RESUMEN
Dilational structures can change in size without changing their shape. Current dilational designs are only suitable for specific shapes or curvatures and often require parts of the structure to move perpendicular to the dilational surface, thereby occupying part of the enclosed volume. Here, we present a general method for creating dilational structures from arbitrary surfaces (2-manifolds with or without boundary), where all motions are tangent to the described surface. The method consists of triangulating the target curved surface and replacing each of the triangular faces by pantograph mechanisms according to a tiling algorithm that avoids collisions between neighboring pantographs. Following this algorithm, any surface can be made to mechanically dilate and could, theoretically, scale from the fully expanded configuration down to a single point. We illustrate the method with three examples of increasing complexity and varying Gaussian curvature.
RESUMEN
We report on a high-frequency electron-paramagnetic-resonance study of the type 1 copper site of pseudoazurin. The spectra fully resolve the contribution of a nearly axial spectrum besides the rhombic spectrum, which unequivocally proves the existence of two conformations of the copper site. Pseudoazurins have been considered from Achromobacter cycloclastes including eight mutants and from Alcaligenes faecalis. The two conformations are virtually the same for all pseudoazurins, but the rhombic/axial population varies largely, between 91/9 and 33/67. These observations are discussed in relation to optical absorption spectra and X-ray diffraction structures. A similar observation for fern plastocyanin from Dryopteris crassirhizoma suggests that dual conformations of type 1 copper sites are more common.