1.
Chem Commun (Camb)
; 54(62): 8645-8648, 2018 Aug 11.
Artigo
em Inglês
| MEDLINE
| ID: mdl-30022209
RESUMO
As an extension of actinide-rotaxane complexes from uranium to transuranium, we report the first crystal structure of a neptunium-rotaxane complex, NRCP-1, in which an interwoven neptunium(v)-rotaxane coordination network incorporating a mechanically-interlocked [c2]daisy chain unit is promoted via the simultaneous coordination of cucurbituril (CB6) and axle molecules in [2]pseudorotaxane to NpV.