Synergistic algal/bacterial interaction in membrane bioreactor for detoxification of 1,2-dichloroethane-rich petroleum wastewater.

The study addressed the challenge of treating petroleum industry wastewater with high concentrations of 1,2-dichloroethane (1,2-DCA) ranging from 384 to 1654 mg/L, which poses a challenge for bacterial biodegradation and algal photodegradation. To overcome this, a collaborative approach using membrane bioreactors (MBRs) that combine algae and bacteria was employed. This synergistic method effectively mitigated the toxicity of 1,2-DCA and curbed MBR fouling. Two types of MBRs were tested: one (B-MBR) used bacterial cultures and the other (AB-MBR) incorporated a mix of algal and bacterial cultures. The AB-MBR significantly contributed to 1,2-DCA removal, with algae accounting for over 20% and bacteria for approximately 49.5% of the dechlorination process. 1,2-DCA metabolites, including 2-chloroethanol, 2-chloro-acetaldehyde, 2-chloroacetic acid, and acetic acid, were partially consumed as carbon sources by algae. Operational efficiency peaked at a 12-hour hydraulic retention time (HRT) in AB-MBR, enhancing enzyme activities crucial for 1,2-DCA degradation such as dehydrogenase (DH), alcohol dehydrogenase (ADH), and acetaldehyde dehydrogenase (ALDH). The microbial diversity in AB-MBR surpassed that in B-MBR, with a notable increase in Proteobacteria, Bacteroidota, Planctomycetota, and Verrucomicrobiota. Furthermore, AB-MBR showed a significant rise in the dominance of 1,2-DCA-degrading genus such as Pseudomonas and Acinetobacter. Additionally, algal-degrading phyla (e.g., Nematoda, Rotifera, and Streptophyta) were more prevalent in AB-MBR, substantially reducing the issue of membrane fouling.

New approaches to second-degree burn healing: Polyvinyl alcohol membrane loaded to arnica combined to laser therapy.

Second-degree burns require greater care, as the damage is more extensive and worrisome and the use of a biomaterial can help in the cell repair process, with better planning, low cost, and better accessibility. Arnica has anti-inflammatory and analgesic properties in skin lesions treatments and laser therapy is another therapeutic alternative for burns. Evaluate the effects of arnica incorporated into PVA associated or not with low intensity laser on burns in rats. PVA and PVA with arnica (PVA+A) were obtained and characterized physicochemically. Through in vivo studies, the effects of PVA and PVA+A with or without the application of laser on the lesions allowed histological and immunohistochemical analyzes. PVA+A was biocompatible and with sustained release of the active, being a promising pharmacological tool and confirmed that laser therapy was effective in accelerating the healing process, due to its potential biomodulator, improving inflammatory aspects, promoting rapid healing in skin lesions.

AnCMBR-AFB-integrated process for the treatment of high nitrogen and phosphorus wastewater.

Improving the nitrogen and phosphorus removal rates and efficiently controlling membrane fouling are the keys to fully exploiting the applicability of anaerobic membrane bioreactor (AnMBR) process in high-concentration wastewater treatment. To that purpose, an integrated reactor composed of an anaerobic ceramic membrane bioreactor and N anaerobic fluidized bed (AnCMBR-AFB) was built and pollutant removal efficiency, nitrogen and phosphorus recovery characteristics, and membrane pollution features of this integrated reactor were investigated. The results revealed that the integrated reactor had good pollutant removal efficiency, with turbidity, chromaticity, and UV254 average values of the effluent being 0.470 NTU, 0.011 A, and 0.057 cm-1, respectively, and the average CODCr removal rate was 80%. The nitrogen and phosphorus recoveries were significantly higher than the nitrogen and phosphorus removal rates of conventional AnMBR at 23.20 ± 1.17% and 43.34 ± 1.54%, respectively. Microscopic analysis revealed the formation of magnesium ammonium phosphate (MAP) crystals on the carrier's surface, and friction between the carrier and the membrane surface could delay membrane fouling while allowing the contaminated membrane surface to retain significant roughness. Membrane fouling was mostly brought on by amides and saturated hydrocarbons, and inorganic metal ions also played a role to some extent.

Treatment and recovery of phosphate from submerged anaerobic membrane bioreactor effluent using thermally treated biowaste and powder activated carbon.

This study presents a novel treatment system using a submerged anaerobic membrane bioreactor (SAnMBR) followed by adsorption onto thermally treated biowaste, and ending with a final treatment using powdered activated carbon (PAC). Despite limited phosphate and ammonium ion removal during SAnMBR operation, thermally treated eggshell (EGSL) and seagrass (SG) received SAnMBR effluent and enhanced phosphate recovery, achieving removal rates of 71.8-99.9% and 60.5-78.0%, respectively. The SAnMBR achieved an 85% COD removal, which was slightly reduced further by biowaste treatment. However, significant further reductions in COD to 20.2 ± 5.2 mg/L for EGSL effluent and 57.0 ± 13.3 mg/L for SG effluent were achieved with PAC. Phytotoxicity tests showed the SAnMBR effluent after PAC treatment notably improved seed growth compared to untreated wastewater. In addition, volatile organic compounds (VOCs) were significantly reduced in the system, including common wastewater contaminants such as dimethyl disulfide, dimethyl trisulfide, phenol, p-cresol, nonanal, and decanal. Fractionation analysis of the solid fraction, post-adsorption from both synthetic and domestic wastewater, indicated that for SG, 77.3%-94% of the total phosphorus (TP) was inorganically bound, while for EGSL, it ranged from 94% to 95.3%. This study represents the first attempt at a proof-of-concept for simultaneous treatment of domestic wastewater and phosphorus recovery using this integrated system.

Effect of antibiotics addition on nutrient removal stability and microbial community change of the solar-powered oxidation ditch-membrane bioreactor in treating building wastewater.

The solar-powered oxidation ditch-membrane bioreactors (SOD-MBR) system was developed and operated with long solid retention times (SRTs) of 80 and 160 days. The aim was to investigate the effects of using a long SRT and antibiotics in building wastewater on the stability of nutrient removal, as well as membrane fouling. An increase in the SRT from 80 days to 160 days did not significantly affect the performance of the SOD-MBR system. Ciprofloxacin and Sulfamethoxazole removal efficiencies were 94.47 ± 1.54% and 87.54 ± 24.7%. However, the presence of antibiotics resulted in lower removal efficiencies for NH4+-nitrogen and phosphorus and stimulated the production of extracellular polymeric substances (EPS), particularly proteins in L-EPS and T-EPS of the foulant. FTIR and FEEM analysis revealed that the microbial sludge primarily consisted of proteins, carbohydrates, and lipids. Furthermore, the relative abundance analysis of microbial communities identified bacteria associated with nitrogen removal in the SOD-MBR system, including Anammox, AOB (ammonia oxidizing bacteria), DNB (denitrifying bacteria), and NOB (nitrite oxidizing bacteria), with a total of 25 genera. The majority of these bacteria were stimulated by the presence of antibiotics, resulting in higher relative abundance. Finally, the SOD-MBR system achieved energy savings of 97.38% by utilizing photovoltaic (PV) technology.

CoFe2O4 modified bentonite-based mixed matrix loose nanofiltration membranes for effective wastewater treatment.

Mixed-matrix membranes (MMMs) with an ideal polymer/hydrophilic flux enhancer interface considerably recuperates the separation and purification performance of membrane. In this direction, a novel CoFe2O4 functionalized natural clay-bentonite (CoFe2O4@BT) material as a compatible flux enhancer was synthesized for preparation of mixed matrix based in polyethersulfone (PES) matrix. Here, the influences of CoFe2O4@BT on the morphology and performance of the MMMs membranes were systematically investigated using various analytical techniques. Meanwhile, the water flux and sepration eficiency of the CoFe2O4@BT-PES membranes significantly enhanced due to the incorporation of CoFe2O4@BT that altered hydrophilicity, pore and surface characteristic features. The water flux as well as separation efficiency range up to 95%, 94.69%, 94.16% of Congo red (CR), Crystal violet (CV), and humic acid (HA) respectively. Meanwhile, the fouling parameters demonstrated that the CoFe2O4@BT-PES membranes exhibited better antifouling property in the long term experiment comparing with commercial polyamide membrane. CoFe2O4@BT material incorporated membranes showed less decline ratio and a better recovery ratio. The high rejection of dyes with a high permeation flux of the newly designed membranes indicated an amazing possibility for dye purification. In this study, a potential dye mechanism for composite membranes impacted by synthetic CoFe2O4@BT was also put forth. Within the context of application considerations for environmental protection, new materials stock in membranes show good potential for the separation of different organic contaminants.

Integrating anaerobic acidification with two-stage forward osmosis concentration for simultaneously recovering organic matter, nitrogen and phosphorus from municipal wastewater.

In order to meet the demand of municipal wastewater for low-carbon treatment and resource recovery, a novel process of anaerobic acidification membrane bioreactor (AAMBR) assisted with a two-stage forward osmosis (FO) (FO-AAMBR-FO) was developed for simultaneously recovering organic matter and nutrients from municipal wastewater. The results indicated that the first FO process concentrated the municipal wastewater to one tenth of the initial volume. The corresponding chemical oxygen demand (COD), ammonia nitrogen (NH4+-N) and total phosphorus (TP) concentration reached up to 2800, 200 and 33 mg/L, respectively. Subsequently, the AAMBR was operated at pH value of 10 for treating the concentration of municipal wastewater, in which the organic matter was successfully converted to acetic acid and propionic acid with a total volatile fatty acids (VFAs) concentration of 1787 mg COD/L and a VFAs production efficiency of 62.36 % during 47 days of stable operation. After that, the NH4+-N and TP concentration in the effluent of the AAMBR were further concentrated to 175 and 36.7 mg/L, respectively, by the second FO process. The struvite was successfully recovered with NH4+-N and TP recovery rate of 94.53 % and 98.59 %, respectively. Correspondingly, the VFAs, NH4+-N and TP concentrations in the residual solution were 2905 mg COD/L, 11.8 and 7.92 mg/L, respectively, which could be used as the raw material for the synthesis of polyhydroxyalkanoate (PHA). Results reported here demonstrated that the FO-AAMBR-FO is a promising wastewater treatment technology for simultaneous recovery of organic matter (in form of VFAs) and nutrients (in form of struvite).

Investigation of a membrane bioreactor's performances in treating sunflower oil refinery wastewater containing high oleic acid at different SRTs.

This study investigated the MBR performance, sludge morphology, and membrane fouling potential in treating sunflower oil refinery wastewater containing high oleic acid at three different SRTs of 10 days, 40 days, and infinite. The analysis of mixed liquor morphology including sludge volume index, PSD, EPS, and SMP showed that the sludge flocs compressibility and bioflocculation considerably improved at 40-days SRT. Additionally, at this SRT, the mixed liquor O&G, COD, and SMP accumulation were low, and the microbial activity and COD removal were enhanced. The gas chromatography/mass spectrometry analysis results confirmed the formation of three different new compounds related to non-readily biodegradable recalcitrant oily compounds and SMP at all SRTs. The analysis of mixed liquor EPS, PSD, SMP, and effluent COD at three different SRTs suggests that under the industrial conditions of MBR operation treating SORW with high oleic acid, the optimal operating conditions are predicted to be at 40-days SRT.

An advanced treatment process for 3-high wastewater discharged from crude oil storage tanks.

The wastewater discharged from crude oil storage tanks (WCOST) contains high concentrations of salt and metal iron ions, and high chemical oxygen demand (COD). It belongs to "3-high" wastewater, which is difficult for purification. In this study, WCOST treatments were comparatively investigated via an advanced pretreatment and the traditional coagulation-microfiltration (CMF) processes. After WCOST was purified through the conventional CMF process, fouling occurred in the microfiltration (MF) membrane, which is rather harmful to the following reverse osmosis (RO) membrane unit, and the effluent featured high COD and UV254 values. The analysis confirmed that the MF fouling was due to the oxidation of ferrous ions, and the high COD and UV254 values were mainly attributable to the organic compounds with small molecular sizes, including aromatic-like and fulvic-like compounds. After the pretreatment of the advanced process consisting of aeration, manganese sand filtration, and activated carbon adsorption in combination with CMF process, the removal efficiencies of organic matter and total iron ions reached 97.3% and 99.8%, respectively. All the water indexes of the effluent, after treatment by the advanced multi-unit process, meet well the corresponding standard. The advanced pretreatment process reported herein displayed a great potential for alleviating the MF membrane fouling and enhanced the lifetime of the RO membrane system in the 3-high WCOST treatment.

Ex Vivo Drug Screening Assay with Artificial Membranes: Characterizing Cholesterol Desorbing Competencies of Beta-Cyclodextrins.

Despite advancements in contemporary therapies, cardiovascular disease from atherosclerosis remains a leading cause of mortality worldwide. Supported lipid bilayers (SLBs) are membrane interfaces that can be constructed with varying lipid compositions. Herein, we use a solvent-assisted lipid bilayer (SALB) construction method to build SLB membranes with varying cholesterol compositions to create a lipid-sterol interface atop a piezoelectric sensor. These cholesterol-laden SLBs were utilized to investigate the mechanisms of various cholesterol-lowering drug molecules. Within a flow-cell, membranes with varying cholesterol content were exposed to cyclodextrins 2-hydroxypropyl-beta-cyclodextrin (HPßCD) and methyl-beta-cyclodextrin (MßCD). Quartz-crystal microgravimetry with dissipation monitoring (QCM-D) enabled the collection of in vitro, real-time changes in relative areal mass and dissipation. We define the cholesterol desorbing competency of a cyclodextrin species via measures of the rate of cholesterol removal, the rate of the transfer of membrane-bound cholesterol to drug-complexed cholesterol, and the binding strength of the drug to the cholesterol-ladened membrane. Desorption data revealed distinct cholesterol removal kinetics for each cyclodextrin while also supporting a model for the lipid-cholesterol-drug interface. We report that MßCD removes a quantity of cholesterol 1.61 times greater, with a speed 2.12 times greater, binding affinity to DOPC lipid interfaces 1.97 times greater, and rate of internal cholesterol transfer 3.41 times greater than HPßCD.

High-efficiency cleaning technology and lifespan prediction for the ceramic membrane treating secondary treated effluent.

Chemical cleaning is one of the key technical means to control membrane fouling, restore membrane flux and ensure the stable operation of membrane systems. In the experiment, the six most representative chemical cleaning agents for ceramic membranes, such as sulfuric acid (H2SO4), sodium hydroxide (NaOH), sodium hypochlorite (NaClO), ethylenediaminetetraacetic acid disodium salt (EDTA-Na2), sodium dodecyl sulfate (SDS) and nonylphenol polyoxyethylene ether (OP-10), were used as research objects. The cleaning effect of the two-step combined cleaning of chemical cleaning agents on the fouled membrane was systematically investigated. Results showed that the order of the chemical cleaning agent had a significant effect on the cleaning effect. The best chemical cleaning program was determined to be NaClO first and then SDS: the fouled ceramic membrane was soaked in NaClO solution at 0.15% for 2.5 h and further soaked in SDS solution at five times its own critical micelle concentration for 2.5 h. The predicted long-term lifespan of the ceramic membranes was 4.91 years. Scanning electron microscopy-energy spectrum analysis showed that the surface roughness of the cleaned ceramic membrane was slightly higher than that of the new membrane. The contact angle was slightly lower than that of the new membrane.

A Tale of Two Foulants: The Coupling of Organic Fouling and Mineral Scaling in Membrane Desalination.

Membrane desalination that enables the harvesting of purified water from unconventional sources such as seawater, brackish groundwater, and wastewater has become indispensable to ensure sustainable freshwater supply in the context of a changing climate. However, the efficiency of membrane desalination is greatly constrained by organic fouling and mineral scaling. Although extensive studies have focused on understanding membrane fouling or scaling separately, organic foulants commonly coexist with inorganic scalants in the feedwaters of membrane desalination. Compared to individual fouling or scaling, combined fouling and scaling often exhibits different behaviors and is governed by foulant-scalant interactions, resembling more complex but practical scenarios than using feedwaters containing only organic foulants or inorganic scalants. In this critical review, we first summarize the performance of membrane desalination under combined fouling and scaling, involving mineral scales formed via both crystallization and polymerization. We then provide the state-of-the-art knowledge and characterization techniques pertaining to the molecular interactions between organic foulants and inorganic scalants, which alter the kinetics and thermodynamics of mineral nucleation as well as the deposition of mineral scales onto membrane surfaces. We further review the current efforts of mitigating combined fouling and scaling via membrane materials development and pretreatment. Finally, we provide prospects for future research needs that guide the design of more effective control strategies for combined fouling and scaling to improve the efficiency and resilience of membrane desalination for the treatment of feedwaters with complex compositions.

Performance and resilience of the PolyCera® Titan membrane for industrial wastewater treatment.

This research aims to evaluate the performance of PolyCera® Titan membrane for different wastewater treatment. Membrane filtration of several cycles was conducted in understanding the fouling mechanism, fouling propensity, and defouling potential of the PolyCera® Titan which had not been studied by any other researcher before. The PolyCera® Titan membrane is effective for the treatment of textile industry wastewater, palm oil mill effluent (POME), leachate, and semiconductor-industry wastewater. Rejection of methylene blue (MB) and Congo red (CR) was in the range of 78.76-86.04% and 88.89-93.71%, respectively; 94.72-96.50% NaCl, 96.07-97.62% kaolin, and 97.26-97.73% glucose were rejected from synthetic leachate indicating the removal of TDS, TSS, and COD from the leachate, respectively. Standard blocking and complete model were the best models used to explain the PolyCera® Titan membrane fouling mechanism in all types of wastewater treatment processes with a high R2 value. Physical cleaning with the use of distilled water was able to recover the permeate flux with the flux recovery ratio (FRR) value in the range of 79.2-95.22% in the first cycle, 81.20-98.16% in the second cycle, and 86.09-95.96% in the third cycle.

Next-generation ultrafiltration membranes: A review of material design, properties, recent progress, and challenges.

Membrane technology utilizing ultrafiltration (UF) processes has emerged as the most widely used and cost-effective simple process in many industrial applications. The industries like textiles and petroleum refining are promptly required membrane based UF processes to alleviate the potential environmental threat caused by the generation of various wastewater. At the same time, major limitations such as material selection as well as fouling behavior challenge the overall performance of UF membranes, particularly in wastewater treatment. Therefore, a complete discussion on material design with structural property relation and separation performance of UF membranes is always exciting. This state-of-the-art review has exclusively focused on the development of UF membranes, the material design, properties, progress in separation processes, and critical challenges. So far, most of the review articles have examined the UF membrane processes through a selected track of paving typical materials and their limited applications. In contrast, in this review, we have exclusively aimed at comprehensive research from material selection and fabrication methods to all the possible applications of UF membranes, giving more attention and theoretical understanding to the complete development of high-performance UF systems. We have discussed the methodical engineering behind the development of UF membranes regardless of their materials and fabrication mechanisms. Identifying the utility of UF membrane systems in various applications, as well as their mode of separation processes, has been well discussed. Overall, the current review conveys the knowledge of the present-day significance of UF membranes together with their future prospective opportunities whilst overcoming known difficulties in many potential applications.

An efficient and simple strategy for fabricating a polypyrrole decorated ceramic-polymeric porous membrane for purification of a variety of oily wastewater streams.

A ceramic-polymeric membrane was fabricated through in-situ oxidative polymerization of pyrrole (Py) on alumina (Al2O3) ceramic ultrafiltration support. The establishment of polypyrrole (PPy) active layer on the ceramic support led to a new PPy coated ceramic-polymeric membrane. Various salient features such as surface wettability, surface morphology, composition and functional goups of PPy coated ceramic-polymeric membrane were determined by various characterization techniques water contact angle (WCA), scanning electron microscopy (SEM), energy dispersive x-ray (EDX) analysis and attenuated total reflectance fourier transform infrared (ATR-FTIR). The PPy coated ceramic-polymeric membrane showed superhydrophilic nature owing to its under water oil contact angle of ≥160° (superoleophobic). Thanks to stable deposition of PPy active layer on ceramic support, the membrane retained a separation efficiency of >99% for O/W emulsions at varied transmembrane pressures ranging from 0.5 bar to 2 bar with a feed concentration of 125 ppm of oil in water. Moreover, the PPy coated ceramic-polymeric membrane exhibited an ideal behaviour to the applied transmembrane pressure with a linear increase from 380 LMH to 2112 LMH in permeate flux as the pressure increased from 0.5 bar to 2 bar. As the concentration of oil was raised from 50 ppm to 250 ppm, the separation efficeincy separation remained at >99%. From among the different types of oils (Motor oil, Diesel oil and Crude oil) to mimic the oily waste water streams, the permeate flux was found to be highest in case of motor oil with a value reaching to 1690 LMH at 1 bar. The stability test revealed that the PPy coated ceramic-polymeric membrane was able to separate >99% of 125 ppm O/W surfactant stabilized emulsion for a period of 420 min.

Influence of operation modes on gravity-driven membrane process in treating the secondary effluent: Flux improvement and biocake layer property.

A low flux level of the gravity-driven membrane (GDM) process constrained its extensive application in treating the secondary effluent. In this study, different operation modes were introduced to the GDM process without aeration, backwashing, and chemical cleanings, hoping to develop simple and economic flux regulating strategies, and their influences on the filtration performances and biocake layer characteristics were systematically investigated. The results indicated that the stable fluxs in the intermittent GDM systems elevated by 40%-100% relative to the continuous GDM case, attributing to the synergetic effects of forming more permeable, mushroom-like structures and reducing the concentrations of EPS and SMP within biocake layers. The quantitative analysis of biocake layer properties suggested that the structural parameters of porosity and absolute roughness were closely related to the flux variation compared to the thickness and relative roughness. Besides, the intermittent GDM system generated an apparent detachment of the biocake layer from the membrane surface along with a persistent flux increase than in the continuous GDM case during long-term filtration, achieving its self-sustained operation in a higher flux level without any interferences. The periodical flux recovery and decline occurred daily in each intermittent GDM system since the biocake layer attached to the membrane surface was mainly reversible. Although there were no significant differences in removing dissolved organic pollutants under different operation modes, the manganese removals decreased by 0%-25% in the intermittent GDM filtrations compared to the continuous GDM scenario. The optimized daily operation mode was 16 h on / 8 h off (operation of 16 h, interruption of 8 h), considering the trade-off effects between membrane flux level and water production. These findings provide a new simply-feasible optimized GDM process operation strategy and benefit promoting the application of the GDM system in the reclamation of wastewater.

Molecular-level insights into the mitigation of magnesium-natural organic matter induced ultrafiltration membrane fouling by high-dose calcium based on DFT calculation.

While magnesium cation (Mg2+) universally coexists with natural organic matter (NOM) in the water environment, influence of Mg2+ on NOM fouling in membrane filtration process is still unclear. This work was therefore performed to investigate effects of Mg2+ on NOM (sodium alginate (SA) as a model substance) fouling and role of Ca2+ in mitigating fouling from Mg2+ in the ultrafiltration (UF) water treatment process. Filtration tests showed two interesting fouling phenomena: (1) membrane fouling caused by combination of Mg2+ and SA maintained at a high value with the increased Mg2+ concentration; (2) the high fouling property of Mg2+ can be significantly improved by the prominent addition of calcium cation (Ca2+). It was found that changes of foulant morphology played essential roles through thermodynamic mechanisms represented by the Flory-Huggins lattice theory. Density functional theory (DFT) calculation showed that the combination of SA and Mg2+ tends to coordinate two terminal carboxyl groups in SA, beneficial to stretching alginate chains and forming a stable gel network at low doses. In addition, intramolecular coordination is difficult to occur between SA and Mg2+ due to the high hydration repulsion radius of Mg2+. Therefore, a dense and thick gel network remained even under high Mg2+concentration. Furthermore, due to the higher binding affinity of Ca2+ over Mg2+, high doses of Ca2+ trigger a transition of the stable SA-Mg2+ gel network to other configurations where flocculation and aggregation occur, thereby reducing the specific filtration resistance. The proposed thermodynamic mechanism satisfactorily explained the above interesting fouling behaviors, facilitating to development of new solutions to control membrane fouling.

Self-Assembled CMC/UiO-66-NH2 Membrane with Anti-Crude Oil Adhesion Property for Highly Efficient Oil-Water Separation.

Developing the high-anti-fouling membrane has kept continuous attention in oil/water emulsion treatment. However, the majority of works on anti-fouling membranes mainly focused on low-viscosity oils, which greatly limited the development and application of a membrane to face the real crude oil wastewater. Inspired by the hydrophilicity of sodium carboxymethyl cellulose (CMC) and zirconium base metal-organic frame (Zr-MOF), an anti-oil-fouling CMC/UiO-66-NH2 composite membrane was constructed by a self-assembly method. Profiting from the hydrophilicity and micro-nanostructure of the CMC/UiO-66-NH2 layer, the obtained CMC/UiO-66-NH2 membranes displayed underwater superoleophobicity and desired oil resistance. It could display the effective separation capability with 1282 ± 62 to 6160 ± 81 L/(m2·h·bar) and above 99.08% toward the different light oil emulsions. More importantly, the CMC/UiO-66-NH2 membrane displayed ultralow crude oil adhesion behaviors toward the crude oil emulsions, which could achieve a considerably high flux (746 ± 60 to 5224 ± 87 L/(m2·h·bar)). Furthermore, electrostatic interaction and physical enwinding-wrapping between CMC and UiO-66-NH2 also endowed the composite membranes with outstanding stability. After immersing the as-prepared membranes into the harsh environments for 24 h, the membranes still maintained high underwater-oil contact angles (UWOCA > 155°) and separation ability (oil rejection was above 99.0%). Therefore, CMC/UiO-66-NH2 composite membranes could demonstrate promising prospects in real oily emulsion treatment.

A membrane-based green and low-cost system for ensuring safe drinking water in a selenium-affected region.

Towards an efficient, low-cost solution to the problem of contamination of groundwater by selenium leached out from earth's mineral crust, a new system is developed using a novel graphene-based nanocomposite membrane. The system not only purified selenium-contaminated groundwater with high degree but also ensured safe disposal of the rejected selenium through algorithmic chemical stabilization in a mineral matrix. All experiments were conducted with live contaminated water from selenium affected area rather than using synthetic solution in a semi-pilot unit involving a largely fouling-free flat sheet cross-flow membrane module. Pure water flux of up to 190 Lm-2h-1(LMH) with 96-97% selenium rejection at an optimum operating pressure of only 14 bar could be achieved. Rejected selenium was stabilized in mineral matrix through chemical coagulation-precipitation using suitable coagulants following prior optimization of the critical operating parameters by Model-based calibration toolbox (MATLAB R2020a). A high degree of stabilization efficiency (99.8%) could be achieved as reflected in an error-index of only 1.13%. For selenium-affected region, the membrane-integrated hybrid treatment system proved to be a potential candidate technology offering safe drinking water at an approximate cost of only 1.77 $/m3 which was found to be affordable to the consumers in subsequent willingness to pay survey.

Progress in alumina ceramic membranes for water purification: Status and prospects.

Ceramic membranes have gained increasing attention in recent years for the removal of various contaminants from water. Alumina membrane is considered as one of the most important ceramic membranes, which plays important roles not only in separation processes such as microfiltration, ultrafiltration, and nanofiltration, but also in catalysis- and adsorption- enhanced separation applications in water purification and wastewater treatment. However, there is currently still lack of a comprehensive critical review about alumina membranes for water purification. In this review, we first discuss recent developments of alumina membranes, and then critically introduce the state-of-the-art strategies for lowering fabrication cost, improving membrane performances and mitigating membrane fouling. Especially, aiming to improve membrane performance, some emerging methods are summarized such as tailoring membrane structure, developing flexible membranes, designing nano-pores for precise separation, and enhancing multi-functionalities. In addition, engineering applications of alumina membranes for water purification are also briefly introduced. Finally, the prospects for future research on alumina membranes are proposed, such as economic preparation/application, challenging precise separation, enriching multi-functionalities, and clarifying separation mechanisms.