RESUMO
A laboratory simulation experiment was conducted to study the release of sediment phosphorous and nitrogen under the effects of coating the sediment with plastic, clinoptilolite, calcite, quartz sand, and calcium nitrate, aimed to provide scientific basis and technical support to control the sediment nutrient release under the background of water environment pollution by different concentrations of nitrogen and phosphorus. The control efficacy of test coating materials for sediment total phosphorous release was in the order of plastic > calcium nitrate > clinoptilolite > calcite > quartz sand, and that for sediment total nitrogen release was in the order of clinoptilolite > plastic > calcite > quartz sand > calcium nitrate. As for the release of sediment NO(3-)-N, the control efficacy of test coating materials was calcium nitrate > quartz sand > clinoptilolite > calcite > plastic coating; whereas for the release of sediment NH(4+)-N, the sequence was calcium nitrate > plastic coating > clinoptilolite > calcite > quartz sand. Water temperature had definite relativity to the sediment nutrient release. With the increase of water temperature, the concentrations of water total phosphorous and nitrogen and NO(3-)-N increased, while the concentration of water NH(4+)-N presented a declining trend.
Assuntos
Sedimentos Geológicos/química , Poluentes Químicos da Água/análise , Poluição da Água/prevenção & controle , China , Nitratos/análise , Nitrogênio/análise , Fósforo/análise , RiosRESUMO
Water samples and sediment cores were taken at 5 sites of Nanhu Lake, Wuhan to investigate the seasonal dynamics of phosphorus in water body, sediments and their interstitial water, as well as the phosphorus forms in sediments. The results showed that the average concentrations of total phosphorus (TP) and orthophosphate (PO4(3-) -P) in water body were 0.240 and 0.033 mg x L(-1), respectively, with the highest concentrations of TP and PO4(3-)-P in November and the lowest concentration of TP and of PO4(3-) -P in February and August, respectively. The concentration of TP in sediments was averagely 1.005 mg x g(-1), being increased from April to November and becoming stable from November to February, and decreased with sedimentation depth. The concentration of PO4(3-) -P in interstitial water was 0.209 mg x L(-1) on average, being the highest in November and the lowest in February, with the same vertical distribution pattern like TP in sediments. The dominant form of phosphorus in sediments was inorganic phosphorus (IP), occupying 61.4%-77.1% of total extracted phosphorus. The concentration of bio-available phosphorus (BA-P) in sediments was very high, but decreased significantly with sedimentation depth. According to the significant correlations between phosphorus forms in sediments and PO4(3-) -P in interstitial water, the BA-P and auto-calcium bound phosphorus (ACa-P) in sediments should be the main P sources released from sediments to water body.