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1.
Chemosphere ; 357: 141920, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38636914

RESUMO

Antimony contamination from textile industries has been a global environmental concern and the existing treatment technologies could not reduce Sb(V) to meet the discharge standards. To overcome this shortcoming, ferric flocs were introduced to expedite the biological process for enhanced Sb(V) removal in wastewater treatment plant (WWTP). For this purpose, a series of laboratorial-scale sequential batch reactor activated sludge processes (SBRs) were applied for Sb(V) removal with varied reactor conditions and the transformation of Fe and Sb in SBR system was investigated. Results showed a significant improvement in Sb(V) removal and the 20 mg L-1 d-1 iron ions dosage and iron loss rate was found to be only 15.2%. The influent Sb(V) concentration ranging 153-612 µg L-1 was reduced to below 50 µg L-1, and the maximum Sb(V) removal rate of the enhanced system reached about 94.3%. Furthermore, it exhibited high stability of Sb(V) removal in the face of antimonate load, Fe strike and matrix change of wastewater. Sludge total Sb determination and capacity calculation revealed decreasing in Sb adsorption capacity and desorption without fresh Fe dosage. While sludge morphology analysis demonstrated the aging and crystallization of iron hydroxides. These results verify the distinct effects of fresh iron addition and iron aging on Sb(V) removal. High-throughput gene pyrosequencing results showed that the iron addition changed microbial mechanisms and effect Fe oxidized bacterial quantity, indicating Sb(V) immobilization achieved by microbial synergistic iron oxidation. The present study successfully established a simple and efficient method for Sb(V) removal during biological treatment, and the modification of biological process by iron supplement could provide insights for real textile wastewater treatment.


Assuntos
Antimônio , Esgotos , Eliminação de Resíduos Líquidos , Águas Residuárias , Poluentes Químicos da Água , Águas Residuárias/química , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/metabolismo , Esgotos/química , Esgotos/microbiologia , Antimônio/química , Ferro/química , Adsorção , Indústria Têxtil , Compostos Férricos/química , Reatores Biológicos/microbiologia , Têxteis , Biodegradação Ambiental , Aerobiose
2.
Water Sci Technol ; 87(5): 1056-1071, 2023 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-36919733

RESUMO

This research aims to evaluate the performance of PolyCera® Titan membrane for different wastewater treatment. Membrane filtration of several cycles was conducted in understanding the fouling mechanism, fouling propensity, and defouling potential of the PolyCera® Titan which had not been studied by any other researcher before. The PolyCera® Titan membrane is effective for the treatment of textile industry wastewater, palm oil mill effluent (POME), leachate, and semiconductor-industry wastewater. Rejection of methylene blue (MB) and Congo red (CR) was in the range of 78.76-86.04% and 88.89-93.71%, respectively; 94.72-96.50% NaCl, 96.07-97.62% kaolin, and 97.26-97.73% glucose were rejected from synthetic leachate indicating the removal of TDS, TSS, and COD from the leachate, respectively. Standard blocking and complete model were the best models used to explain the PolyCera® Titan membrane fouling mechanism in all types of wastewater treatment processes with a high R2 value. Physical cleaning with the use of distilled water was able to recover the permeate flux with the flux recovery ratio (FRR) value in the range of 79.2-95.22% in the first cycle, 81.20-98.16% in the second cycle, and 86.09-95.96% in the third cycle.


Assuntos
Águas Residuárias , Purificação da Água , Membranas Artificiais , Óleo de Palmeira , Indústria Têxtil
3.
Environ Sci Pollut Res Int ; 30(12): 33907-33916, 2023 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-36502479

RESUMO

Textile wastewater still poses a huge environmental problem due to its high water consumption and high effluent release that is full of toxic chemicals. In the present study, different approaches were studied to layout an operating procedure for textile wastewater treatment in order to obtain treated wastewater that is safe for non-potable uses. Our approach depended on (1) co-substrate to biostimulate indigenous microbial textile wastewater community by adding Tryptone Soy Broth (TSB) and TSB supplemented with 1% glucose, (2) co-culture (bioaugmentation) with Bacillus spizizenii DN cells (previously isolated, identified and characterized as efficient decolorizing bacteria), and (3) co-metabolites using Bacillus spizizenii DN metabolites. The obtained results show that using Bacillus spizizenii DN cells resulted in 97.78% decolorization while adding Bacillus spizizenii DN metabolites resulted in 82.92% decolorization, both after 48 h incubation under microaerophilic conditions. The phyla identified for all treatments were Bacteroidota, Firmicutes, and Proteobacteria. The dynamic changes in the bacteria showed that both Clostridium and Acinetobacter disappeared for co-substrate, co-culture, and co-metabolite cultures. While Alkalibacterium and Stenotrophomonas appeared after adding Bacillus spizizenii DN cells, Flavobacterium increased for co-substrate and co-metabolic cultures while iron reducing bacteria appeared only for co-metabolic cultures. The use of 25 kGy gamma irradiation as a sterilization dose post bioremediation ensured safe use of treated wastewater. This was confirmed by cytotoxicity assay; the obtained IC50 tested on BJ fibroblasts obtained from skin showed that gamma irradiated treated wastewater are about 80.1% less toxic than non-irradiated treated wastewater. We conclude that (1) we can use combined bioaugmentation and biostimulation as initial steps for in situ bioremediation in collection tanks and that (2) the proposed protocol for bioremediation of industrial wastewater should be tailored based on the required application and level of safety needed for re-use.


Assuntos
Bacillus , Purificação da Água , Águas Residuárias , Consórcios Microbianos , Bacillus/metabolismo , Bactérias/metabolismo , Biodegradação Ambiental , Purificação da Água/métodos , Têxteis , Indústria Têxtil , Corantes/metabolismo
4.
Environ Sci Pollut Res Int ; 30(8): 21863-21871, 2023 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-36279062

RESUMO

For the current study, Bougainvillea flowers as environment friendly sustainable source of plant-based natural dye have been selected as an alternative to toxic synthetic dyes for dyeing of cotton and silk. Natural colorant from Bougainvillea flowers (Bougainvillea glabra) was extracted using aqueous and acidic extraction media. Maximum colorant was extracted in aqueous medium, and further it was used for cotton and silk dyeing. The optimum values of the dyeing parameters including dyeing time, dye to liquor ratio and salt level as exhausting agent were found to be 30 min, 35-mL liquor ratio and 3.0 g for cotton and for silk 45 min dyeing time, 45-mL liquor ratio and 3.0 g exhausting agent in aqueous dye extract. Bio mordanting has been applied to attain a variety of color shades. The utilization of 3% of henna, 4% of turmeric for silk pre-mordanting and for post-mordanting turmeric at 3% and henna at 4% for silk gave a darker shade. For cotton bio mordanting, 2% turmeric rhizome powder, 3% henna leaves powder extract as pre-mordant and 2% turmeric, 3% henna as post-mordant has developed a variety of shade. Overall, it has been found that natural colorant from Bougainvillea flowers is the new dye source for bio-coloration of natural fabrics, and addition of bio mordants has made the process more calming and eco-friendly.


Assuntos
Nyctaginaceae , Seda , Corantes , Indústria Têxtil , Pós , Extratos Vegetais , Flores
5.
Environ Monit Assess ; 195(1): 14, 2022 Oct 22.
Artigo em Inglês | MEDLINE | ID: mdl-36271209

RESUMO

Being one of the leading industries worldwide, the textile industry has been consuming large quantities of groundwater and discharging huge volumes of dye-contaminated effluents into our aquatic environment. Augmentation of water sources via reuse of treated effluents is therefore highly necessary. In the present study, the decolorization and degradation of synthetic toxic dye from an aqueous solution were investigated through an electro-biological route. Initially, decolorization of synthetic dye solutions (100, 500, and 1000 mg L-1) was carried out by electrooxidation process using mixed metal oxide and titanium as anode and cathode, respectively. The electrooxidation solutions were further treated using bacteria (Pseudomonas aeruginosa) that were isolated from petroleum-transporting pipelines. UV-Vis, TOC, chemical oxygen demand, and NMR analyses revealed that the biodegradation process with electrooxidation enhanced the mineralization of the synthetic dye solutions. An optimum NaCl electrolyte concentration of 3 g L-1 was sufficient to produce reactive species viz., free chlorine and hypochlorite, which are responsible for the Reactive Blue 19 (RB-19) decolorization. Among the three RB-19 concentrations, the highest removal percentage was noticed at 100 mg L-1 (100%) with energy consumption and energy costs equal to 5.44 kWh m-3 and 0.65 USD m-3, respectively.


Assuntos
Fenômenos Biológicos , Petróleo , Corantes/química , Cloro , Titânio/química , Ácido Hipocloroso , Cloreto de Sódio , Monitoramento Ambiental , Indústria Têxtil , Biodegradação Ambiental , Água
6.
Bioresour Technol ; 351: 126861, 2022 May.
Artigo em Inglês | MEDLINE | ID: mdl-35183728

RESUMO

MnP-YC4, a newly constructed manganese peroxidase-producing yeast consortium, has been developed to withstand lignin degradation inhibitors while degrading and detoxifying azo dye. MnP-YC4 tolerance to major biomass-derived inhibitors was promising. MnP induced by lignin was found to be highly related to dye decolorization by MnP-YC4. Simulated azo dye-containing wastewater supplemented with a lignin co-substrate (3,5-Dimethoxy-4-hydroxybenzaldehyde) decolorized up to 100, 91, and 76% at final concentrations of 20, 40, and 60%, respectively. MnP-YC4 effectively decolorized the real textile wastewater sample, reaching up to 91.4%, and the COD value decreased significantly during the decolorization, reaching 7160 mg/l within 7 days. A possible dye biodegradation pathway was proposed based on the degradation products identified by UV-vis, FTIR, GC/MS, and HPLC techniques, beginning with azo bond cleavage and eventually mineralized to CO2 and H2O. When compared to the phytotoxic original dye, the phytotoxicity of MnP-YC4 treated dye-containing wastewater samples confirmed the nontoxic nature.


Assuntos
Compostos Azo , Águas Residuárias , Compostos Azo/metabolismo , Biodegradação Ambiental , Corantes/metabolismo , Lignina , Peroxidases , Saccharomyces cerevisiae/metabolismo , Indústria Têxtil , Têxteis , Águas Residuárias/química
7.
Environ Sci Pollut Res Int ; 29(23): 34974-34983, 2022 May.
Artigo em Inglês | MEDLINE | ID: mdl-35040061

RESUMO

Natural products particularly natural colorants have attained worldwide importance and being eco-friendly can be considered an alternative to toxic dyes in order to reduce environmental pollution. The current study is based on the exploration of natural coloring behavior of bitter gourd leaves extract for cotton dyeing. Colorant was extracted using different extraction media like aqueous, alkali, organic, and acidic at different conditions. It has been found that on application of 50 ml of acidic extract having 6 g/100 ml of table salt for 55 min at 60 C°, maximum color yield has been obtained onto cotton. Upon using chemical and bio-mordants, new shade with good color fastness rating was obtained. FTIR analysis of extract showed the presence of flavonoids. It is concluded that under mild condition, bitter gourd leaves extract can be considered potential source of natural colorant for cotton dyeing and the presence of bio-mordant has made the process more soothing and sustainable in nature.


Assuntos
Corantes , Momordica charantia , Extratos Vegetais , Indústria Têxtil , Têxteis
8.
Artigo em Inglês | MEDLINE | ID: mdl-34769609

RESUMO

BACKGROUND: We conducted a meta-analysis to quantitatively assess the association between asbestos exposure and esophageal cancer. METHODS: We systematically collected articles from three electronic databases and calculated the pooled standardized mortality rate (SMR) from the meta-analysis. Subgroup analysis according to the type of asbestos exposure, follow-up years, sample size, industry classification, sex, and high-dose exposure was conducted. RESULTS: From 242 studies, 34 cohort studies were included in our meta-analysis. Pooled SMR was positively associated with asbestos exposure and esophageal cancer (pooled SMR = 1.28; 95% confidence interval (CI) 1.19-1.38, p < 0.00001). In the subgroup analysis, (1) chrysolite, (2) four groups with follow-up over ten years, (3) the textile industry and shipyard, (4) both male and female, and (5) eight studies on highest asbestos exposure, all the subgroups showed significantly increased pooled SMRs. CONCLUSION: Asbestos exposure was significantly and positively associated with esophageal cancer, especially chrysolite. Considering the long latency period, we suggest that patients should be followed up for cancer, including esophageal cancer, for over ten years.


Assuntos
Amianto , Neoplasias Esofágicas , Neoplasias Pulmonares , Doenças Profissionais , Exposição Ocupacional , Amianto/toxicidade , Estudos de Coortes , Neoplasias Esofágicas/induzido quimicamente , Neoplasias Esofágicas/epidemiologia , Feminino , Humanos , Masculino , Exposição Ocupacional/efeitos adversos , Indústria Têxtil
9.
Water Sci Technol ; 83(9): 2242-2258, 2021 May.
Artigo em Inglês | MEDLINE | ID: mdl-33989190

RESUMO

The existing knowledge on the reactivity of green iron particles on textile dye and wastewater decolorization is very limited. In this study, the potential of green iron particles synthesized using grape leaves extract on reactive dye (reactive red 195, reactive yellow 145, reactive blue 4 and reactive black 5) decolorization were investigated. 95-98% of decolorization was achieved for all reactive dyes at 1.4-2.0 g/L of green iron. Maximum decolorization was attained at lower dye concentration and showed very little impact on decolorization when pH was increased from 3 to 11. The pseudo-first-order fit confirms the reaction between iron particles and dye molecules with rate constant 0.317-0.422 and it is followed by adsorption, data fit with pseudo-second-order model. Hence, not only adsorption but also the reduction process is involved in the reactive dye decolorization. Benzene, phenyl sodium, 2-chloro-1,3,5-triazine, naphthalene, sodium benzene sulfonate, benzene 1,2 di amine, anthracene-9,10 dione, aniline, phenol, benzene sulfonic acid were the major intermediates detected in dye decolorization and the respective reaction pathway is proposed. Green iron from grape leaves extract demonstrated better performance and it is recognized as the promising cost-effective material for textile wastewater treatment.


Assuntos
Nanopartículas , Vitis , Purificação da Água , Compostos Azo , Corantes , Ferro , Extratos Vegetais , Folhas de Planta , Indústria Têxtil , Têxteis
10.
Chemosphere ; 279: 130554, 2021 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-33873067

RESUMO

Desizing process in textile industry produces large volume of starch effluent. This carbon-rich waste can be used for resource recovery, such as the production of industrially useful enzymes. The present work assesses the usability of starch effluent from textile industry as an additional carbon source for enhanced production of α-amylase during solid-state fermentation (SSF) of agro-wastes by Trichoderma reesei. A significant increase (p ≤ 0.05) in α-amylase activity (25.48 ± 1.12 U mL-1) was observed with supplementation of starch effluent in SSF. Partial purification of α-amylase by 80% ammonium sulphate precipitation produced a yield of 58.39% enzyme with purification fold of 1.89. The enzyme was thermally stable at 40 °C with 90% residual activity after 5 h and 70% residual activity at 50 °C after 3 h. Using Michaelis-Menten kinetics analysis, the estimated Km and Vmax values for the partially purified α-amylase were found to be 2.55 mg mL-1 and 53.47 U mg-1, respectively. For the rapid assessment of the industrial application, desizing of the fabric was attempted. The cotton fabric was efficiently desized using α-amylase (at a concentration of 1% on the weight of fabric basis) at 80 °C. The present work demonstrates starch effluent from desizing process as a resource for the production of amylase. The amylase can further be used in the desizing process. With in-depth research, the work may lead to the development of a closed-loop, waste-recycling process for the textile industry.


Assuntos
Amido , alfa-Amilases , Amilases , Suplementos Nutricionais , Hypocreales , Temperatura , Indústria Têxtil
11.
PLoS One ; 16(3): e0247452, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-33651835

RESUMO

The treatability of seven wastewater samples generated by a textile digital printing industry was evaluated by employing 1) anammox-based processes for nitrogen removal 2) microalgae (Chlorella vulgaris) for nutrient uptake and biomass production 3) white-rot fungi (Pleurotus ostreatus and Phanerochaete chrysosporium) for decolorization and laccase activity. The biodegradative potential of each type of organism was determined in batch tests and correlated with the main characteristics of the textile wastewaters through statistical analyses. The maximum specific anammox activity ranged between 0.1 and 0.2 g N g VSS-1 d-1 depending on the sample of wastewater; the photosynthetic efficiency of the microalgae decreased up to 50% during the first 24 hours of contact with the textile wastewaters, but it improved from then on; Pleurotus ostreatus synthetized laccases and removed between 20-62% of the colour after 14 days, while the enzymatic activity of Phanerochaete chrysosporium was inhibited. Overall, the findings suggest that all microbes have great potential for the treatment and valorisation of textile wastewater after tailored adaptation phases. Yet, the depurative efficiency can be probably enhanced by combining the different processes in sequence.


Assuntos
Purificação da Água/métodos , Compostos de Amônio/análise , Compostos de Amônio/química , Compostos de Amônio/metabolismo , Biodegradação Ambiental , Biomassa , Chlorella vulgaris/metabolismo , Resíduos Industriais/análise , Resíduos Industriais/prevenção & controle , Microalgas/metabolismo , Phanerochaete/metabolismo , Pleurotus/metabolismo , Indústria Têxtil/tendências , Águas Residuárias/análise , Águas Residuárias/química
12.
Environ Technol ; 42(21): 3348-3359, 2021 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-32043941

RESUMO

Fabrication, characterization and application of ceramic membrane developed from Tunisian natural kaolin clay for textile wastewater treatment are presented in this study. The morphology and properties of the resulting membrane sintered at 1000°C for 3 h were then determined by Scanning Electron Microscopy (SEM), mechanical and chemical resistance and water permeability. Separation performance of the membrane was evaluated during the treatment of textile wastewater. SEM images reveal the homogeneous surface of the membrane. The membrane displayed good chemical and mechanical resistances as well. Its permeability was of 21.2 L.h -1.m-2.bar-1, indicating that separation performance could occur in the domain of Ultrafiltration (UF). Performances of the membrane during the treatment of raw and biologically pretreated textile effluents are promising in terms of the removal of colour (99% for the raw effluent and 100% for the biologically pretreated effluent), chemical oxygen demand (COD) (80% for the raw effluent and 93% for the biologically pretreated effluent) and turbidity (98% for the raw effluent and 100% for the biologically pretreated effluent).


Assuntos
Poluentes Químicos da Água , Purificação da Água , Cerâmica , Argila , Resíduos Industriais/análise , Caulim , Indústria Têxtil , Têxteis , Eliminação de Resíduos Líquidos , Águas Residuárias , Poluentes Químicos da Água/análise
13.
Environ Sci Pollut Res Int ; 27(26): 32998-33007, 2020 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-32519107

RESUMO

In current years, pollution caused by synthetic dyes has become one of the most serious environmental issues. By rapidly developing industrial units, effluents having synthetic dyes are directly or indirectly being discharged into the environment. Bio-sorption is cost-effective way for the eradication of toxic dyes present in textile effluent. The present study involves the synthesis of nickel nanoparticles using Citrullus colocynthis stem extract. The characterization of synthesized nickel nanoparticles (Ni-NPs) was done by SEM. The synthesized Ni-NPs were used to degrade the Reactive Yellow 160 dye following the optimization of different experimental parameters. The maximum decolorization (91.4%) was obtained at 0.02% dye conc., 9 mg/L conc. of Ni-NPs, pH 7 at 40 °C. TOC and COD were used to assess the efficiency of this experiment. Percent reduction in COD and TOC was found to be 84.35% and 83.24% respectively. The degradation pathway of dye under study confirmed the formation of non-toxic end-products.


Assuntos
Citrullus colocynthis , Nanopartículas , Corantes , Níquel , Extratos Vegetais , Indústria Têxtil
14.
J Environ Manage ; 263: 110383, 2020 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-32174525

RESUMO

Dyes are toxic and inherently resistant to microbial degradation. In this study, decolorization and degradation of textile dye reactive yellow 145 (RY145) were evaluated using pure bacterial strains Pseudomonas aeruginosa (RS1) and Thiosphaera pantotropha ATCC 35512. In nutrient broth under static condition, complete decolorization of 50 mg L-1 RY145 could be achieved within 96 h and 72 h, for Pseudomonas aeruginosa (RS1) and Thiosphaera pantotropha, respectively. In contrast, under shaking condition both the cultures could achieve only 50% decolorization in 96 h. Treatment under sequential static and shaking condition resulted in complete decolorization and 65% mineralization after 96 h. Higher dye concentration in excess of 100 mg L-1 and 50 mg L-1 decreased the extent of dye mineralization in Pseudomonas aeruginosa and Thiosphaera pantotropha, respectively. Even with the repetitive addition of the dye, both the strains were capable of decolorizing the dye. Acclimatized cultures showed 54% decolorization of RY145 in mineral media (MM) even in the absence of a readily degradable external carbon source. Amongst various individual carbon and nitrogen sources, maximum decolorization was observed in MM supplemented with peptone as carbon and nitrogen source at pH 7 under static condition.


Assuntos
Paracoccus pantotrophus , Compostos Azo , Biodegradação Ambiental , Corantes , Pseudomonas aeruginosa , Indústria Têxtil , Têxteis
15.
Crit Rev Biotechnol ; 40(3): 365-379, 2020 May.
Artigo em Inglês | MEDLINE | ID: mdl-31948287

RESUMO

Chitosan, obtained as a result of the deacetylation of chitin, one of the most important naturally occurring polymers, has antimicrobial properties against fungi, and bacteria. It is also useful in other fields, including: food, biomedicine, biotechnology, agriculture, and the pharmaceutical industries. A literature survey shows that its antimicrobial activity depends upon several factors such as: the pH, temperature, molecular weight, ability to chelate metals, degree of deacetylation, source of chitosan, and the type of microorganism involved. This review will focus on the in vitro and in vivo antimicrobial properties of chitosan and its derivatives, along with a discussion on its mechanism of action during the treatment of infectious animal diseases, as well as its importance in food safety. We conclude with a summary of the challenges associated with the uses of chitosan and its derivatives.


Assuntos
Anti-Infecciosos/química , Anti-Infecciosos/farmacologia , Quitina/química , Quitosana/química , Quitosana/farmacologia , Doenças dos Animais/tratamento farmacológico , Animais , Bactérias/efeitos dos fármacos , Biotecnologia , Bovinos , Terapia por Quelação , Indústria Alimentícia , Inocuidade dos Alimentos , Fungos , Concentração de Íons de Hidrogênio , Ostreidae/efeitos dos fármacos , Temperatura , Indústria Têxtil
16.
Crit Rev Food Sci Nutr ; 60(16): 2655-2675, 2020.
Artigo em Inglês | MEDLINE | ID: mdl-31456411

RESUMO

Phenylpropanoids and their derivatives are plant secondary metabolites widely present in fruits, vegetables, cereal grains, beverages, spices and herbs. They are known to have multifaceted effects which include antimicrobial, antioxidant, anti-inflammatory, antidiabetic, anticancer activities and as well as exhibits renoprotective, neuroprotective, cardioprotective and hepatoprotective effects. Owing to their antioxidant, antimicrobial and photoprotective properties, these compounds have wide application in the food (preservation, packaging films and edible coating), pharmaceutical, cosmetic and other industries such as textile (colorant), biofuel (antioxidant additive) and sensors (sensing biologically relevant molecules). Phenylpropanoids are present in commercially available dietary supplements and skin care products. In this review, we have presented the current knowledge on the biosynthesis, occurrence, biological activities of phenylpropanoids and their derivatives, along with the mechanism of action and their potential applications in various industries.


Assuntos
Cosméticos , Indústria Farmacêutica , Indústria Alimentícia , Fenilpropionatos/química , Fenilpropionatos/metabolismo , Indústria Têxtil , Suplementos Nutricionais , Humanos , Fenilpropionatos/farmacologia
17.
Bull Environ Contam Toxicol ; 104(2): 245-252, 2020 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-31858153

RESUMO

Textile effluent treatment methods use biological and chemical treatments to reduce the toxicity and to comply with standard effluent discharge limits. However, trace amounts of pollutants can affect the biological organisms in the receiving environment. The present study used Allium cepa bio assay to assess the cytotoxic and genotoxic effects of treated textile effluents discharged to the natural environment. The results of the bioassay indicated that treated textile effluents can induce alterations in the mitotic index. Also nuclear buds, bi nuclei, condensed nuclei, were recorded in the bioassay and the severity of them decreased towards downstream of the effluent discharge point. Therefore, it can be concluded that even the discharged effluents comply with the standard limits, there is a possibility of causing cytotoxic and genotoxic effects in the organisms living in the natural environment.


Assuntos
Resíduos Industriais/análise , Indústria Têxtil , Poluentes Químicos da Água/toxicidade , Núcleo Celular/efeitos dos fármacos , Dano ao DNA , Monitoramento Ambiental , Mitose/efeitos dos fármacos , Cebolas/citologia , Cebolas/efeitos dos fármacos , Cebolas/genética , Testes de Toxicidade Aguda , Eliminação de Resíduos Líquidos , Poluentes Químicos da Água/análise
18.
PLoS One ; 14(9): e0222146, 2019.
Artigo em Inglês | MEDLINE | ID: mdl-31532804

RESUMO

Cotton gin trash (CGT), a waste product of cotton gins, make up about 10% of each bale of cotton bolls ginned. The current study investigates high value volatile compounds in CGT to add value to this by-product. The volatile compounds in CGT and different parts of the cotton plant were extracted using various methods, identified by gas chromatography-mass spectrometry (GC-MS) or nuclear magnetic resonance (NMR) spectroscopy, and then quantified by gas chromatography-flame ionisation detection (GC-FID) against available standards. Terpenoids including monoterpenoids and sesquiterpenoids were found to be the most abundant, making up 64.66% (area under peak) of total volatiles extracted by hydro-distillation. The major extractable terpenoids in CGT were α-pinene (13.69-23.05 µg/g), ß-caryophyllene (3.99-74.32 µg/g), α-humulene (2.00-25.71 µg/g), caryophyllene oxide (41.50-102.08 µg/g) and ß-bisabolol (40.05-137.32 µg/g). Recoveries varied between different extraction methods. The terpenoids were found to be more abundant in the calyx (659.12 µg/g) and leaves (627.72 µg/g) than in stalks (112.97 µg/g) and stems (24.24 µg/g) of the cotton plant, indicating the possible biological origin of CGT volatiles. This study is the first to identify and quantify the different terpenoids present in CGT and significantly, ß-bisabolol, an abundant compound (sesquiterpene alcohol) which may have valuable biological prospects. These findings therefore contribute to identifying alternative management strategies and uses of CGT.


Assuntos
Gossypium/química , Resíduos Industriais/análise , Terpenos/isolamento & purificação , Fibra de Algodão , Cromatografia Gasosa-Espectrometria de Massas , Espectroscopia de Ressonância Magnética , Extratos Vegetais/química , Extratos Vegetais/isolamento & purificação , Terpenos/química , Indústria Têxtil
19.
Nutrients ; 11(6)2019 Jun 03.
Artigo em Inglês | MEDLINE | ID: mdl-31163648

RESUMO

Eight in ten female readymade garment (RMG) workers in Bangladesh suffer from anemia, a condition which damages both health and productivity. This study evaluated the effectiveness of a workplace nutrition program on anemia reduction in female RMG workers of Bangladesh. A quasi-experimental mixed method study was conducted on 1310 non-pregnant female RMG workers from four factories. Two types of intervention packages (A and C) were tested against their respective controls (B and D) over a 10-month period. Among factories that already provided lunch to workers with regular behavior change counseling (BCC), one intervention (A) and one control (B) factory were selected, and among factories that did not provide lunches to their workers but provided regular BCC, one intervention (C) and one control (D) factory were selected: (A) Lunch meal intervention package: daily nutritionally-enhanced (with fortified rice) hot lunch, once weekly iron-folic acid (IFA) supplement and monthly enhanced (with nutrition module) behavior change counseling (BCC) versus (B) Lunch meal control package: regular lunch and BCC; and (C) Non-meal intervention package: twice-weekly IFA and enhanced BCC versus (D) Non-meal control package: BCC alone. Body weight and capillary hemoglobin were measured. Changes in anemia prevalence were estimated by difference-in-difference (DID) method. Thematic analysis of qualitative in-depth interviews with RMG workers was performed and findings were triangulated. Anemia was reduced significantly in both lunch meal and non-meal intervention (A and C) group (DID: 32 and 12 percentage points, p: <0.001 and <0.05 respectively). The mean hemoglobin concentration also significantly increased by 1 gm/dL and 0.4 gm/dL in both A and C group (p: <0.001 respectively). Weight did not change in the intervention groups (A and C) but significantly increased by more than 1.5 kg in the comparison groups (B and D). The knowledge of different vitamin and mineral containing foods and their benefits was increased significantly among all participants. Workplace nutrition programs can reduce anemia in female RMG workers, with the greatest benefits observed when both nutritionally enhanced lunches and IFA supplements are provided.


Assuntos
Anemia/dietoterapia , Almoço , Estado Nutricional , Serviços de Saúde do Trabalhador , Indústria Têxtil , Anemia/epidemiologia , Anemia/prevenção & controle , Bangladesh/epidemiologia , Vestuário , Suplementos Nutricionais , Feminino , Ácido Fólico/administração & dosagem , Humanos , Ferro/administração & dosagem , Necessidades Nutricionais , Tamanho da Porção , Avaliação de Programas e Projetos de Saúde , Local de Trabalho
20.
Molecules ; 24(3)2019 Feb 11.
Artigo em Inglês | MEDLINE | ID: mdl-30754712

RESUMO

The aqueous extract of dry onion skin waste from the 'Dorata di Parma' cultivar was tested as a new source of biomolecules for the production of colored and biofunctional wool yarns, through environmentally friendly dyeing procedures. Specific attention was paid to the antioxidant and UV protection properties of the resulting textiles. On the basis of spectrophotometric and mass spectrometry analyses, the obtained deep red-brown color was assigned to quercetin and its glycoside derivatives. The Folin⁻Ciocalteu method revealed good phenol uptakes on the wool fiber (higher than 27% for the textile after the first dyeing cycle), with respect to the original total content estimated in the water extract (78.50 ± 2.49 mg equivalent gallic acid/g onion skin). The manufactured materials showed remarkable antioxidant activity and ability to protect human skin against lipid peroxidation following UV radiation: 7.65 ± 1.43 (FRAP assay) and 13.60 (ORAC assay) mg equivalent trolox/g textile; lipid peroxidation inhibition up to 89.37%. This photoprotective and antioxidant activity were therefore ascribed to the polyphenol pool contained in the outer dried gold skins of onion. It is worth noting that citofluorimetric analysis demonstrated that the aqueous extract does not have a significative influence on cell viability, neither is capable of inducing a proapoptotic effect.


Assuntos
Antioxidantes/farmacologia , Cebolas/química , Polifenóis/farmacologia , Protetores contra Radiação/farmacologia , Pele/efeitos dos fármacos , Fibra de Lã/análise , Animais , Antioxidantes/química , Sobrevivência Celular , Ácido Gálico , Glicosídeos/química , Glicosídeos/farmacologia , Humanos , Peroxidação de Lipídeos/efeitos dos fármacos , Peroxidação de Lipídeos/efeitos da radiação , Espectrometria de Massas , Camundongos , Extratos Vegetais/química , Polifenóis/química , Quercetina/análogos & derivados , Quercetina/química , Células RAW 264.7 , Protetores contra Radiação/química , Pele/efeitos da radiação , Espectrofotometria , Indústria Têxtil
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