Green synthesis of Fe3O4 nanoparticles using Alliaceae waste (Allium sativum) for a sustainable landscape enhancement using support vector regression.

The synthesis of metal nanoparticles using green chemistry methods has gained significant attention in the field of landscape enhancement. Researchers have paid close attention to the development of very effective green chemistry approaches for the production of metal nanoparticles (NPs). The primary goal is to create an environmentally sustainable technique for generating NPs. At the nanoscale, ferro- and ferrimagnetic minerals such as magnetite exhibit superparamagnetic properties (Fe3O4). Magnetic nanoparticles (NPs) have received increased interest in nanoscience and nanotechnology due to their physiochemical properties, small particle size (1-100 nm), and low toxicity. Biological resources such as bacteria, algae, fungus, and plants have been used to manufacture affordable, energy-efficient, non-toxic, and ecologically acceptable metallic NPs. Despite the growing demand for Fe3O4 nanoparticles in a variety of applications, typical chemical production processes can produce hazardous byproducts and trash, resulting in significant environmental implications. The purpose of this study is to look at the ability of Allium sativum, a member of the Alliaceae family recognized for its culinary and medicinal benefits, to synthesize Fe3O4 NPs. Extracts of Allium sativum seeds and cloves include reducing sugars like glucose, which may be used as decreasing factors in the production of Fe3O4 NPs to reduce the requirement for hazardous chemicals and increase sustainability. The analytic procedures were carried out utilizing machine learning as support vector regression (SVR). Furthermore, because Allium sativum is widely accessible and biocompatible, it is a safe and cost-effective material for the manufacture of Fe3O4 NPs. Using the regression indices metrics of root mean square error (RMSE) and coefficient of determination (R2), the X-ray diffraction (XRD) study revealed the lighter, smoother spherical forms of NPs in the presence of aqueous garlic extract and 70.223 nm in its absence. The antifungal activity of Fe3O4 NPs against Candida albicans was investigated using a disc diffusion technique but exhibited no impact at doses of 200, 400, and 600 ppm. This characterization of the nanoparticles helps in understanding their physical properties and provides insights into their potential applications in landscape enhancement.

Application of aluminum oxide nanoparticles in asphalt cement toward non-polluted green environment using linear regression.

In order to decrease the greenhouse gas emissions generated by regular Portland cement (OPC), additional cementitious ingredients have been frequently employed, even while building road bases. OPC's susceptibility to moisture and lack of flexibility make it ineffective for stabilizing road bases. This research used alkali-activated materials (AAM) with fly ash to investigate the mechanical properties of cold asphalt binder (freeze-thaw cycles) including the compressive, flexural strength, workability and porosity of cement. Dry specimens and specimens in distilled water have both been used in the experiments to study these temperature correlations. One sample was tested at 20 °C, and the other was frozen and thawed five times at a temperature of -5 °C (cold region environment). The resulting mixtures' morphologies and microstructures were analyzed via SEM images. During the 7 to 28-day curing period, the mixture's growth ratio rose. The combination registered both the greatest and lowest robust elastic modulus. The total compressive strength of the material decreased as the water-to-cement ratio increased due to the greater amount of free water accessible with a higher cationic asphalt emulsion (CAE) content. The moderate loss of flexural strength with increasing CAE concentration after 7 and 28 days of curing was seen. There is not a major impact on flexural strength in the materials by looking at the very modest gaps in flexural strength between 7 and 28 days curing periods. Due to the particle shape and size of this precursor, FA's inclusion allowed for a lower water to binder rate while maintaining a similar level of workability. The porosity and water absorption values rose with FA substitutions. Further studies might clarify the lower flexural strength observed in this study by adding other hybrids plus fly ash such as lime or nanoparticles.