Nutrient treatment of greywater in green wall systems: A critical review of removal mechanisms, performance efficiencies and system design parameters.

Greywater has lower pathogen and nutrient levels than other mixed wastewaters, making it easier to treat and to reuse in nature-based wastewater treatment systems. Green walls (GWs) are one type of nature-based solutions (NBS) that are evolving in design to support on-site and low-cost greywater treatment. Greywater treatment in GWs involves interacting and complex physical, chemical, and biological processes. Design and operational considerations of such green technologies must facilitate these pivotal processes to achieve effective greywater treatment. This critical review comprehensively analyses the scientific literature on nutrient removal from greywater in GWs. It discusses nutrient removal efficiency in different GW types. Total nitrogen removal ranges from 7 to 91% in indirect green facades (IGF), 48-93% for modular living walls (MLW), and 8-26% for continuous living walls (CLW). Total phosphorus removal ranges from 7 to 67% for IGF and 2-53% for MLW. The review also discusses the specific nutrient removal mechanisms orchestrated by vegetation, substrates, and biofilms to understand their role in nitrogen and phosphorus removal within GWs. The effects of key GW design parameters on nutrient removal, including substrate characteristics, vegetation species, biodegradation, temperature, and operating parameters such as irrigation cycle and hydraulic loading rate, are assessed. Results show that greater substrate depth enhances nutrient removal efficiency in GWs by facilitating efficient filtration, straining, adsorption, and various biological processes at varying depths. Particle size and pore size are critical substrate characteristics in GWs. They can significantly impact the effectiveness of physicochemical and biological removal processes by providing sufficient pollutant contact time, active surface area, and by influencing saturation and redox conditions. Hydraulic loading rate (HLR) also impacts the contact time and redox conditions. An HLR between 50 and 60 mm/d during the vegetation growing season provides optimal nutrient removal. Furthermore, nutrient removal was higher when watering cycles were customized to specific vegetation types and their drought tolerances.

Performance evaluation of various individual and mixed media for greywater treatment in vertical nature-based systems.

Nature-based systems (NBS) are a cost-effective, energy efficient and aesthetically pleasing approach for greywater treatment, but they are space intensive. Vertical NBS overcome this issue but must utilize lightweight media to reduce their construction costs. This study evaluates four common plant growing media: perlite, coco coir, LECA and sand, and compares them with two new media derived from local waste materials: date seeds and spent coffee grounds (SCG). The media are characterized and tested for their removal of various greywater pollutants. Further tests are conducted comparing mixtures of perlite-coco coir and date seeds-SCG. SCG was found to be an excellent media for greywater treatment, providing a similar degree of treatment as the best traditional media, coco coir and providing improved drainage. Drainage was further improved by mixing SCG with date seeds, which performed better than any mixture of perlite and coco coir. Most pollutants showed a slight deterioration in treatment performance with this mixture, although the removal of suspended solids and chemical oxygen demand was improved. An increased bed height improved the treatment performance with SCG, while increased hydraulic loading resulted in decreased treatment performance for all media. This study demonstrates the potential of date seeds and SCG as locally recycled waste materials to realize treatment of greywater in vertical NBS.

Biological sulfur oxidation in wastewater treatment: A review of emerging opportunities.

Sulfide prevails in both industrial and municipal waste streams and is one of the most troublesome issues with waste handling. Various technologies and strategies have been developed and used to deal with sulfide for decades, among which biological means make up a considerable portion due to their low operation requirements and flexibility. Sulfur bacteria play a vital role in these biotechnologies. In this article, conventional biological approaches dealing with sulfide and functional microorganisms are systematically reviewed. Linking the sulfur cycle with other nutrient cycles such as nitrogen or phosphorous, and with continued focus of waste remediation by sulfur bacteria, has led to emerging biotechnologies. Furthermore, opportunities for energy harvest and resource recovery based on sulfur bacteria are also discussed. The electroactivity of sulfur bacteria indicates a broad perspective of sulfur-based bioelectrochemical systems in terms of bioelectricity production and bioelectrochemical synthesis. The considerable PHA accumulation, high yield and anoxygenic growth conditions in certain phototrophic sulfur bacteria could provide an interesting alternative for bioplastic production. In this review, new merits of biological sulfide oxidation from a traditional environmental management perspective as well as a waste to resource perspective are presented along with their potential applications.

An exploratory study on seawater-catalysed urine phosphorus recovery (SUPR).

Phosphorus (P) is a crucial and non-renewable resource, while it is excessively discharged via sewage, significant amounts originating from human urine. Recovery of P from source-separated urine presents an opportunity not only to recover this precious resource but also to improve downstream sewage treatment works. This paper proposes a simple and economic method to recover urine derived P by using seawater as a low-cost precipitant to form struvite, as Hong Kong has practised seawater toilet flushing as an alternative water resource since 1958. Chemical reactions, process conditions and precipitate composition for P precipitation in urine have been investigated to develop this new urine P recovery approach. This study concluded that ureolysis extent in a urine-seawater mixture determines the reaction pH that in turn influences the P recovery efficiency significantly; 98% of urine P can precipitate with seawater within 10 min when 40-75% of the urea in urine is ureolysed; the urine to seawater ratio alters the composition of the precipitates. The P content in the precipitates was found to be more than 9% when the urine fraction was 40% or higher. Magnesium ammonium phosphate (MAP) was confirmed to be the predominant component of the precipitates.