Designed Core-Shell Fe3O4@Polydopamine for Effectively Removing Uranium(VI) from Aqueous Solution.

Adsorbents with the combination of magnetic separation and removal performance are expected for reducing the adverse impact of nuclear pollution. In this study, the core-shell Fe3O4@polydopamine (Fe3O4@PDA) was successfully synthesized and used for removal of uranium (U(VI)) ion from aqueous solution. The abundant N-containing groups derived from PDA exist as the chelate sites for U(VI) and contribute greatly for U(VI) removal. Experimental results show that Fe3O4@PDA (56.39 mg g-1) exhibits greater sorption capacity for U(VI) removal compared with the pure Fe3O4 (9.17 mg g-1). The sorption isotherm can be well fitted with Freundlich model and the sorption process is endothermic and spontaneous. The removal of U(VI) can be explained by the complexation of U(VI) with -NH-, -NH2 and C-O in the surface of Fe3O4@PDA by X-ray photoelectron spectroscopy (XPS) analysis.

Fully phosphorylated 3D graphene oxide foam for the significantly enhanced U(VI) sequestration.

Efficient sequestration of U(VI) from complex aqueous solution is of vital importance for environmental remediation. In this work, the fully phosphorylated graphene oxide foam (phos-GOF) was synthesized via a facile hydrothermal method and the as-prepared 3D phos-GOF was served as an adsorbent to capture U(VI) from aqueous solution. The introduction of abundant phosphorus-containing groups via phytic acid endows phos-GOF good hydrophilia and excellent affinity for U(VI). The adsorption performance of phos-GOF for U(VI) was carefully evaluated under different environments. phos-GOF shows rapid and high efficiency for U(VI) adsorption. The maximum adsorption capacity of phos-GOF for U(VI) is ∼483 mg/g, which is much higher than that of pristine graphene oxide foam (GOF). In addition, the spent 3D phos-GOF can be easily regenerated by a simple and low-cost desorption process using 0.02 mol/L HNO3. The interaction mechanism between phos-GOF and U(VI) is mainly attributed to the inner-sphere complexation between phosphoric functional groups and U(VI) based on a series of spectroscopic analyses. The 3D phos-GOF exhibits favorable sequestration performance towards U(VI) which can be used as a potential candidate in uranium-bearing wastewater treatment and disposal.

K2Ti6O13 hybridized graphene oxide: Effective enhancement in photodegradation of RhB and photoreduction of U(VI).

The environmental pollutions by organic pollutants and radionuclides have aroused great concern. Developing highly efficient elimination methods becomes an imperious demand. In this study, a nanocomposite of K2Ti6O13 (KTO) nanobelts hybridized graphene oxide (GO) nanosheets (GO/KTO) was used to photodegrade RhB (dye) and photoreduce U(VI) (radionuclide), which was synthesized by a facile hydrothermal method. The adsorption capacity and the slope (k) of the curve -ln(C/C) versus time in photodegradation of RhB by GO/KTO were higher than that by GO and KTO. In the presence of different free radical scavengers, superoxide radical (·O2-) was found to play the most significant role in the reaction. The XPS experiment indicates U(VI) was successfully photoreduced to less toxic U(IV). The pH dependent photocatalytic experiments on RhB and U(VI) both showed the best performance at neutral pH value (from pH 6 to pH 8). To investigate the reason for the enhanced photocatalysis of GO/KTO, the morphology/microstructure, optical and photo-electrochemical properties were examined. The enhanced abilities of separation of photo electrons and holes and the adsorption of GO/KTO were ascribed to the structure of KTO nanobelts laying on the surface of GO nanosheets, which may maximize the contacting area between KTO and GO, and thus greatly reduce the surface related oxygen defects to enhance the electron interface transfer between KTO and GO and decrease the recombination efficiency of electrons and holes. These results showed the GO/KTO has great application potential in environmental treatment of organic pollutants and high valent heavy/radionuclide ions at neutral condition.