Thermally stable gold nanorod dispersed silicone composite with plasmonic resonance in the optical communication window.

Gold nanorods (AuNRs) possess a high optical nonlinear coefficient, ultrafast optical response speed and widely tunable localized surface plasmon resonance (LSPR) wavelength covering the visible and near infrared region. Therefore, they are extensively investigated for many optical applications. However, the poor thermal stability of the AuNRs seriously restricts their practical performance. In addition, for many applications, such as optical communication or laser modulation, AuNRs have to be combined with transparent solids, for example polymers, glass or crystals to make devices. Here, we report on the preparation of 0.23 mg AuNR dispersed methyl silicone resin (MSR) with longitudinal LSPR (L-LSPR) wavelength (1450 nm) in the optical communication window. We found that AuNR-silicone composites possess high thermal stability. After calcination in ambient environment at a temperature of 250 °C for 10 h, the L-LSPR peak of the sample can remain longer than 1380 nm, implying that the NR shape of the Au particles was well maintained. Using the open-aperture Z-scan technique, the nonlinear absorption coefficient of the composites was measured as -11.71 cm GW-1, higher than many nonlinear materials. Thus, the thermally stable AuNR@SiO2-MSR composite with high nonlinearity is promising for practical applications in the optical communication window.

Structural changes and expression of hepatic fibrosis-related proteins in coculture of Echinococcus multilocularis protoscoleces and human hepatic stellate cells.

BACKGROUND: Echinococcus multilocularis is the causative agent of human hepatic alveolar echinococcosis (AE). AE can cause damage to several organs, primarily the liver, and have severe outcomes, such as hepatic failure and encephalopathy. The main purpose of this study was to explore the interactions between hepatic stellate cells (HSCs) and E. multilocularis protoscoleces (PSCs). The results of this study provide an experimental basis for further examination of the pathogenesis of hepatic fibrosis due to AE infection. METHODS: We investigated the role of Echinococcus multilocularis (Echinococcus genus) PSCs in hepatic fibrosis by examining structural changes and measuring hepatic fibrosis-related protein levels in cocultures of PSCs and human HSCs. Structural changes were detected by transmission electron microscopy (TEM), and levels of the hepatic fibrosis-related proteins collagen I (Col-I), alpha-smooth muscle actin (α-SMA) and osteopontin (OPN) were measured by western blotting and enzyme-linked immunosorbent assay (ELISA). RESULTS: Under coculture (1) both PSCs and HSCs exhibited morphological changes, as observed by TEM; (2) Col-I, α-SMA, and OPN expression levels, which were determined by western blotting and ELISA, significantly increased after 3 days of incubation. CONCLUSIONS: The results of this study provide insights into the molecular mechanisms of AE-induced hepatic fibrosis.

A Superstretchable and Ultrastable Liquid Metal-Elastomer Wire for Soft Electronic Devices.

One-dimensional (1D) elastic conductors are an important component for constructing a wide range of soft electronic devices due to their small footprint, light weight, and integration ability. Here, we report the fabrication of an elastic conductive wire by employing a liquid metal (LM) and a porous thermoplastic elastomer (TPE) as building blocks. Such an LM-TPE composite wire was prepared by electrospinning of TPE microfibers and coating of a liquid metal. An additional layer of electrospun TPE microfibers was deposited on the wire for encapsulation. The porous structure of the TPE substrate that is composed of electrospun fibers can substantially improve the stretchability and electrical stability of the composite LM-TPE wire. Compared with the wire using a nonporous TPE as a substrate, the break strain of the LM-TPE wire was increased by 67% (up to ∼2300% strain). Meanwhile, the resistance increase of the wire during 1900% strain of stretching could be controlled as low as 12 times, which is much more stable than that of other LM-based 1D elastic conductors. We demonstrate that a light-emitting diode and an audio playing setup, which use the LM-TPE wire as an electrical circuit, can work with low-intensity attenuation or waveform deformation during large-strain (1000%) stretching. For a proof-of-concept application, an elastic inductance coil was made using the LM-TPE wire as building blocks, and its potential applications in strain sensing and magnetic field detection were demonstrated.

Solvothermal synthesis of octahedral and magnetic CoFe2O4-reduced graphene oxide hybrids and their photo-Fenton-like behavior under visible-light irradiation.

We report a facile solvothermal synthesis of novel octahedral CoFe2O4-reduced graphene oxide (RGO) hybrid and pure CoFe2O4 that were used as heterogeneous photo-Fenton catalysts for the degradation of organic dyes in water. We investigated the structures, morphologies and catalytic activity of both the CoFe2O4 nanoparticles and CoFe2O4-RGO hybrids. The morphology of CoFe2O4 nanoparticles displays size-dependent shapes changing from granular (or sheet) to octahedral shapes with the introduction of RGO. Compared with bare CoFe2O4, the octahedral CoFe2O4-RGO hybrids serve as novel bifunctional materials displaying higher saturation magnetization values and excellent heterogeneous activation of H2O2 at nearly neutral pH. The high saturation magnetization (41.98 emu g-1) of CoFe2O4-RGO hybrids aids their separation from the reaction mixture. In addition, the remarkable enhancement in the photo-Fenton activity of the CoFe2O4-RGO hybrids under visible light irradiation was attributed to the graphene/CoFe2O4 heterojunction, which aided the separation of excited electrons and holes. Furthermore, the CoFe2O4-RGO hybrids exhibited better removal efficiency for cationic methylene blue (MB) dye than for anionic methyl orange (MO) dye. Meanwhile, the CoFe2O4-RGO hybrids displayed acceptable photocatalytic stability, and we proposed an activation mechanism of H2O2 by the octahedral CoFe2O4-RGO hybrids.

Permeable Weldable Elastic Fiber Conductors for Wearable Electronics.

Elastic fiber conductors are advantageous for applications in wearable electronics due to their small size, light weight, and excellent integration ability. Here, we report the fabrication of elastic fiber conductors with a three-dimensional (3D) porous structure using electrospun thermoplastic elastomer (TPE) microfibers and silver nanoparticles (AgNPs) as the building blocks. With the 3D porous structure, such a fiber is highly permeable to gases and liquids. As such, the performance of the fiber in many applications of wearable electronics (especially wearable sensors and detectors) can be improved significantly. Benefitting from the excellent processability of TPE and dispersibility of AgNPs, the fiber is highly compatible with thermal and solvent welding. In addition, the fiber also possesses super stretchability, high conductivity, and robust endurance to deformation. As a proof-of-concept application, we demonstrate that a rope-shaped capacitor made by plying one pair of such fibers can detect the volume change of artificial sweat with 17-times higher sensitivity than the capacitor using nonporous fibers as electrodes. We further demonstrate that, by integrating two groups of perpendicularly arranged fibers into a monolithic porous mat, sensitive matrix-addressed monitoring of artificial sweat can be realized.