RESUMEN
We propose a novel design of hollow-core fiber for enhanced light guidance in the mid-infrared. The structure combines an arrangement of non-touching antiresonant elements in the air core with a multilayer glass/polymer structure in the fiber's cladding. Through numerical modeling, we demonstrate that the combination of antiresonant/inhibited-coupling and photonic bandgap guidance mechanisms can decrease the optical loss of a tubular antiresonant fiber by more than one order of magnitude. More specifically, our simulations demonstrate losses of the HE11 mode in the few dB/km level, which can be tuned through mid-infrared wavelengths (5 µm-10.6 µm) by carefully optimizing the structural parameters of both structures. We also show that the hybrid hollow-core fiber design is more robust to bend-induced loss than an equivalent tubular antiresonant fiber or a Bragg/OmniGuide fiber. As a result, if successfully fabricated, the hybrid hollow-core fiber will offer low-loss, high beam-quality, effectively single-mode operation, and low bending losses, potentially solving many of the problems that affect all known mid-infrared fiber types.
RESUMEN
We describe the fabrication of metamaterial magnifying hyperlenses with subwavelength wire array structures for operation in the mid-infrared (around 3 µm). The metadevices are composed of approximately 500 tin wires embedded in soda-lime glass, where the metallic wires vary in diameter from 500 nm to 1.2 µm along the tapered structure. The modeling of the hyperlenses indicates that the expected overall losses for the high spatial frequency modes in such metadevices are between 20 dB to 45 dB, depending on the structural parameters selected, being promising candidates for far-field subdiffraction imaging in the mid-infrared. Initial far-field subdiffraction imaging attempts are described, and the problems encountered discussed.
RESUMEN
We demonstrate in this paper thermal poling of multi-wire array fibers, which extends poling of fibers with two anodes to ~50 and ~500 wire array anodes. The second harmonic microscopy observations show that second order nonlinearity (SON) layers are developed surrounding all the rings of wires in the ~50 anode array fiber with poling of 1.8kV, 250°C and 30min duration, and the outer rings of the ~500 anode array fiber at lower poling temperature. Our simulations based on a two-dimensional charge dynamics model confirm this can be explained by the self-adjustment mechanism, and show the SON layers are induced from the outer rings to the inner rings.
RESUMEN
Characterization of slow chemical reactions is essential for assessing catalytic efficiency in chemistry and biology. Traditionally, chemical reaction rates are obtained from population relaxation kinetics measurements and the Arrhenius equation. Unfortunately, it is difficult to use this approach to characterize reactions wherein concentrations change slowly. Thus, it is interesting to see whether a dynamical view of chemical reactions may be used to obtain the reaction rates of slow processes. In the present work, we perform Brownian dynamics simulations of an asymmetric double-well potential to investigate how enhanced sampling of barrier crossing at transition states improves the characterization of reaction rate constants. We then present the design of a liquid-filled capillary optical fiber-based fluorescence spectrometer, which, like rare events, is also based on Poissonian statistics. We use the instrument to characterize the slow photochemical degradation kinetics of poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) in o-dichlorobenzene. We have employed in situ optical microscopy measurements and electrodynamics simulations to characterize the excitation beam profile inside a liquid-filled capillary fiber. We compare the cuvette and capillary fiber sample holders and show that the MEH-PPV fluorescence line shape is independent of the sample holder, as expected. We characterize the photochemical degradation kinetics of MEH-PPV in o-dichlorobenzene solutions placed in the cuvette versus that in the capillary fiber. We observe small and slow changes in the time-dependent fluorescence spectra when the degradation reaction is performed in the cuvette. On the other hand, we are able to characterize reactant-concentration decay and product-concentration buildup from the time-dependent fluorescence spectra recorded during photochemical degradation of MEH-PPV performed inside the capillary optical fiber. Ultrafast optically heterodyne-detected optical Kerr effect spectroscopy and multimode Brownian oscillator analysis provide further insights into the role of bath oscillator modes of friction in the mechanism of MEH-PPV photochemical degradation. Overall, the work presented herein shows that slow photochemical degradation kinetics of MEH-PPV can be successfully and efficiently assessed in the capillary fiber fluorescence spectrometer.
RESUMEN
We analyze the dependence of the electromagnetic properties of wire array metamaterial media on the choice of metal, and identify promising material combinations for use in the near and mid infrared. We propose a figure of merit for the metal optical quality and consider it as a function of several parameters, such as material loss, wavelength of operation and wire diameter. Accordingly, we select promising material combinations, based on optical quality and fabrication compatibility, and simulate the loss of the quasi-TEM mode, for different wavelengths between 1 and 10 µm. We conclude that wire arrays are unlikely to deliver on their many promises at 1 µm, but should prove useful beyond 3 µm.
RESUMEN
In this paper the development of a side-hole photonic-crystal fiber (SH-PCF) pressure sensor for dual environment monitoring is reported. SH-PCF properties (phase and group birefringence, sensitivity to pressure variations) are measured and compared to simulated data. In order to probe two environments, two sections of the SH-PCF with different lengths are spliced and set in a Solc filter-like configuration. This setup allows obtaining the individual responses of the first and second fiber independently, which is useful for a space-multiplexed measurement. As the employed fiber is sensitive to pressure variations, we report the use of this configuration for dual environment pressure sensing.
RESUMEN
The proposed sensing device relies on the self-imaging effect that occurs in a pure silica multimode fiber (coreless MMF) section of a single-mode-multimode-single-mode (SMS)-based fiber structure. The influence of the coreless-MMF diameter on the external refractive index (RI) variation permitted the sensing head with the lowest MMF diameter (i.e., 55 µm) to exhibit the maximum sensitivity (2800 nm/RIU). This approach also implied an ultrahigh sensitivity of this fiber device to temperature variations in the liquid RI of 1.43: a maximum sensitivity of -1880 pm/°C was indeed attained. Therefore, the results produced were over 100-fold those of the typical value of approximately 13 pm/°C achieved in air using a similar device. Numerical analysis of an evanescent wave absorption sensor was performed, in order to extend the range of liquids with a detectable RI to above 1.43. The suggested model is an SMS fiber device where a polymer coating, with an RI as low as 1.3, is deposited over the coreless MMF; numerical results are presented pertaining to several polymer thicknesses in terms of external RI variation.