Study on non-point source pollution characteristics under different spatial scales: a case study of Hanjiang River Basin, China.

In recent years, the research on non-point source (NPS) pollution has been deepening, but it is focused on the large-scale watershed or region. There are a few studies on the scales of small watershed and runoff plot, and it is even less to analyze the characteristics and mechanism of non-point source pollution in certain watershed by combining three different scales. Based on the combination of natural rainfall monitoring and MIKE model simulation, the Shaanxi section of Hanjiang River Basin in China was taken as an example to study the characteristics of NPS pollution at different spatial scales. The results showed that there was an obvious correlation between rainfall and runoff/sediment yield. The order of runoff yield/sediment yield per unit area was as follows: woodland > forested and grassy land > arable land. There was a significant relationship between the loss of total phosphorus and the sediment yield in the runoff plots. The total nitrogen pollution was serious, with an average concentration of 3.8 mg/L. The nutrient loss was in the form of nitrate nitrogen, with an average proportion of 63.06%. For small watershed scale, the characteristics of rainfall runoff pollution generation were like runoff plot scale, both have obvious initial scour phenomenon. However, compared with runoff plot scale, the pollutant loss concentration increases with a strong lag. The MIKE model based on the coupling of hydrology, hydrodynamics, and pollution load had a strong applicability in the basin. The critical source areas of NPS pollution were identified, and five scenarios were laid out in the areas for the control of NPS pollution. Centralized livestock and poultry farming had the best reduction effect.

[Adsorption of Phosphate and Heavy Metals by Lanthanum Modified Zeolite and Its Performance in Sediment Inactivation].

Due to the large scale of mining and smelting activities, considerable amounts of heavy metals are discharged into the environment and accumulate in the sediment of rivers and lakes. The combined pollution of heavy metals and the intrinsic phosphorus in sediment calls for novel remediation technologies. In this study, lanthanum-modified zeolite (LMZ) was employed as an inactivation agent for the immobilization of phosphorus, zinc, and lead in sediments. The adsorption capacities as well as the inactivation performance of LMZ for P, Zn, and Pb were investigated, and the adsorption mechanisms were explored via desorption experiments, X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). The results indicated that the adsorption maximums of LMZ for P, Zn, and Pb were 53.76, 27.70, and 123.45 mg·g-1, respectively. Pre-adsorption of Zn and Pb had a negligible effect on the P adsorption by LMZ, whereas the adsorption of Zn and Pb were inhibited significantly by the pre-adsorption. P, Zn, and Pb in the sediment were transformed to more stable or less bioavailable forms by dosing 0.83% and 1.66% weight percentages of LMZ. It was found that P, Zn, and Pb were adsorbed through the formation of inner-sphere complexes. Further, desorption experiments and XRD patterns suggested that electrostatic attraction and surface precipitation also contributed to the adsorption of Zn and Pb, respectively.

Quantitative assessment of non-point source pollution load of PN/PP based on RUSLE model: a case study in Beiluo River Basin in China.

The runoff-sediment relationship in the Yellow River Basin of China is still grim. People pay more and more attention to non-point source (NPS) pollution caused by surface pollutants migrating into the receiving water body with rainfall runoff. The particulate load of pollutants adsorbed in the soil and sediment by erosion and denudation and migration into water is also quite serious. It is necessary to deeply analyze the quantitative relationship between particulate nitrogen and phosphorus (PN/PP) load and soil loss. The soil erosion estimation of different administrative units in the study basin is obtained by the revised universal soil loss equation (RUSLE). The spatial distribution and the variation characteristics at different slopes and different land use of PN/PP load are discussed. An empirical equation of particulate organic load is used to calculate the PN/PP load. The results show that the multi-annual average erosion modulus of the basin is 358.33 t/(km2∙a); the multi-annual average soil erosion reaches 9.62 million tons. The PN/PP load caused by soil loss reaches 11,107.1 t and 7909.3 t, and the export coefficients are 4.13 kg/hm2 and 2.94 kg/hm2, respectively. Spatial distribution of the PN/PP load is in step with the soil erosion distribution. Soil erosion is prone to occur in the region under the slope of 8 ~ 25°, the NPS load of PN/PP are relatively large, and the average export coefficients of PN/PP are 7.17 kg/hm2 and 5.06 kg/hm2. With the increase of the slope, the PN/PP load export coefficient increases first and then decreases. Agricultural land (AGRL), forest land (FRST), and pasture (PAST) are the land use types that contribute the most to the PN/PP load and soil erosion, and the average export coefficients of PN/PP are 4.54 kg/hm2 and 3.23 kg/hm2, respectively. The variability of natural elements, the unevenness and heterogeneity of spatial distribution, and the heavy involvement of human activities will have a conspicuous impact on the soil erosion and NPS pollution processes in the basin. The research on the influence of single factor and combined factors on NPS pollution process can be strengthen and provides scientific theoretical basis for formulating reasonable and efficient water and soil conservation measures and NPS pollution control scheme, so as to achieve effective control and scientific management of environment pollution.

Design parameters and treatment efficiency of a retrofit bioretention system on runoff nitrogen removal.

Mixed media design is key factor that affects the operation of bioretention systems. In this study, four types of modifiers, namely, water treatment residual (WTR), green zeolite, fly ash, and coconut bran, were mixed with traditional bioretention soil (65% sand + 30% soil + 5% sawdust, by mass). Consequently, four kinds of modified media were obtained. Ten pilot-scale bioretention basins were constructed by setting different configurations. The steady infiltration rates of the modified packing bioretention systems were 3.25~62.78 times that of plant soil, which was 2.88~55.75 m/day. Results showed that the average concentration removal (ACR) of both mixed and layered fly ash and WTR were better than those of the other media, and the effects could reach over 61.92%. In the bioretention basins with WTR as the modifier, the treatment efficiency of nitrogen under the submerged zone height of 150 mm was relatively optimal, and ACR could reach 65.46%. Outflow total nitrogen (TN) load was most influenced by inflow load, and the correlation coefficient was above 0.765. Relative to the change of inflow concentration (IC), the change of recurrence interval (RI) and discharge ratio (DR) was more sensitive to TN load reduction. The reduction rate of TN load decreased by approximately 15% when the recurrence interval increased from 0.5 to 3 years. It decreased by approximately 12% when the discharge ratio increased from 10 to 20. This study will provide additional insights into the treatment performance of retrofit bioretention systems, and thus, can guide media and configuration design, effect evaluation, and related processes.