2-Amino-6-chloro-N-methyl-benzamide.

In the title compound, C8H9ClN2O, the dihedral angle between the benzene ring and the methyl-amide substituent is 68.39 (11)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming layers parallel to the ab plane.

2-Amino-N,3-dimethyl-benzamide.

In the title compound, C9H12N2O, the mean plane through the amide group and the benzene ring form a dihedral angle of 33.93 (7)°. An intra-molecular N-H⋯O hydrogen bond is present. In the crystal, mol-ecules are linked by N-H⋯N and N-H⋯O hydrogen bonds, forming double-stranded chains parallel to the b axis.

(4-Bromo-3,5-dimethyl-1H-pyrazol-1-yl)(2,6-difluoro-phen-yl)methanone.

There are two mol-ecules in the asymmetric unit of the title compound, C(12)H(9)BrF(2)N(2)O. They have very similar conformations: the dihedral angles between their pyrazole and benzene ring systems are 78.4 (3) and 78.6 (4)°. In the crystal, weak aromatic π-π stacking [centroid-centroid separation = 3.696 (5) Å] helps to establish the packing.