Airflow Triggered Water Film Self-Sculpturing on Femtosecond Laser-Induced Heterogeneously Wetted Micro/Nanostructured Surfaces.

Liquid manipulation is essential for daily life and modern industry, and it is widely used in various fields, including seawater desalination, microfluidic robots, and biomedical engineering. Nevertheless, the current research focuses on the manipulation of individual droplets. There are a few projects for water film management. Here, we proposed a facile method of wind-triggered water film self-sculpturing based on a heterogeneous wettability surface, which is achieved by the femtosecond laser direct writing technology and femtosecond laser deposition. Under the conditions of various airflow velocities and water film thicknesses, three distinct behaviors of the water film were analyzed. As a result, when the water film thickness is lower than 4.9 mm, the self-sculpture process will occur until the whole superhydrophobic surface dewetting. Four potential applications are demonstrated, including encryption, oil containers, reconfigurable patterning, and self-splitting devices. This work provides a new approach for manipulating a water film of fluid control engineering.

Reversible non-volatile electronic switching in a near-room-temperature van der Waals ferromagnet.

Non-volatile phase-change memory devices utilize local heating to toggle between crystalline and amorphous states with distinct electrical properties. Expanding on this kind of switching to two topologically distinct phases requires controlled non-volatile switching between two crystalline phases with distinct symmetries. Here, we report the observation of reversible and non-volatile switching between two stable and closely related crystal structures, with remarkably distinct electronic structures, in the near-room-temperature van der Waals ferromagnet Fe5-δGeTe2. We show that the switching is enabled by the ordering and disordering of Fe site vacancies that results in distinct crystalline symmetries of the two phases, which can be controlled by a thermal annealing and quenching method. The two phases are distinguished by the presence of topological nodal lines due to the preserved global inversion symmetry in the site-disordered phase, flat bands resulting from quantum destructive interference on a bipartite lattice, and broken inversion symmetry in the site-ordered phase.

Recent advances in functional micro/nanomaterials for removal of crude oil via thermal effects.

Crude oil is one of the most widely used energy and industrial raw materials that is crucial to the world economy, and is used to produce various petroleum products. However, crude oil often spills during extraction, transportation and use, causing negative impacts on the environment. Thus, there is a high demand for products to remediate leaked crude oil. Among them, oleophilic and hydrophobic adsorbents can absorb crude oil through thermal effects and are research hotspots. In this review, we first present an overview of wettability theory, the heating principles of various thermal effects, and the theory of reducing crude oil viscosity by heating. Then we discuss adsorbents based on different heating methods including the photothermal effect, Joule heating effect, alternating magnetic field heating effect, and composite heating effect. Preparation methods and oil adsorption performance of adsorbents are summarized. Finally, the advantages and disadvantages of various heating methods are briefly summarized, as well as the prospects for future research.

Multifunctional polyimide-based femtosecond laser micro/nanostructured films with triple Janus properties.

Flexible multifunctional composite films in which opposing surfaces have two or more distinct physical properties are highly applicable for wearable electronic devices, electrical power systems and biomedical engineering. However, fabrication of such "Janus" films can be time consuming, complex or economically not feasible. In this work, Janus polyimide (PI) films were prepared by femtosecond laser direct writing technology, which generated a honeycomb porous structure (HPS) on one side and a lawn-like structure (LLS) on the other. Deposition of silver nanowires (AGNWs) by drop coating on the LLS side (AGNWs@LLS) resulted in a film in which each face possessed highly distinct triple properties. The HPS side was superhydrophobic with a water contact angle (WCA) of ∼153.3° and electrically non-conductive, while the AGNWs@LLS side was superhydrophilic (WCA ∼7.8°) and highly conductive (∼3.8 Ω). Moreover, the AGNWs@LLS face showed ultra-low thermal radiation performance, almost reaching saturation. On a heating table at ∼100 °C, the temperature of the AGNWs@LLS side remained at ∼44.5 °C, while the HPS side exhibited a temperature of ∼93.9 °C. This "triple Janus film" and lasing techniques developed might be useful for designing new materials for the integration and miniaturization of multifunctional electronic equipment.

A Robust Droplet Triboelectric Nanogenerator with Self-Cleaning Ability Achieved by Femtosecond Laser.

A droplet triboelectric nanogenerator (TENG) has great potential for harvesting the high entropy energy in water. Despite extensive research, it still suffers from low average power density, poor long-term stability, and insufficient flexibility. Here, a porous micronanostructured polytetrafluoroethylene (PTFE) with superhydrophobicity and self-cleaning ability, is generated by femtosecond laser direct processing. The droplet TENG with laser treated PTFE (LT-PTFE) dielectric layer (L-DTENG) can reach a higher output compared with the droplet TENG with a PTFE dielectric layer (P-DTENG). L-DTENG also demonstrated good long-term stability, self-cleaning ability, and flexibility, making it suitable for various applications, including those involving dust and sewage pollution, as well as bending and pressing conditions. Furthermore, a simulation of finite element method (FEM) and an equivalent circuit model are established to understand the working mechanism of L-DTENG. This multifunctional device and theoretical research provide a smart strategy to generate electricity in a complex environment and lay a solid foundation for droplet TENG applications on a large scale.

Femtosecond laser-scribed superhydrophilic/superhydrophobic self-splitting patterns for one droplet multi-detection.

Superwettable patterned composite surfaces are being recognized as essential components in the field of precise droplet manipulation. However, developing simple and effective methods for manufacturing such surfaces remains a challenge especially for multi-detection surfaces. Here we present a femtosecond laser-based method to create a superhydrophobic/superhydrophilic (SHB/SHL) self-splitting pattern on a polyimide film to achieve droplet multi-detection. The mechanism behind droplet self-splitting on the SHB/SHL pattern surface is related to the dynamic behaviors of liquid recoiling and spreading. This behavior was affected by two main factors, including the width of the SHB stripe, and the radius of the SHL pattern. When the characteristic width is larger than 0.2, droplets are able to fully self-split. Furthermore, the SHB/SHL pattern can be utilized for alcohol detection and multiple biological tests performed using a single drop of biological fluid. This work provides a facile strategy for precise separation and distribution of microdroplets, and potentially could be applied in fluid recognition, biological screening, and combinatorial analysis.

One Droplet toward Efficient Alcohol Detection Using Femtosecond Laser Textured Micro/Nanostructured Surface with Superwettability.

Alcohol with different concentrations is commonly used in food, industry, and medicine fields all over the world. However, current methods for detecting alcohol concentration are restricted to large sample consumption, additional senergy consuming, or complex operations. Here, inspired by superwettability of lotus leaves, a superhydrophobic and superorganophilic surface is designed on the polydimethylsiloxane (PDMS) for one droplet efficient alcohol detection, which is prepared via femtosecond laser direct writing technology. Meanwhile, the contact angles of droplets with various alcohol concentrations on the laser-treated PDMS (LTP) surface are different. Based on the above characteristic, alcohol concentration through contact angle measurement without any external energy is directly detected, which is simple and efficient. Furthermore, it is worth noting that the LTP surface remains stable wettability after 1000 water-ethanol cycles and 300 days tests in air, indicating strong surface repeatability and stability. Significantly, the LTP surface has a broad potential application in one droplet detecting alcohol concentration, fake or genuine wine, and alcohol molecules. This work provides a new strategy to fabricate a superwetting surface for efficient one droplet alcohol detection.

Magnetically Actuated Superhydrophilic Robot Sphere Fabricated by a Femtosecond Laser for Droplet Steering.

Droplet steering has important applications in biomedical detection, local chemical reactions, liquid collection, and microfluidic control. Presently, droplet steering methods typically require specific paths and can be challenging to operate, involving complex fabrications for the operating systems. Here, we show a magnetically actuated superhydrophilic robot sphere (MSR) based on femtosecond laser direct writing technology for droplet steering. Through femtosecond laser treatment, uniform micro-/nanostructures are constructed on the surface of a MSR. Additionally, the contactless magnetic actuator makes it possible to remotely steer the MSR to transport droplets. After preliminary exploration of the mechanism by which MSR drives the droplet movement, the ability of MSR to control the droplet movement was systematically tested and analyzed. Moreover, the applications of the MSR in complex path liquid collection and transport, three-dimensional space transport, self-cleaning, etc., are further verified. This strategy provides a novel and reliable path for droplet manipulation and broadens its application.

Wetting Ridge-Guided Directional Water Self-Transport.

Directional water self-transport plays a crucial role in diverse applications such as biosensing and water harvesting. Despite extensive progress, current strategies for directional water self-transport are restricted to a short self-driving distance, single function, and complicated fabrication methods. Here, a lubricant-infused heterogeneous superwettability surface (LIHSS) for directional water self-transport is proposed on polyimide (PI) film through femtosecond laser direct writing and lubricant infusion. By tuning the parameters of the femtosecond laser, the wettability of PI film can be transformed into superhydrophobic or superhydrophilic. After trapping water droplets on the superhydrophilic surface and depositing excess lubricant, the asymmetrical wetting ridge drives water droplets by an attractive capillary force on the LIHSS. Notably, the maximum droplet self-driving distance can approach ≈3 mm, which is nearly twice as long as the previously reported strategies for direction water self-transport. Significantly, it is demonstrated that this strategy makes it possible to achieve water self-transport, anti-gravity pumping, and chemical microreaction on a tilted LIHSS. This work provides an efficient method to fabricate a promising platform for realizing directional water self-transport.

Femtosecond Laser Thermal Accumulation-Triggered Micro-/Nanostructures with Patternable and Controllable Wettability Towards Liquid Manipulating.

Versatile liquid manipulating surfaces combining patternable and controllable wettability have recently motivated considerable attention owing to their significant advantages in droplet-solid impacting behaviors, microdroplet self-removal, and liquid-liquid interface reaction applications. However, developing a facile and efficient method to fabricate these versatile surfaces remains an enormous challenge. In this paper, a strategy for the fabrication of liquid manipulating surfaces with patternable and controllable wettability on Polyimide (PI) film based on femtosecond laser thermal accumulation engineering is proposed. Because of its controllable micro-/nanostructures and chemical composition through adjusting the local thermal accumulation, the wettability of PI film can be tuned from superhydrophilicity (~ 3.6°) to superhydrophobicity (~ 151.6°). Furthermore, three diverse surfaces with patternable and heterogeneous wettability were constructed and various applications were successfully realized, including water transport, droplet arrays, and liquid wells. This work may provide a facile strategy for achieving patternable and controllable wettability efficiently and developing multifunctional liquid steering surfaces.

An Efficient Hypergraph Approach to Robust Point Cloud Resampling.

Efficient processing and feature extraction of large-scale point clouds are important in related computer vision and cyber-physical systems. This work investigates point cloud resampling based on hypergraph signal processing (HGSP) to better explore the underlying relationship among different points in the point cloud and to extract contour-enhanced features. Specifically, we design hypergraph spectral filters to capture multilateral interactions among the signal nodes of point clouds and to better preserve their surface outlines. Without the need and the computation to first construct the underlying hypergraph, our low complexity approach directly estimates hypergraph spectrum of point clouds by leveraging hypergraph stationary processes from the observed 3D coordinates. Evaluating the proposed resampling methods with several metrics, our test results validate the high efficacy of hypergraph characterization of point clouds and demonstrate the robustness of hypergraph-based resampling under noisy observations.

Effect of Leifsonia sp. on retardation of uranium in natural soil and its potential mechanisms.

Uranium mining and milling activities for many years resulted in release of uranium into the adjoining soil in varying degrees. Bioremediation approaches (i.e., immobilization via the action of bacteria) resulting in uranium bearing solid is supposed as an economic and clean in-situ approach for the treatment of uranium contaminated sites. This study purposes to determine the immobilization efficiency of uranium in soil by Leifsonia sp. The results demonstrated that cells have a good proliferation ability under the stress of uranium and play a role in retaining uranium in soil. Residual uranium in active Leifsonia-medium group (66%) was higher than that in the controls, which was 31% in the deionised water control, 46% in the Leifsonia group, and 47% in the medium group, respectively. This indicated that Leifsonia sp. facilitates the immobilization efficiency of uranium in soil by converting part of the reducible and oxidizable fraction of uranium into the residual fraction. X-ray photoelectron fitting results showed that tetravalent states uranium existed in the soil samples, which indicated that the hexavalent uranium was converted into tetravalent by cells. This is the first report of effect of Leifsonia sp. on uranium immobilization in soil. The findings implied that Leifsonia sp. could, to some extent, prevent the migration and diffusion of uranium in soil by changing the chemical states into less toxicity and less risky forms.

Correction to: Influence of Leifsonia sp. on U(VI) removal efficiency and the Fe-U precipitates by zero-valent iron.

The original publication of this paper contains a mistake.

Influence on Uranium(VI) migration in soil by iron and manganese salts of humic acid: Mechanism and behavior.

Soil contains large amounts of humic acid (HA), iron ions and manganese ions, all of which affect U(VI) migration in the soil. HA interacts with iron and manganese ions to form HA salts (called HA-Fe and HA-Mn in this paper); however, the effects of HA-Fe and HA-Mn on the migration of U(VI) is not fully understood. In this study, HA-Fe and HA-Mn were compounded by HA interactions with ferric chloride hexahydrate and manganese chloride tetrahydrate, respectively. The influence of HA, HA-Fe and HA-Mn on U(VI) immobilization and migration was investigated by bath adsorption experiments and adsorption-desorption experiments using soil columns. The results showed that the presence of HA, HA-Fe and HA-Mn retarded the migration of U(VI) in soil. Supported by X-ray photoelectron spectroscopy (XPS) and BCR sequential extraction analyses, a plausible explanation for the retardation was that HA-Fe and HA-Mn could reduce hexavalent uranium to stable tetravalent uranium and increase the specific gravity of Fe/Mn oxide-bound uranium and organic/sulfide-bound uranium, which made it difficult for them to longitudinally migrate in soil. Scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), and surface area and pore size analyses indicated that the complex formed between the hydroxyl, amino and carboxyl groups of HA-Fe and U(VI) increased the crystallinity of HA-Fe. The reaction between U(VI) and the hydroxyl, amino, aldehyde, keto and chlorine-containing groups of HA-Mn had no effect on the crystallinity of HA-Mn. Notably, the column desorption experiment found that the U(VI) immobilized in the soil remigrated under the effect of rain leaching, and acid rain promoted uranium remigration better than neutral rain. The findings provide some guidance for the decommissioning disposal of uranium contaminated site and it's risk assessments.

Influence of Leifsonia sp. on U(VI) removal efficiency and the Fe-U precipitates by zero-valent iron.

Zero-valent iron (ZVI) has been widely applied to the remediation of uranium (U)-contaminated water. Notably, indigenous bacteria may possess potential positive or unfavorable influence on the mechanism and stability of Fe-U precipitates. However, the focus of the researches in this field has mainly been on physical and/or chemical aspects. In this study, batch experiments were conducted to explore the effects of an indigenous bacterium (Leifsonia sp.) on Fe-U precipitates and the corresponding removal efficiency by ZVI under different environmental factors. The results showed that the removal rate and capacity of U(VI) was significantly inhibited and decreased by ZVI when the pH increased to near-neutral level (pH = 6~8). However, in the ZVI + Leifsonia sp. coexistence system, the U(VI) removal efficiency were maintained at high levels (over 90%) within the experimental scope (pH = 3~8). This revealed that Leifsonia sp. had a synergistic effect on U(VI) remove by ZVI. According to scanning electron microscope and energy dispersive X-ray detector (SEM-EDX) analysis, dense scaly uranium-phosphate precipitation was observed on ZVI + Leifsonia sp. surface. The X-photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) analysis indicated that Leifsonia sp. facilitated the generation of U(VI)-phosphates precipitates. The X-ray diffraction (XRD) analyses further revealed that new substances, such as (Fe(II)Fe(III)2(PO4)2(OH)2), Fe(II)(UO2)2(PO4)2·8H2O, Fe(II)Fe(III)5(PO4)4(OH)2·4H2O, etc., were produced in the coexisting system of ZVI and Leifsonia sp. This study provides new insights on the feasibility and validity of site application of ZVI to U(VI)-contaminated subsurface water in situ. Graphical abstract.

Construction of the Syngonium podophyllum-Pseudomonas sp. XNN8 Symbiotic Purification System and Investigation of Its Capability of Remediating Uranium Wastewater.

The endophyte Pseudomonas sp. XNN8 was separated from Typha orientalis which can secrete indole-3-acetic acid and 1-aminocyclopropane-1-carboxylate deaminase and siderophores and has strong resistance to uranium it was then colonized in the Syngonium podophyllum; and the S. podophyllum-Pseudomonas sp. XNN8 symbiotic purification system (SPPSPS) for uranium-containing wastewater was constructed. Afterwards, the hydroponic experiments to remove uranium from uranium-containing wastewater by the SPPSPS were conducted. After 24 days of treatment, the uranium concentrations of the wastewater samples with uranium concentrations between 0.5 and 5.0 mg/L were lowered to below 0.05 mg/L. Furthermore, the uranium in the plants was assayed using Fourier transform infrared spectroscopy (FTIR) and extended X-ray absorption fine structure (EXAFS) spectroscopy. The Pseudomonas sp. XNN8 was found to generate substantial organic groups in the roots of the Syngonium podophyllum, which could improve the complexing capability of S. podophyllum for uranium. The uranium in the roots of S. podophyllum was found to be the uranyl phosphate (47.4 %) and uranyl acetate (52.6 %).

An artificially constructed Syngonium podophyllum-Aspergillus niger combinate system for removal of uranium from wastewater.

Aspergillus niger was inoculated to the roots of five plants, and the Syngonium podophyllum-A. niger combinate system (SPANCS) was found to be the most effective in removing uranium from hydroponic liquid with initial uranium concentration of 5 mg L(-1). Furthermore, the hydroponic experiments on the removal of uranium from the hydroponic liquids with initial uranium concentrations of 0.5, 1.0, and 3.0 mg L(-1) by the SPANCS were conducted, the inhibitory effect of A. niger on the growth of S. podophyllum in the SPANCS was studied, the accumulation characteristics of uranium by S. podophyllum in the SPANCS were analyzed, and the Fourier transform infrared (FT-IR) and extended X-ray absorption fine structure (EXAFS) spectra were measured. The results show that the removal of uranium by the SPANCS from the hydroponic liquids with initial uranium concentrations of 0.5, 1.0, and 3.0 mg L(-1) reached 98.20, 97.90, and 98.50%, respectively, after 37 days of accumulation of uranium; that the uranium concentrations in the hydroponic liquids decreased to 0.009, 0.021, and 0.045 mg L(-1), respectively, which are lower than the stipulated concentration for discharge of 0.050 mg L(-1) by the People's Republic of China; that A. niger helped to generate more groups in the root of S. podophyllum which can improve the complexing capability of S. podophyllum for uranium; and that the uranium accumulated in the root of S. podophyllum was in the form of phosphate uranyl and carboxylic uranyl.