1.
Chem Asian J
; 11(9): 1357-60, 2016 05 06.
Artigo
em Inglês
| MEDLINE
| ID: mdl-27101381
RESUMO
An unsymmetrically protonated PN(3) -pincer complex in which ruthenium is coordinated by one nitrogen and two phosphorus atoms was employed for the selective generation of hydrogen from formic acid. Mechanistic studies suggest that the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150â h with a turnover number over 1 million was achieved.