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1.
Waste Manag ; 31(7): 1570-5, 2011 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-21376554

RESUMO

For urban community composting centers, the proper selection and use of bulking agent is a key element in not only the cost but also the quality of the finished compost. Besides wood chips (WC) widely used as BA, readily usable cereal residue pellets (CRP) can provide biodegradable carbon and sufficient free air space (FAS) to produce stabilizing temperatures. The objective of the present project was to test at a community center, the effectiveness of CRP in composting food waste (FW). Two recipes were used (CRP with and without WC) to measure: FAS; temperature regimes, and; losses in mass, water, carbon and nitrogen. Both recipes were composted during three consecutive years using a 2 m(3) commercial in-vessel composter operated in downtown Montreal (Canada). For all recipes, FAS exceeded 30% for moisture content below 60%, despite yearly variations in FW and BA physical properties. When properly managed by the center operator, both FW and CRP compost mixtures with and without WC developed within 3 days thermophilic temperatures exceeding 50 °C. The loss of total mass, water, carbon and nitrogen was quite variable for both recipes, ranging from 36% to 54%, 42% to 55%, 48% to 65%, and 4% to 55%, respectively. The highest loss in dry mass, water and C was obtained with FW and CRP without WC aerated to maintain mesophilic rather than thermophilic conditions. Although variable, lower nitrogen losses were obtained with CRP and WC as BA, compared to CRP alone, as also observed during previous laboratory trials. Therefore and as BA, CRP can be used alone but nitrogen losses will be minimized by adding WC. Compost stabilization depends on operator vigilance in terms of aeration. The measured fresh compost density of 530-600 kg/m(3) indicates that the 2 m(3) in-vessel composter can treat 6.5 tons of FW/year if operated during 7 months.


Assuntos
Conservação dos Recursos Naturais/métodos , Alimentos , Eliminação de Resíduos/métodos , Solo , Movimentos do Ar , Canadá , Carbono/análise , Cidades , Humanos , Nitrogênio/análise , Compostos Orgânicos/análise , Características de Residência , Temperatura , Fatores de Tempo , Volatilização , Água/análise
2.
Waste Manag Res ; 28(11): 1039-53, 2010 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-20571148

RESUMO

As a result of urbanization and economic prosperity, which has accelerated the generation of municipal solid waste (MSW) along with its organic fraction, the management of MSW is a challenge faced by urban centres worldwide, including the European Union (EU) and Canada. Within a concept of waste recovery, the source separation and on-site treatment of urban organic waste (UOW) can resolve some of the major economic issues faced by urban centres along with the environmental and social issues associated with landfilling. In this context and in a comparison with the traditional landfilling practice, this paper examines on-site UOW composting strategies using a combination of centralized composting facilities, community composting centres and home composting. This study consisted of a feasibility and economic study based on available data and waste management costs. The results indicate that on-site treatment of UOW using practices such as home and community composting can lower management costs by 50, 37 and 34% for the rich European countries (annual GDP over US$25,000), the poorer European countries (annual GDP under US$25 000), and Canada, respectively. Furthermore, on-site composting can reduce greenhouse gas emissions by 40% for Europe and Canada, despite gas capture practices on landfill sites. However, the performance of home composters and the quality of the compost products are issues to be further addressed for the successful implementation of UOW on-site composting.


Assuntos
Conservação dos Recursos Naturais , Eliminação de Resíduos , Canadá , Cidades , Europa (Continente) , Habitação , Eliminação de Resíduos/economia , Eliminação de Resíduos/métodos , Características de Residência , Solo
3.
Waste Manag ; 30(8-9): 1464-71, 2010.
Artigo em Inglês | MEDLINE | ID: mdl-20395122

RESUMO

Composting is a feasible biological treatment for the recycling of wastewater sludge as a soil amendment. The process can be optimized by selecting an initial compost recipe with physical properties that enhance microbial activity. The present study measured the microbial O(2) uptake rate (OUR) in 16 sludge and wood residue mixtures to estimate the kinetics parameters of maximum growth rate mu(m) and rate of organic matter hydrolysis K(h), as well as the initial biodegradable organic matter fractions present. The starting mixtures consisted of a wide range of moisture content (MC), waste to bulking agent (BA) ratio (W/BA ratio) and BA particle size, which were placed in a laboratory respirometry apparatus to measure their OUR over 4 weeks. A microbial model based on the activated sludge process was used to calculate the kinetic parameters and was found to adequately reproduced OUR curves over time, except for the lag phase and peak OUR, which was not represented and generally over-estimated, respectively. The maximum growth rate mu(m), was found to have a quadratic relationship with MC and a negative association with BA particle size. As a result, increasing MC up to 50% and using a smaller BA particle size of 8-12 mm was seen to maximize mu(m). The rate of hydrolysis K(h) was found to have a linear association with both MC and BA particle size. The model also estimated the initial readily biodegradable organic matter fraction, MB(0), and the slower biodegradable matter requiring hydrolysis, MH(0). The sum of MB(0) and MH(0) was associated with MC, W/BA ratio and the interaction between these two parameters, suggesting that O(2) availability was a key factor in determining the value of these two fractions. The study reinforced the idea that optimization of the physical characteristics of a compost mixture requires a holistic approach.


Assuntos
Fenômenos Microbiológicos , Solo/análise , Biodegradação Ambiental , Fracionamento Químico , Cinética , Modelos Teóricos , Oxigênio/metabolismo , Tamanho da Partícula , Fenômenos Físicos , Microbiologia do Solo
4.
Water Sci Technol ; 57(3): 419-22, 2008.
Artigo em Inglês | MEDLINE | ID: mdl-18309221

RESUMO

This research adapted a batch test for biochemical methane production (BMP) to follow the degradation of complex compounds such as proteins and vegetable oils. The test measured the transformation of albumin and olive oil into methane under mesophilic and thermophilic conditions and assess limiting step in the overall degradation process. The thermophilic sludge used for the BMP tests was adapted during ten month from mesophilic sludge while being fed food waste. As compared to acetic acid, the specific rate of transformation of albumin and olive oil into methane reached 22 and 51%, respectively, under mesophilic conditions. Acetoclastic methanogenesis was not the limiting step in the presence of albumin or olive oil (and its monomer-like molecules such as amino acids, glycerol and oleic acid). Rather, the degradation of albumin was restricted by the presence of proteins. The thermophilically adapted sludge showed good proteolytic activity, but its acetoclastic methanogens were unable to degrade olive oil, because of the inhibitory effect of oleic acid.


Assuntos
Resíduos de Alimentos , Metano/biossíntese , Ácido Acético/metabolismo , Albuminas/metabolismo , Aminoácidos/metabolismo , Anaerobiose , Glicerol/metabolismo , Cinética , Ácido Oleico/metabolismo , Azeite de Oliva , Oxigênio/metabolismo , Óleos de Plantas/metabolismo , Temperatura , Fatores de Tempo
5.
Bioresour Technol ; 99(2): 368-77, 2008 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-17267213

RESUMO

Aspergillus niger NRRL 567 was grown in an inert support material for citric acid production. Optimization of the medium components, including ethanol, methanol, phytate, olive oil and surfactant was carried out using "one-factor-at-a-time" and central composite design (CCD) methods. Optimization using "one-factor-at-a-time" was performed and the supplement of ethanol and methanol between 15 and 30 g/kg dry peat moss (DPM) enhanced citric acid production while higher levels than 30 g/kg DPM had an inhibitory effect on citric acid production at 48 and 72 h of incubation. Based on the results of "one-factor-at-a-time" optimization, phytate, olive oil and methanol were the selected additives to test the effect on citric acid production using CCD. The three variables were identified to have significant effects on citric acid production and the maximum citric acid production of 354.8 g/kg DPM was resulted from the combination of 19 g phytate/kg DPM, 49 g olive oil/kg DPM and 37 g methanol/kg DPM at 120 h. Maximum citric acid production in optimized condition by CCD represented about a 2.7-fold increase compared to that obtained from control before optimization.


Assuntos
Aspergillus niger/fisiologia , Ácido Cítrico/metabolismo , Sphagnopsida/microbiologia , Meios de Cultura , Cinética , Metanol/análise , Azeite de Oliva , Ácido Fítico/análise , Óleos de Plantas/análise , Propriedades de Superfície
6.
J Environ Manage ; 83(2): 191-7, 2007 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-16678965

RESUMO

The objectives of the project were to isolate a bacterial strain capable of degrading pentyl amine and aniline and to define the optimal pentyl amine and aniline degradation conditions for this bacterial strain. The bacterial strain was isolated from activated sludge obtained from a Northeastern China treatment facility for petrochemical wastewater rich in pentyl amine and aniline. Once the strain was isolated, five triplicate (5) batch tests were used to establish the conditions for maximum pentyl amine and aniline degradation, by varying one at a time the following five factors: temperature, pH, reaction time, pollutant concentrations and aeration rate. In a final test, oil refinery sludge was inoculated with the strain and tested for the degradation of pentyl amine and aniline under optimal conditions, while observing the degradation pathway of pentyl amine and aniline. The isolated strain, PN1001, is a member of the Pseudomonas species and it was capable of degrading pentyl amine and aniline. The optimal reactor conditions for the degradation of a mixture of pentyl amine and aniline, at a concentration ranging between 150 and 200mg/L, were found to be 30 degrees C at a pH of 7.0, under a reaction time of 24h and a maximum solution dissolved oxygen level of 6 mgO(2)/L. Under such conditions, the strain PN1001 degraded 93% and 89% of the pentyl amine and aniline, respectively, aniline being more toxic and demonstrating a more complex degradation pathway. The strain PN1001 degraded more contaminants when both were present because of the pi and sigma electron cloud coordination functions of aniline and pentyl amine, respectively, presumed to reduce the toxic effect of aniline. Once inoculated with the strain, oil refinery sludge degraded 93% and 88% of the pentyl amine and aniline, compared to the strain alone which degraded 72% and 82%, likely because of the sludge's buffering effect against the toxic environment.


Assuntos
Aminas/metabolismo , Compostos de Anilina/metabolismo , Resíduos Industriais/análise , Petróleo/metabolismo , Microbiologia da Água , Biodegradação Ambiental , China , Concentração de Íons de Hidrogênio , Oxigênio/química , Oxigênio/metabolismo , Pseudomonas/classificação , Pseudomonas/isolamento & purificação , Pseudomonas/metabolismo , Esgotos/química , Esgotos/microbiologia , Temperatura , Fatores de Tempo
7.
J Environ Sci Health B ; 37(6): 613-23, 2002 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-12403269

RESUMO

The effectiveness of SPS and PULPRO, fine limestone dusts, in precipitating swine and dairy manure phosphorous (P) was determined in the laboratory. Both manures were sieved before being treated with limestone, to reproduce the treatment of mechanically separated manure and to observe the precipitation effect of limestone without that of the large manure solid particles. P precipitation was optimized by varying precipitation conditions (propeller blade speeds, mixing time and limestone levels) and limestone particle size. P precipitation was optimized using a propeller blade mixing speed of 0.3 m s(-1) for at least 5 minutes, using 3% limestone (dry limestone mass over wet manure mass). In terms of particle size, PULPRO 20 (limestone with a particle size of 0.02 mm) produced the most P precipitation and the smallest volume and mass of sludge, as compared to PULPRO 10, PULPRO 3 and SPS (limestone with a particle size of 0.01, 0.003 and 0.3 to 0.003 mm, respectively). For both 9.5% TS (total solids) dairy and 8.8% TS swine manure, mechanical separation followed by limestone precipitation concentrated 90% of manure TS and TP in a sludge volume representing 45% of the initial raw manure mass.


Assuntos
Carbonato de Cálcio/química , Esterco , Fósforo/química , Animais , Bovinos , Poeira , Suínos
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