High efficiency electrochemical separation of uranium(VI) from uranium-containing wastewater by microbial fuel cells with different cathodes.

As an emerging versatile technology for separating uranium from uranium-containing wastewater (UCW), microbial fuel cell (MFC) offers a novel approach to UCW treatment. Its cathode is essential for the treatment of UCW. To thoroughly investigate the efficacy of MFC in treating UCW, investigations were conducted using MFCs with five materials (containing iron sheet (IP), stainless steel mesh (SSM), carbon cloth (CC), carbon brush (CB), and nickel foam (NF)) as cathodes. The results revealed that each MFC system performed differently in terms of carbon source degradation, uranium removal, and electricity production. In terms of carbon source degradation, CB-MFC showed the best performance. The best uranium removal method was NF-MFC, and the best electricity production method was carbon-based cathode MFC. Five MFC systems demonstrated stable performance and consistent difference over five cycles, with CC-MFC outperforming the others. Furthermore, SEM and XPS characterization of the cathode materials before and after the experiment revealed that a significant amount of U(IV) was generated during the uranium removal process, indicating that uranium ions were primarily removed by electrochemical reduction precipitation. This study confirmed that abiotic cathode MFC had a high UCW removal potential and served as a good guideline for obtaining the best cathode for MFC.

Dual Effect of Acetic Acid Efficiently Enhances Sludge-Based Biochar to Recover Uranium From Aqueous Solution.

Excess sludge (ES) treatment and that related to the uranium recovery from uranium-containing wastewater (UCW) are two hot topics in the field of environmental engineering. Sludge-based biochar (SBB) prepared from ES was used to recover uranium from UCW. Excellent effects were achieved when SBB was modified by acetic acid. Compared with SBB, acetic acid-modified SBB (ASBB) has shown three characteristics deserving interest: 1) high sorption efficiency, in which the sorption ratio of U(VI) was increased by as high as 35.0%; 2) fast sorption rate, as the equilibrium could be achieved within 5.0 min; 3) satisfied sorption/desorption behavior; as a matter of fact, the sorption rate of U(VI) could still be maintained at 93.0% during the test cycles. In addition, based on the test conditions and various characterization results, it emerged as a dual effect of acetic acid on the surface of SBB, i.e., to increase the porosity and add (-COOH) groups. It was revealed that U(VI) and -COO- combined in the surface aperture of ASBB via single-dentate coordination. Altogether, a new utilization mode for SBB is here proposed, as a means of efficient uranium sorption from UCW.