High-potential reversible Li deintercalation in a substituted tetrahydroxy-p-benzoquinone dilithium salt: an experimental and theoretical study.

Efficient organic Li-ion batteries require air-stable lithiated organic structures that can reversibly deintercalate Li at sufficiently high potentials. To date, most of the cathode materials reported in the literature are typically synthesized in their fully oxidized form, which restricts the operating potential of such materials and requires use of an anode material in its lithiated state. Reduced forms of quinonic structures could represent examples of lithiated organic-based cathodes that can deintercalate Li(+) at potentials higher than 3 V thanks to substituent effects. Having previously recognized the unique electrochemical properties of the C(6)O(6)-type ring, we have now designed and then elaborated, through a simple three-step method, lithiated 3,6-dihydroxy-2,5-dimethoxy-p-benzoquinone, a new redox amphoteric system derived from the tetralithium salt of tetrahydroxy-p-benzoquinone. Electrochemical investigations revealed that such an air-stable salt can reversibly deintercalate one Li(+) ion on charging with a practical capacity of about 100 mAh g(-1) at about 3 V, albeit with a polarization effect. Better capacity retention was obtained by simply adding an adsorbing additive. A tetrahydrated form of the studied salt was also characterized by XRD and first-principles calculations. Various levels of theory were probed, including DFT with classical functionals (LDA, GGA, PBEsol, revPBE) and models for dispersion corrections to DFT. One of the modified dispersion-corrected DFT schemes, related to a rescaling of both van der Waals radii and s(6) parameter, provides significant improvements to the description of this kind of crystal over other treatments. We then applied this optimized approach to the screening of hypothetical frameworks for the delithiated phases and to search for the anhydrous structure.

MetaSurv: Web-Platform Generator for the Monitoring of Health Indicators and Interactive Geographical Information System.

The control of the transmissible epidemics of diseases requires fast and effective tools for data acquisition, analysis, and information feedback to the actors of health like to general public. We present a tool for the fast creation of platforms of monitoring on Internet allowing the collection and the analysis in real time of the epidemic data of any origin with the dynamic and interactive cartographic representation. A Web-based Geographic Information System (Web-GIS) has been designed for communicable diseases monitoring. The Web-GIS was coupled to a data warehouse and embedded in an n-tier architecture designed as the Multi-Source Information System. It allows to access views of communicable diseases. Thus it is a useful tool for supporting health care decision-making for communicable diseases.This tool is based on the 20 years experiment of the Network Sentinels, with the daily participation of the general practitioners.