RESUMO
This study focuses on the investigation of the nitrogen (N) and phosphorus (P) removal characteristics of a combination of enhanced phosphorus removal (EBPR) with simultaneous partial nitrification endogenous denitrification (SPND) and post-partial denitrification process. An anaerobic/aerobic/anoxic (A/O/A) operated sequencing batch reactor (SBR) fed with urban sewage was optimized by regulating the aeration rate and anoxic time. Based on this optimization, deep-level nitrogen and phosphorus removals from low C/N urban sewage could be realized. The experimental results show that the effluent PO43--P concentration decreased from 0.06 mg·L-1 to 0 mg·L-1, the effluent NH4+-N, NO2--N, and NO3--N concentrations gradually decreased from 0.18, 18.79, and 0.08 mg·L-1 to 0, 16.46, and 0.05 mg·L-1, respectively, and the TN removal efficiency increased from 72.69% to 77.97% when the aeration rate decreased from 1.0 L·min-1 to 0.6 L·min-1 and the anoxic duration was 180 min. With the reduction of the aeration rate, the SPND phenomenon became notable and the SND rate increased from 19.18% to 31.20%. When the anoxic duration was extended from 180 min to 420 min, the effluent PO43--P, NH4+-N, and NO3--N concentrations stabilized at~0, 0, and 0.03 mg·L-1, respectively. The effluent NO2--N concentration was as low as 3.06 mg·L-1, the SND rate was~32.21%, the TN removal performance gradually improved, and the TN removal efficiency was as high as 99.42%. Thus, deep-level nitrogen and phosphorus removals could be realized with the SPNDPR-PD system.
Assuntos
Reatores Biológicos , Desnitrificação , Fósforo/isolamento & purificação , Esgotos , Eliminação de Resíduos Líquidos , Nitrogênio/isolamento & purificaçãoRESUMO
To determine the performance of nitrogen and phosphorus removal within a simultaneous nitrification endogenous denitrification system (SNEDPR), an extended anaerobic/low aerobic (dissolved oxygen:0.5-2.0 mg·L-1)-operated sequencing batch reactor (SBR) was fed with simulation wastewater. The SBR was initiated under a constant influent C/N ratio of 10, with the simultaneous enrichment of polyphosphate-accumulating organisms (PAOs). It was then investigated at different influent C/N ratios of 10, 7.5, 5, and 2.5. The experimental results indicated that, when the influent C/N ratio was 10, SNEDPR could be successfully started up. The effluent PO43--P and total nitrogen (TN) concentrations were 0.1 mg·L-1 and 8.1 mg·L-1. PO43--P efficiency, TN efficiency, and SNED efficiency were 99.79%, 89.38%, and 58.0%, respectively. When the influent C/N ratio increased from 5 to 10, the nitrogen and phosphorus removal performance of the system improved with PRA, and SNED efficiency increased from 16.0 m·L-1 and 48.0% to 24.4 mg·L-1 and 69.2%, respectively. When the C/N ratio was 10, the TN and PO43--P removal efficiencies increased to 94.5% and 100%, respectfully. When the C/N ratio was decreased to 2.5, the nitrogen and phosphorus removal performance of the system decreased. The PRA and SNED efficiencies were only 1.36 mg·L-1 and 10%, respectively. During the stable phase of the system (C/N ratio were 10, 7.5 and 5), SNED efficiency reached to 85.9%, with the average effluent concentration of NH4+-N, x--N, and PO43--P being 0.0, 8.1, and 0.1 mg·L-1, respectively.