Photodegradation of pesticides using compound-specific isotope analysis (CSIA): a review.

Pesticides are commonly applied in agriculture to protect crops from pests, weeds, and harmful pathogens. However, chronic, low-level exposure to pesticides can be toxic to humans. Photochemical degradation of pesticides in water, soil, and other environmental media can alter their environmental fate and toxicity. Compound-specific isotope analysis (CSIA) is an advanced diagnostic tool to quantify the degradation of organic pollutants and provide insight into reaction mechanisms without the need to identify transformation products. CSIA allows for the direct quantification of organic degradation, including pesticides. This review summarizes the recent developments observed in photodegradation studies on different categories of pesticides using CSIA technology. Only seven pesticides have been studied using photodegradation, and these studies have mostly occurred in the last five years. Knowledge gaps in the current literature, as well as potential approaches for CSIA technology for pesticide monitoring, are discussed in this review. Furthermore, the CSIA analytical method is challenged by chemical element types, the accuracy of instrument analysis, reaction conditions, and the stability of degradation products. Finally, future research applications and the operability of this method are also discussed.

Ecological risk assessment of current-use pesticides in an aquatic system of Shanghai, China.

The widespread use of current-use pesticides (CUPs) in modern agriculture has threatened the survival of aquatic organisms. Therefore, the residual levels, spatial distribution, and ecological risk assessment of 18 CUPs are investigated in an aquatic system of Shanghai. The aquatic system focused on a freshwater system that contains particles smaller than 0.45 µm in size, which are easily absorbed by aquatic organisms. The mean values of chlorpyrifos, napropamide, and atrazine were found to be the highest concentration CUPs, and propazine, mevinphos, ametryn, butylate, dichlorvos, ethoprop, and prometryn displayed the most significant positive correlations with each other. The concentration of the ∑18CUPs was higher in the southern areas of Shanghai (generally greater than 100 ng/L), but it was relatively low in the central areas (generally smaller than 75 ng/L). Six important CUPs were identified, and the differences in the concentration contribution rates and contribution amounts among different intensive land-use types were noticeable. The ecological risk in most areas of this aquatic system of Shanghai was high. Chlorpyrifos and butachlor produced the maximum toxic unit (mTU) for daphnid and green algae, respectively, and their toxic unit contribution rates to the entire mixture toxicity were both greater than 50%. This confirms that the mixture toxicity of the CUPs to aquatic organisms in this aquatic system of Shanghai primarily resulted from a few dominant toxic pesticides. However, for each sensitive organism, there will still be a risk contribution of approximately 5%-30% due to other CUPs.