RESUMEN
Ultraviolet (UV) detectors based on zinc oxide (ZnO) nanorods (NRs) are ideal materials for UV radiation detection. However, owing to the surface effect of ZnO NRs, their speed of photoresponse and photosensitivity need to be improved. In this study, a UV photodetector was fabricated via electrochemical coating of poly(3,4-propylenedioxythiophene) grafted with functional groups (-OH) on a hydrothermally grown ZnO NRs. For comparison, poly(3,4-propylenedioxythiophene)/ZnO composites were synthesized using the same method. The structure of the composite film was characterized by Fourier transform infrared spectroscopy (FT-IR), UV-visible spectroscopy (UV-vis), X-ray diffraction (XRD), Raman spectroscopy (Raman), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). The effect of the polymer structure on the UV sensing ability of ZnO NRs was evaluated by fabricating a UV detector with a composite material. The structural results indicated that the PProDOT-type conductive polymer and ZnO composites were successfully synthesized. The UV photodetection results showed that the presence of functional groups (-OH) in polymer chains could enhance the responsivity of the material. The response time of the ZnO/PProDOT-OH composite was 15 s shorter than that of the ZnO/PProDOT composite. A rise in photocurrent induced an increase from 2.5 A W-1 to 34.75 A W-1 in the UV photoresponsivity of the ZnO/PProDOT-OH composite, compared with that of the pure ZnO NRs. The external quantum efficiency and detectivity significantly improved, the increases of which were attributed to the coupling of the polymer and ZnO NRs.
RESUMEN
In this study, an electrochemical sensor for dopamine (DA) detection has been developed by a composite of poly(3,4-ethylenedioxyselenophene) (PEDOS) and nitrogen-doped graphene (PEDOS/N-Gr) using an in situ polymerization method. Its structure and properties were then compared with those of the composites of poly(3,4-ethylenedioxythiophene) (PEDOT)/nitrogen-doped graphene (PEDOT/N-Gr), which were prepared by the same methods. FT-IR, Raman, UV-vis, XPS, mapping and SEM investigated the structure and morphology of these composites. These revealed that PEDOS/N-Gr had a higher conjugation degree than PEDOT/N-Gr. The synergetic effect between PEDOS and N-Gr was beneficial for the formation of a homogenous surface coating. The cyclic voltammetry (CV) and differential pulse voltammetry (DPV) methods were conducted for electrochemical detection of DA. Compared with PEDOT/N-Gr, the PEDOS/N-Gr displayed an enhanced sensitivity and electrocatalytic performance for DA detection with linear ranges of 0.008-80 µM (PEDOT/N-Gr: 0.04-70 µM) and limits of detection (LOD) of 0.0066 µM (S/N = 3) (PEDOT/N-Gr: 0.018 µM (S/N = 3)).