A PAM hydrogel surface-coated hydroponic bamboo evaporator with efficient thermal utilization for solar evaporation.

Solar-driven interfacial water purification emerges as a sustainable technology for seawater desalination and wastewater treatment to address the challenge of water scarcity. Currently, the energy losses via radiation and convection to surrounding environment minimize its energy efficiency. Therefore, it is necessary to develop strategies to minimize the heat losses for efficient water purification. Here, a novel evaporator was developed through the in situ gelation of PAM hydrogel on the surface carbonized hydroponic bamboo (PSC) to promote energy efficiency. The inherent porous and layered network structures of bamboo, in synergy with the functional hydration capacity of PAM hydrogel, facilitated adequate water transportation, while reducing evaporation enthalpy. The PAM hydrogel firmly covered on the photothermal layer surface effectively minimized the radiation and convection heat losses, while further harvesting those thermal energy that would otherwise dissipate into the surrounding environment. The reduced thermal conductivity of PSC served as a thermal insulator as well, obstructing heat transfer to bulk water and thus diminishing conduction losses. Consequently, the rational designed PSC could efficiently convert solar energy to purified water, leading to the evaporation of 2.09 kg m-2 h-1, the energy efficiency of 87.6 % under one sun irradiation, and yielding 9.6 kg m-2 fresh water over 11 h outdoor operation. Moreover, the PSC also performs excellent salt rejection, and long-term stability at outdoor experiment. These results demonstrated high and stable solar evaporation performance could be achieved if turning heat losses into a way of extra energy extraction to further enhance the evaporation performance. This strategy appears to be a promising strategy for effective thermal energy management and practical application.

Enhancement of acetate production in hydrogen-mediated microbial electrosynthesis reactors by addition of silica nanoparticles.

Microbial electrosynthesis (MES) is a promising technology for CO2 fixation and electrical energy storage. Currently, the low current density of MES limits its practical application. The H2-mediated and non-biofilm-driven MES could work under higher current density, but it is difficult to achieve high coulombic efficiency (CE) due to low H2 solubility and poor mass transfer. Here, we proposed to enhance the hydrogen mass transfer by adding silica nanoparticles to the reactor. At pH 7, 35 â„ƒ and 39 A·m- 2 current density, with the addition of 0.3wt% silica nanoparticles, the volumetric mass transfer coefficient (kLa) of H2 in the reactor increased by 32.4% (from 0.37 h- 1 to 0.49 h- 1), thereby increasing the acetate production rate and CE of the reactor by 69.8% and 69.2%, respectively. The titer of acetate in the reactor with silica nanoparticles (18.5 g·L- 1) was 56.9% higher than that of the reactor without silica nanoparticles (11.8 g·L- 1). Moreover, the average acetate production rate of the reactor with silica nanoparticles was up to 2.14 g·L- 1·d- 1 in the stable increment phase, which was much higher than the other reported reactors. These results demonstrated that the addition of silica nanoparticles is an effective approach to enhancing the performance of H2-mediated MES reactors.