Nutrient recovery from municipal solid waste leachate in the scope of circular economy: Recent developments and future perspectives.

Holistically considering the current situation of the commercial synthetic fertilizer (CSF) market, recent global developments, and future projection studies, dependency on CSFs in agricultural production born significant risks, especially to the food security of foreign-dependent countries. The foreign dependency of countries in terms of CSFs can be reduced by the concepts such as the circular economy and resource recovery. Recently, waste streams are considered as a source in order to produce recovery-based fertilizers (RBF). RBFs produced from different waste streams can be substituted with CSFs as input for agricultural applications. Municipal solid waste leachate (MSWL) is one of the waste streams that have a high potential for RBF production. Distribution of the published papers over the years shows that this potential was noticed by more researchers in the millennium. MSWL contains a remarkable amount of nitrogen and phosphorus which are the main nutrients required for agricultural production. These nutrients can be recovered with many different methods such as microalgae cultivation, chemical precipitation, ammonia stripping, membrane separation, etc. MSWL can be generated within the different phases of municipal solid waste (MSW) management. Although it is mainly composed of landfill leachate (LL), composting plant leachate (CPL), incineration plant leachate (IPL), and transfer station leachate (TSL) should be considered as potential sources to produce RBF. This study compiles studies conducted on MSWL from the perspective of nitrogen and phosphorus recovery. Moreover, recent developments and limitations of the subject were extensively discussed and future perspectives were introduced by considering the entire MSW management. Investigated studies in this review showed that the potential of MSWL to produce RBF is significant. The outcomes of this paper will serve the countries for ensuring their food security by implementing the resource recovery concept to produce RBF. Thus, the risks born with the recent global developments could be overcome in this way besides the positive environmental outcomes of resource recovery.

Impact of primary sedimentation on granulation and treatment performance of municipal wastewater by aerobic granular sludge process.

Aerobic granules contain microorganisms that are responsible for carbon, nitrogen, and phosphorus removal in aerobic granular sludge (AGS) process in which aerobic/anoxic/anaerobic layers (from surface to core) occur in a single granule. Optimizing the aerobic granular sludge (AGS) process for granulation and efficient nutrient removal can be challenging. The aim of this study was to examine the impact of settling prior to AGS process on granulation and treatment performance of the process. For this purpose, synthetic wastewater mimicking municipal wastewater was fed directly (Stage 1), and after primary sedimentation (Stage 2) to a laboratory-scale AGS system. In full-scale wastewater treatment plants, primary sedimentation is used to remove particulate organic matter and produce primary sludge which is sent to anaerobic digesters to produce biogas. Performances obtained in both stages were compared in terms of treatment efficiency, granule settling behavior, and granule morphology. Granulation was achieved in both stages with more than 92% chemical oxygen demand (COD) removal efficiencies in each stage. High nutrient removal was obtained in Stage 1 since anaerobic phase was long enough (i.e., 50 min) to hydrolyze particulate matter to become available for PAOs. Primary sedimentation caused a decrease in influent organic load and COD/N ratio, as a result, low nitrogen and phosphorus removal efficiencies were observed in Stage 2 compared to Stage 1. With this study, the effect of the primary sedimentation on the biological removal performance of AGS process was revealed. COD requirement for nutrient removal in AGS systems should be assessed by considering energy generation via biogas production from primary sedimentation sludge.