and thermochromism ability for DSSCs have been discussed.

Red Phosphorus: An Up-and-Coming Photocatalyst on the Horizon for Sustainable Energy Development and Environmental Remediation.

Photocatalysis is a perennial solution that promises to resolve deep-rooted challenges related to environmental pollution and energy deficit through harvesting the inexhaustible and renewable solar energy. To date, a cornucopia of photocatalytic materials has been investigated with the research wave presently steered by the development of novel, affordable, and effective metal-free semiconductors with fascinating physicochemical and semiconducting characteristics. Coincidentally, the recently emerged red phosphorus (RP) semiconductor finds itself fitting perfectly into this category ascribed to its earth abundant, low-cost, and metal-free nature. More notably, the renowned red allotrope of the phosphorus family is spectacularly bestowed with strengthened optical absorption features, propitious electronic band configuration, and ease of functionalization and modification as well as high stability. Comprehensively detailing RP's roles and implications in photocatalysis, this review article will first include information on different RP allotropes and their chemical structures, followed by the meticulous scrutiny of their physicochemical and semiconducting properties such as electronic band structure, optical absorption features, and charge carrier dynamics. Besides that, state-of-the-art synthesis strategies for developing various RP allotropes and RP-based photocatalytic systems will also be outlined. In addition, modification or functionalization of RP with other semiconductors for promoting effective photocatalytic applications will be discussed to assess its versatility and feasibility as a high-performing photocatalytic system. Lastly, the challenges facing RP photocatalysts and future research directions will be included to propel the feasible development of RP-based systems with considerably augmented photocatalytic efficiency. This review article aspires to facilitate the rational development of multifunctional RP-based photocatalytic systems by widening the cognizance of rational engineering as well as to fine-tune the electronic, optical, and charge carrier properties of RP.

An Intrinsically Micro-/Nanostructured Pollen Substrate with Tunable Optical Properties for Optoelectronic Applications.

There is broad interest in developing photonically active substrates from naturally abundant, minimally processed materials that can help to overcome the environmental challenges of synthetic plastic substrates while also gaining inspiration from biological design principles. To date, most efforts have focused on rationally engineering the micro- and nanoscale structural properties of cellulose-based materials by tuning fibril and fiber dimensions and packing along with chemical modifications, while there is largely untapped potential to design photonically active substrates from other classes of natural materials with distinct morphological features. Herein, the fabrication of a flexible pollen-derived substrate is reported, which exhibits high transparency (>92%) and high haze (>84%) on account of the micro- and nanostructure properties of constituent pollen particles that are readily obtained from nature and require minimal extraction or processing to form the paper-like substrate based on colloidal self-assembly. Experiments and simulations confirm that the optical properties of the pollen substrate are tunable and arise from light-matter interactions with the spiky surface of pollen particles. In a proof-of-concept example, the pollen substrate is incorporated into a functional perovskite solar cell while the tunable optical properties of the intrinsically micro-/nanostructured pollen substrate can be useful for a wide range of optoelectronic applications.

A Combined Experimental and Computational Study of Chrysanthemin as a Pigment for Dye-Sensitized Solar Cells.

The theoretical study of chrysanthemin (cyanidin 3-glucoside) as a pigment for TiO2-based dye-sensitized solar cells (DSSCs) was performed with the GAUSSSIAN 09 simulation. The electronic spectra of neutral and anionic chrysanthemin molecules were calculated by density functional theory with B3LYP functional and DGDZVP basis set. A better energy level alignment was found for partially deprotonated molecules of chrysanthemin, with the excited photoelectron having enough energy in order to be transferred to the conduction band of TiO2 semiconductor in DSSCs. In addition, we used the raw aqueous extracts of roselle (Hibiscus sabdariffa) calyces as the source of chrysanthemin and the extracts with various pH values were tested in DSSCs. The extracts and photosensitized semiconductor layers were characterized by UV-Vis spectroscopy, and DSSCs based on raw extracts were characterized by current density-voltage measurements.

SiOxNy back-contact barriers for CZTSe thin-film solar cells.

The formation of molybdenum diselenide (MoSe2) is widely observed at the back-contact interface for copper zinc tin selenide (CZTSe) thin-film solar cells. Depending on individual selenium (Se) supply and thermal conditions for forming CZTSe absorbers on molybdenum (Mo) substrates, the thickness of MoSe2 can vary from a few hundreds of nanometers up to ≈ 1 µm, which is comparable to the commonly adopted thickness of 1 ~ 1.5 µm for CZTSe absorbers. In this study, for controlling the thickness of interfacial MoSe2, thin diffusion barrier layers of silicon oxynitride (SiOxNy) are deposited onto Mo layers prior to the growth of CZTSe absorbers in the fabrication process. As a result, a reduction in the thicknesses of MoSe2 layers is achieved. In terms of energy conversion efficiency (η), CZTSe solar cells grown on Mo/SiOxNy back contacts suffer a deterioration as the SiOxNy layers get thicker. CZTSe solar cells grown on Mo/SiOxNy/Mo back contacts preserve their efficiencies at ≈ 11% with thin 10 nm SiOxNy layers.

Conversion of Non-Optical Material to Photo-Active Nanocomposites through Non-Conventional Techniques for Water Purification by Solar Energy.

Development of optical materials has attracted strong attention from scientists across the world to obtain low band gap energy and become active in field of solar energy. This challenge, which cannot be accomplished by the usual techniques, has overcome through the current study using non-conventional techniques. This study has used explosive reactions to convert non-optical alumina to series of new optical nanocomposites with very low band gap energy for the first time. In this trend, alumina nanoparticles were prepared and modified by explosive reactions using ammonium nitrate as a solid fuel. By using methanol or ethanol as a source of carbon species, three nanocomposites were produced indicating a gradual reduction of the band gap energy of alumina from 4.34 eV to 1.60 eV. These nanocomposites were obtained by modifying alumina via two different carbon species; core-shell structure and carbon nanotubes. This modification led to sharp reduction for the band gap energy to become very sensitive in sunlight. Therefore, these nanocomposites caused fast decolorization and mineralization of green dyes after illuminating in sunlight for ten minutes. Finally, it can be concluded that reduction of the band gap energy introduces new optical materials for developing optical nano-devices and solar cells.

Evaluating treatment pathways for managing packaging materials from construction of a solar photovoltaic power station.

The reuse of end-of-life packaging materials (EOLPM) on site represents, particularly for remote sites, an important contribution to sustainable business practice because it provides a higher value end use when used to develop on-site mulch to enable soil improvement, thereby reducing transport emissions (in relation to the least preferred option of off-site disposal to landfill), lowering costs and offering employment to local contractors. The objective of the study was to demonstrate a local application of the circular economy for EOLPM to a utility-scale solar electricity (USSE) construction site. Although the principles of the circular economy could not be applied fully at the site, it was possible to demonstrate that EOLPM can be reused on site for a higher value than off-site disposal would give. Given the common occurrence of these materials in the rapidly growing renewable energy sector, this represents an important step forward for the sector internationally. The study is the first of its type reported, and the methods used for characterization of the EOLPM included a range of organic and inorganic chemical analyses and phytotoxicity testing, which were followed by an environmental and financial cost-benefit analysis. The selected option of on-site reuse of the materials as a mulch had a global warming potential of 58 t CO2e compared with the business as usual option (transport to landfill) of 3145 t CO2e. The results also demonstrated the broader potential for using EOLPM from USSE sites for soil improvement at remote locations rather than transporting these materials off site for disposal or reuse.

Determination of Antioxidant and Antifungal Activities in Cookies Fortified with Solar Dried Prickly Pear Peels Powder.

BACKGROUND AND OBJECTIVE: The fortification of bakery products by new materials that attain various goals is considered a challenging that finally gains useful health amelioration. This study was planned to assess the effect of incorporation of solar dried prickly pear peels powder in qaraqeesh (Egyptian cookies) with respect to increase shelf life, sensory palatability and nutritional value. Prickly pear cactus (Opuntia ficus-indica) beside distributed in arid and semiarid regions proved to have phytochemical compounds with high antioxidants capacity. MATERIALS AND METHODS: Fungi colonies were isolated from prickly pear peels. Three levels (1, 3 and 5%) of dried peels powder were added to wheat flour along with other ingredients to make cookies samples. Mycological analysis was assessed in yeast with the three concentrations of peels powder as well as the fresh peels and negative control. The total phenolics, flavonoids, tannins, anthocyanins and carotenoids as well as the antioxidant activity were evaluated in fresh and dried cactus peels. RESULTS: Findings showed that the prickly pear peels powder (PPPP) antioxidant activity was not much affected by the solar drying conditions. The effect of different extracting solvents at different polarties and pH on the phenolic and flavonoids contents of PPPP was studied. Aflatoxins production by aflatoxignicity A. flavus (ATCC 28542) was inhibited by adding different concentrations of PPPP to cookies. Sensory evaluation of fortified cookies was done. All the evaluated characteristics of cookies were given nearly the same values for all levels of dried peels powder. CONCLUSION: Addition of 5% dried cactus peel had lower overall quality and color than the control. Adding 3% of PPPP to cookies (qaraqeesh) showed the highest sensory score. Dried cactus peels may improve quality, nutritional value and shelf life of cookies.

Paper-Based Constant Potential Electrochemiluminescence Sensing Platform with Black Phosphorus as a Luminophore Enabled by a Perovskite Solar Cell.

Exploring efficient luminophores in the electrochemiluminescence (ECL) system is highly desired to pursue a sensitive ECL sensing platform. Herein, the black phosphorus nanosheets (BP NSs) with excellent ECL properties are investigated and serve as the luminophore with the coreactant of peroxydisulfate (S2O82-) solution. Moreover, owing to the overlapping of emission and absorbance spectra, effective resonance energy transfer (RET) is realized between the BP NSs and the introduced Au nanoparticles. In order to achieve the portable and miniaturized developing trends for the paper-based ECL sensing platform, a paper-based perovskite solar cell (PSC) device is designed to act as the power source to replace the commonly utilized expensive and cumbersome electrochemical workstation. Benefiting from that, a PSC driven paper-based constant potential ECL-RET sensing platform is constructed, thereby realizing sensitive microRNAs (miRNAs) detection. What's more, to attain the preferable analytical performance, the duplex-specific nuclease (DSN) is also introduced to assist the target recycling signal amplification strategy. Based on this, highly sensitive detection of miRNA-107 with a range from 0.1 pM to 15 nM is achieved by this designed sensing platform. Most importantly, this work not only pioneers a precedent for developing a high-sensitivity PSC triggered ECL sensing platform but also explores the application prospect of BP nanomaterial in the field of bioanalysis.