RESUMEN
Encouragingly, a lot of research studies have demonstrated that two-dimensional (2D) nanosheets applied as an additive in oils show preferable friction-reducing and wear resistance performance. However, the current issue was that an elusive way could be adopted to probe the structure-activity relationship between the structure and tribological properties of bulk layered materials due to the structural evolution during friction testing. In this study, we studied the structure-activity relationship between the structure and tribological properties of bulk layered materials (graphite, h-BN, WS2, and MoS2) by an in situ four-ball friction tester. The morphological and structural changes of the layered materials after in situ four-ball-milling were detected by a series of characterizations. This study revealed the friction-induced nanostructural evolution behaviors of bulk layered materials by a four-ball mode.
RESUMEN
In this work, we developed a novel approach for few-layer graphene by employing Li+/Na+ co-intercalated exfoliation assisted by ultrasound method. The experiments were conducted under the ultrasonic power of 300 W and the frequency of 40 kHz without the participation of any organic solvent. The effect of Li+/Na+ proportion on the exfoliation of graphite was intensively investigated. The structure and morphology of the as-exfoliated graphene nanosheets (UGN) was determined by a series of characterizations. The results showed that the thicknesses of the as-exfoliated graphene nanosheets were about 2.38-2.56 nm (about 7-8 layers) at the optimal Li+/Na+ ratio. The potential application of the as-exfoliated graphene nanosheets as additive in grease was evaluated by four-ball friction tester. The results demonstrated that the antifriction and antiwear performances of the grease with 0.06 wt% graphene were significantly improved by 21.35% and 30.32% relative to pure grease, respectively. The friction mechanism was proposed by detecting the worn surfaces.