Nanomolar detection of food additive tert-butylhydroquinone in edible oils based on novel ternary metal oxide embedded ß-cyclodextrin functionalized carbon black.

It is pivotal to precisely detect food preservatives to ascertain food quality and safety. In this work, we report the sensitive electrochemical detection of widely used cytotoxic food preservative tert-butylhydroquinone (TBHQ). A novel nanocomposite was sonochemically prepared by embedding ternary metal oxide (TMO) comprising ZnO, CuO, and MgO in ß-cyclodextrin (ß-CD) functionalized carbon black (CB). The properties of the prepared nanocomposite were evaluated by employing multiple characterization methods. The nanocomposite fabricated on a screen printed carbon electrode exhibited exceptional electrocatalytic activity towards TBHQ detection, evident from the resultant very low detection limit of 1 nM and high sensitivity of 22.67 µA µM-1 cm-2. Moreover, the developed TBHQ sensor evinced all the important traits of a good electrochemical sensor including excellent selectivity, stability, reproducibility, and repeatability. Furthermore, for validating practical feasibility of TBHQ detection, we successfully determined this food additive in edible oils.

Ultrasensitive detection of food colorant sunset yellow using nickel nanoparticles promoted lettuce-like spinel Co3O4 anchored GO nanosheets.

Synthetic food colorants are extensively used across the globe regardless of the fact that they induce deleterious side effects when used in higher amounts. In this work, a novel electrochemical sensor based on nickel nanoparticles doped lettuce-like Co3O4 anchored graphene oxide (GO) nanosheets was developed for effective detection of sulfonated azo dye sunset yellow widely used as a food colorant. Hydrothermal synthesis was adopted for the preparation of lettuce-like spinel Co3O4 nanoparticles and Ni-Co3O4 NPs/GO nanocomposite was prepared using ecofriendly and economical sonochemical method. The prepared ternary nanocomposite meticulously fabricated on a screen-printed carbon electrode exhibited remarkable electrocatalytic activity towards sunset yellow determination. This is apparent from the resultant well-defined and intense redox peak currents of Ni-Co3O4 NPs/GO nanocomposite modified electrode at very low potentials. The developed sunset yellow sensor exhibited a high sensitivity of 4.16 µA µM-1 cm-2 and a nanomolar detection limit of 0.9 nM in the linear range 0.125-108.5 µM. Furthermore, experiments were conducted to affirm excellent stability, reproducibility, repeatability, and selectivity of proposed sensor. The practicality of sunset yellow determination using the developed sensor was analyzed in different varieties of food samples including jelly, soft drink, ice cream, and candy resulting in recovery in the range of 96.16%-102.56%.

Bi-functional renewable biopolymer wrapped CNFs/Ag doped spinel cobalt oxide as a sensitive platform for highly toxic nitroaromatic compound detection and degradation.

Nanomolar-level detection of priority toxic pollutant 4-nitrophenol (4-NP) in environment using a novel ternary nanocomposite based electrochemical sensor and its photocatalytic degradation is reported in this paper. A non-toxic and renewable natural biopolymer, chitosan wrapped carbon nanofibers was embedded with Ag doped spinel Co3O4 to prepare the bi-functional ternary nanocomposite. Economical and ecofriendly sonochemical method was employed in preparation of this porous nanocomposite. We used one-pot aqueous solution approach to synthesize Ag-Co3O4 nanoflowers and ultrasound-assisted method was utilized to prepare CS-CNFs. Morphological and structural properties of synthesized materials were analyzed using different characterization techniques. Electrochemical investigations using cyclic voltammetry and differential pulse voltammetry carried out with prepared ternary nanocomposite modified carbon electrode revealed its outstanding electrocatalytic activity in 4-NP quantification. The developed 4-NP sensor showcased excellent sensitivity of 55.98 µAµM-1cm-2 and nanomolar detection limit of 0.4 nM. Moreover, reproducibility, repeatability, stability, and selectivity were evaluated to confirm reliability of developed sensor. Further, real sample analyses were conducted using domestic sewage, underground water, and tomato to affirm the practical feasibility of 4-NP detection using the proposed sensor.

HPV high risk and protective behaviors: the effects of religious affiliation.

The majority of Americans identify themselves as belonging to some religious group. There is a mixed body of literature on whether or not religious affiliation has an influence on engaging in risky behaviors among young adults attending college. This study examined associations between religious affiliation, risky sexual practices, substance use, and family structure among a sample of predominantly white college females attending a southeastern university. Given the high risk of acquiring genital human papillomavirus infection as a result of high risk sexual practices, gaining a better understanding of how religious affiliation can be used to promote healthy sexual behaviors is warranted.