RESUMO
A series of red to near-infrared (NIR) emitting quantum dots (QDs) with spherical morphologies and tunable photoluminescence (PL) properties have been synthesized by a facile organic route using octadecene (ODE) as solvent and oleic acid (OA) as single capping agent. CdSe cores with the average size of 4.5 nm display the typical optical behaviors with the PL emission peak around 610 nm. The coating CdZnS shells are introduced on the surface of CdSe cores for improving the photostability and PL efficiency of the initial QDs. As the thickness of CdZnS shells increasing, the gradual red-shift of emission wavelength varying from 617 to 634 nm of the resulting QDs can be observed, along with the remarkable increase of PL quantum yield (QY). The composition-dependent CdTe(x)Se(1-x) (CdTeSe) cores with the emission in NIR region are easily carried out by adjusting the molar ratio of Se/Te. The abnormal variation of optical bowling effect is mainly ascribed to the composition effect of alloyed QDs. Compared with CdTe0.1Se0.9/CdZnS core/shell QDs, the introducing of CdZnS shells on CdTe0.05Se0.95 cores can exhibit better passivation effect on surface status, consequently leading to the red-shifted emission peaks in the range of 739-752 nm with the maximum PL QY reaching up to 45.09%. The unique PL properties of CdTeSe-based QDs in the red to NIR range make these core/shell QDs attractive for future biological sensing and labeling applications.