Visible-Light-Driven C-H Imidation of Arenes and Heteroarenes by a Phosphonium Ylide Organophotoredox Catalyst: Application to C-H Functionalization of Alkenes.

Phosphonium ylide catalysis through an oxidative quenching cycle has been developed for visible-light-driven C-H imidation of arenes and heteroarenes. The present protocol could be applied not only to trihalomethylative lactonization reactions involving trifluoromethyl, trichloromethyl, and tribromomethyl radicals but also to the first example of an organophotoredox-catalyzed imidative lactonization reaction involving a nitrogen-centered electrophilic radical species.

Compact and Lightweight Transradial Electric Prosthesis for Children with Forearm Deficiency.

Children with congenital forearm deficiency have difficulty in daily activities and body balance problem. Since most electric prostheses have been developed for adult amputees, it is necessary to develop a compact and lightweight electric prosthesis for children to manipulate various daily objects. In this paper, we report a compact and lightweight transradial electric prosthesis for children with forearm deficiency. Based on an electric prosthesis termed as Finch for adult amputees, we designed a smaller electric prosthesis by using a compact actuator and a control unit. We downsized the fingers of the Finch without impairing the workability. The total weight of the developed prosthesis was 274 g, which was about 100 g lighter than that of the conventional electric prosthesis for children. The result of upper limb function evaluation using developed prosthesis participated in a child with congenital forearm deficiency demonstrated that the effectiveness of the prosthesis to manipulate daily objects.