Evaluation of violations in water quality standards in the monitoring network of São Francisco River basin, the third largest in Brazil.

The São Francisco River is the largest river located entirely within Brazil, and water scarcity problems have been a major concern of Brazilian society and government. Water quality issues are also a concern and have worsened with the recent intensification of urbanization and industrialization. In this study, violations to water quality standards established by local legislation were calculated as a percentage for 26 selected parameters over a monitoring period of 14 years. The violation percentages were analyzed spatially using the Kruskal-Wallis test, followed by multiple comparison analysis. Temporal analysis was performed using the Mann-Kendall test and Spearman correlation. Some parameters could be identified as cause for concern due to high violation levels, such as the fecal coliform indicator (FCI) and phosphorus-both related to domestic and effluent disposal without treatment or with insufficient treatment-and color, turbidity, manganese, and total suspended solids-which can be affected by erosive processes of natural and anthropogenic causes. The study found that these violations are concentrated in the most urbanized and industrialized areas of the basin. Some metallic parameters, such as iron and arsenic violations, may be related to mining activities in the rich soil of the Iron Quadrangle area located within the Minas Gerais State. Trend analysis results indicated that most monitoring stations did not have significant modification (elevation or reduction) trends over time, which, together with the high violation percentages, might indicate the maintenance of a scenario of constant pressure upon water resources, in particular in those more urbanized areas.

Temporal and spatial characteristics of the water pollutant concentration in Huaihe River Basin from 2003 to 2012, China.

Based on the monitoring data of 78 monitoring stations from 2003 to 2012, five key water quality indexes (biochemical oxygen demand: BOD5, permanganate index: CODMn, dissolved oxygen: DO, ammonium nitrogen: NH3-N, and total phosphorus: TP) were selected to analyze their temporal and spatial characteristics in the highly disturbed Huaihe River Basin via Mann-Kendall trend analysis and boxplot analysis. The temporal and spatial variations of water pollutant concentrations in the Huaihe River Basin were investigated and analyzed to provide a scientific basis for water pollution control, water environment protection, and ecological restoration. The results indicated that the Yinghe River, Quanhe River, Honghe River, Guohe River, and Baohe River were the most seriously polluted rivers, followed by Hongze Lake, Luoma Lake, Yishuhe River, and Nansi Lake. BOD5, CODMn, and NH3-N were the major pollution indexes, for which the monitoring stations reported that more than 40 % of the water quality concentrations exceeded the class IV level. There were 21, 50, 36, and 21 monitoring stations that recorded significantly decreasing trends for BOD5, CODMn, NH3-N, and TP, respectively, and 39 monitoring stations showed a significantly increasing trend for DO. Moreover, the water quality concentrations had a certain concentricity and volatility according to boxplot analysis for the 20 monitoring stations. The majority of monitoring stations recorded a large fluctuation for the monitoring indexes in 2003 and 2004, which indicated that the water quality concentrations were unstable. According to the seasonal variations of the water quality concentrations in the mainstream of Huaihe River, the monthly variation trends of the BOD5, CODMn, DO, NH3-N, and TP concentrations were basically consistent among the seven monitoring stations. The BOD5, CODMn, NH3-N, and TP concentrations were affected by the change of the stream discharge; changes in DO and NH3-N concentrations were influenced by the regional environmental temperature, and the DO and NH3-N concentrations decreased when the water temperature increased.

Environmental response of an Irish estuary to changing land management practices.

Anthropogenic pressures have led to problems of nutrient over-enrichment and eutrophication in estuarine and coastal systems on a global scale. Recent improvements in farming practices, specifically a decrease in fertiliser application rates, have reduced nutrient loadings in Ireland. In line with national and European Directives, monitoring of Irish estuarine systems has been conducted for the last 30years, allowing a comparison of the effectiveness of measures undertaken to improve water quality and chemical and biological trends. The Blackwater Estuary, which drains a large agricultural catchment on the south coast of Ireland, has experienced a decrease in calculated nitrogen (N) (17%) and phosphorus (P) (20%) loads in the last decade. Monitored long-term river inputs reflect the reductions while estuarine P concentrations, chlorophyll and dissolved oxygen saturation show concurrent improvement. Consistently high N concentrations suggest a decoupling between N loads and estuarine responses. This highlights the complex interaction between N and P load reductions, and biochemical processes relating to remineralisation and primary production which can alter the effectiveness of the estuarine filter in reducing nutrient transport to the coastal zone. Effective management and reduction of both diffuse and point nutrient sources to surface waters require a consideration of the processes which may alter the effectiveness of measures in estuarine and coastal waters.