Enhancing wool dyeing with clove bud (Syzygium aromaticum) based natural dye via microwave treatment using a central composite design.

This research investigates the viability of using Syzygium aromaticum (clove) as a natural dye for wool yarn through the application of microwave treatment and optimization using central composite design (CCD). As concerns grow over the environmental impact of synthetic dyes and their detrimental disposal in water bodies, the search for eco-friendly alternatives becomes imperative to revolutionize the textile industry. Microwave-assisted extraction of the colorant from clove powder is explored as an efficient and sustainable method, minimizing solvent usage and energy consumption compared to conventional techniques. To enhance colorfastness properties while eliminating the need for toxic mordants, green alternatives such as Al, Fe, and tannic acid, combined with plant phenolics from red sumac, pomegranate rind, and weld, are employed. According to the analysis of CCD, the higher color strength value 18.1653 was achieved using pH = 3, time = 50 min, temperature = 70 °C, and salt concentration = 1.5 g/100 mL. The optimized dyeing conditions also showed a maximum level of colorfastness properties of 5 for light, 5 for wash, 5 for dry rubbing, and 4 for wet rubbing. The findings from Fourier-transform infrared spectroscopy and scanning electron microscopy analyses provide valuable insights into the chemical and morphological changes induced by microwave treatment and dyeing with clove extract. The results affirm the presence of eugenol as a potential active molecule responsible for the captivating color of clove flower buds, validating its suitability as a natural dye source for wool. This study highlights the promising potential of microwave-assisted extraction and plant-based biomolecules as innovative and environmentally friendly approaches in natural dyeing, paving the way for a more sustainable future in the textile industry. Embracing these eco-friendly practices allows the textile sector to reduce its ecological footprint and contribute to a cleaner and greener environment. Further research and implementation of these techniques can foster a more harmonious coexistence with nature, ensuring a healthier ecosystem for all.

Effect of Citric Acid on Growth, Ecophysiology, Chloroplast Ultrastructure, and Phytoremediation Potential of Jute (Corchorus capsularis L.) Seedlings Exposed to Copper Stress.

Soil and water contamination from heavy metals and metalloids is one of the most discussed and caused adverse effects on food safety and marketability, crop growth due to phytotoxicity, and environmental health of soil organisms. A hydroponic investigation was executed to evaluate the influence of citric acid (CA) on copper (Cu) phytoextraction potential of jute (Corchorus capsularis L.). Three-weeks-old seedlings of C. capsularis were exposed to different Cu concentrations (0, 50, and 100 µM) with or without the application of CA (2 mM) in a nutrient growth medium. The results revealed that exposure of various levels of Cu by 50 and 100 µM significantly (p < 0.05) reduced plant growth, biomass, chlorophyll contents, gaseous exchange attributes, and damaged ultra-structure of chloroplast in C. capsularis seedlings. Furthermore, Cu toxicity also enhanced the production of malondialdehyde (MDA) which indicated the Cu-induced oxidative damage in the leaves of C. capsularis seedlings. Increasing the level of Cu in the nutrient solution significantly increased Cu uptake by the roots and shoots of C. capsularis seedlings. The application of CA into the nutrient medium significantly alleviated Cu phytotoxicity effects on C. capsularis seedlings as seen by plant growth and biomass, chlorophyll contents, gaseous exchange attributes, and ultra-structure of chloroplast. Moreover, CA supplementation also alleviated Cu-induced oxidative stress by reducing the contents of MDA. In addition, application of CA is helpful in increasing phytoremediation potential of the plant by increasing Cu concentration in the roots and shoots of the plants which is manifested by increasing the values of bioaccumulation (BAF) and translocation factors (TF) also. These observations depicted that application of CA could be a useful approach to assist Cu phytoextraction and stress tolerance against Cu in C. capsularis seedlings grown in Cu contaminated sites.