Polyvinyl alcohol/PEDOT:PSS with Fe3+/amylopectin enabled highly tough, anti-freezing and healable hydrogels for multifunctional wearable sensors.

In recent years, hydrogel-based flexible sensors have garnered increasing attention in research. Ionic hydrogels, enriched with large amounts of ionic liquids, exhibit electrical conductivity, excellent electrochemical stability, anti-freezing, and antimicrobial properties. However, most ionic hydrogels suffer from poor mechanical properties, limiting their adaptability to more complex application scenarios. Integrating conductive polymers into hydrogels leads to desirable features such as increased specific surface area, soft and biocompatible interfaces, and high electrolyte permeability. In this study, we successfully prepared Fe3+/Ap@PVA/PEDOT double-network hydrogel. Utilizing polyvinyl alcohol (PVA) as the primary matrix, we introduced PEDOT:PSS and FeCl3 to confer conductivity to the hydrogel. The incorporation of amylopectin (Ap) further enhanced mechanical performance. The resulted hydrogel sensor exhibits outstanding mechanical properties, allowing for stretching up to 347 % and withstanding a tensile force of 505 kPa. In addition, it exhibits excellent antifreeze properties (can work at -30 °C), healability, water retention, and high sensitivity to stretching (GF = 4.72 at a 200 % strain ratio), compression (GF = 2.97 at a 12 % compressive ratio), and temperature (TCR = 2.46). These remarkable properties of the hydrogel make it possible in applications such as human motion monitoring, handwriting recognition, and temperature sensing.

The analysis of complete genome sequence and comparative genomics of Vibrio parahaemolyticus LF1113 in Hainan.

Vibrio parahaemolyticus is a Gram-negative, halophilic and polymorphic coccobacillus. It is world-widely distributed and has resulted in great economic losses since its first appearance. In this study, a pathogenic strain was isolated from diseased pearl gentian grouper and identified as V. parahaemolyticus based on the sequencing results of 16S rDNA gene. In order to gain a comprehensive understanding of this isolation, the whole genome sequencing was conducted. Phylogenetic analysis of the complete genomes of 16 Vibrio species showed that LF1113, ATCC17802, ATCC33787, 2210633, FORC 004, and 160807 were the most closely related. Animal experiments demonstrated that the isolated LF1113 strain was pathogenic in a fish model. This study is the first study to describe the complete genome sequence of a V. parahaemolyticus isolate, which infected pearl gentian grouper from an outbreak in a fish factory farm in Hainan. The results will expand our understanding of genetic characteristics, pathogenesis, diagnostics and disease prevention of V. parahaemolyticus, and lay the foundation for further study.

Molecular Heptazine-Triazine Junction over Carbon Nitride Frameworks for Artificial Photosynthesis of Hydrogen Peroxide.

Revealing the photocatalytic mechanism between various junctions and catalytic activities has become a hotspot in photocatalytic systems. Herein, an internal molecular heptazine/triazine (H/T) junction in crystalline carbon nitride (HTCN) is constructed and devoted to selective two-electron oxygen reduction reaction (2e- ORR) for efficient hydrogen peroxide (H2 O2 ) production. In-situ X-ray diffraction spectra under various temperatures authenticate the successful formation of molecular H/T junction in HTCN during the calcining process rather than physically mixing. The increased surface photovoltage and transient photovoltage signals, and the decreased exciton binding energy undoubtably elucidate that an obvious increasement of carrier density and diffusion capability of photogenerated electrons are realized over HTCN. Additionally, the analyses of in situ photoirradiated Kelvin probe force microscopy and femto-second transient absorption spectra reveal the successful construction of the strong internal built-in-electric field and the existence of the majority of long-lived shallow trapped electrons associated with molecular H/T junction over HTCN, respectively. Benefiting from these, the photocatalytic results exhibit an incredible improvement (96.5-fold) for H2 O2 production. This novel work provides a comprehensive understanding of the long-lived reactive charges in molecular H/T junctions for strengthening the driving-force for photocatalytic H2 O2 production, which opens potential applications for enhancing PCN-based photocatalytic redox reactions.

Porous BiVO4/Boron-Doped Diamond Heterojunction Photoanode with Enhanced Photoelectrochemical Activity.

Constructing heterojunction is an attractive strategy for promoting photoelectrochemical (PEC) performance in water splitting and organic pollutant degradation. Herein, a novel porous BiVO4/Boron-doped Diamond (BiVO4/BDD) heterojunction photoanode containing masses of ultra-micro electrodes was successfully fabricated with an n-type BiVO4 film coated on a p-type BDD substrate by magnetron sputtering (MS). The surface structures of BiVO4 could be adjusted by changing the duration of deposition (Td). The morphologies, phase structures, electronic structures, and chemical compositions of the photoanodes were systematically characterized and analyzed. The best PEC activity with the highest current density of 1.8 mA/cm2 at 1.23 VRHE was achieved when Td was 30 min, and the sample showed the highest degradation efficiency towards tetracycline hydrochloride degradation (TCH) as well. The enhanced PEC performance was ascribed to the excellent charge transport efficiency as well as a lower carrier recombination rate, which benefited from the formation of BiVO4/BDD ultra-micro p-n heterojunction photoelectrodes and the porous structures of BiVO4. These novel photoanodes were expected to be employed in the practical PEC applications of energy regeneration and environmental management in the future.

Intrinsic Defects in Polymeric Carbon Nitride for Photocatalysis Applications.

Introducing intrinsic defects in polymeric carbon nitride (PCN) without the addition of exotic atoms have been verified as an available strategy to boost the photocatalytic performance. This minireview focuses on the fundamental classifications and positive roles of intrinsic defects in PCN for photocatalysis applications. The intrinsic defects in PCN are classified into several types, such as nitrogen vacancy, carbon vacancy and derivative functional groups such as cyano, amino and cyanamide groups. The critical roles of these defects on the electronic configuration, charge transfer and surface properties of PCN are also carefully classified and elaborated. Furthermore, the photocatalysis applications of the defective PCN including photocatalytic water splitting, N2 fixation, H2 O2 production, CO2 reduction and NO removal are summarized. In the end, the challenges and opportunities of defect chemistry in PCN for photocatalysis field are presented.

Dual Cocatalysts in TiO2 Photocatalysis.

Semiconductor photocatalysis is recognized as a promising strategy to simultaneously address energy needs and environmental pollution. Titanium dioxide (TiO2 ) has been investigated for such applications due to its low cost, nontoxicity, and high chemical stability. However, pristine TiO2 still suffers from low utilization of visible light and high photogenerated-charge-carrier recombination rate. Recently, TiO2 photocatalysts modified by dual cocatalysts with different functions have attracted much attention due to the extended light absorption, enhanced reactant adsorption, and promoted charge-carrier-separation efficiency granted by various cocatalysts. Recent progress on the component and structural design of dual cocatalysts in TiO2 photocatalysts is summarized. Depending on their components, dual cocatalysts decorated on TiO2 photocatalysts can be divided into the following categories: bimetallic cocatalysts, metal-metal oxide/sulfide cocatalysts, metal-graphene cocatalysts, and metal oxide/sulfide-graphene cocatalysts. Depending on their architecture, they can be categorized into randomly deposited binary cocatalysts, facet-dependent selective-deposition binary cocatalysts, and core-shell structural binary cocatalysts. Concluding perspectives on the challenges and opportunities for the further exploration of dual cocatalyst-modified TiO2 photocatalysts are presented.

TiO2-MnO x-Pt Hybrid Multiheterojunction Film Photocatalyst with Enhanced Photocatalytic CO2-Reduction Activity.

Photocatalytic CO2 conversion into solar fuels has an alluring prospect. However, the rapid recombination of photogenerated electron-hole pairs for TiO2-based photocatalyst hinders its wide application. To alleviate this bottleneck, a ternary hybrid TiO2-MnO x-Pt composite is excogitated. Taking advantage of the surface junction between {001} and {101} facets, MnO x nanosheets and Pt nanoparticles are selectively deposited on each facet by a facile photodeposition method. This design accomplishes the formation of two heterojunctions: p-n junction between MnO x and TiO2 {001} facet and metal-semiconductor junction between Pt and TiO2 {101} facet. Both of them, together with the surface heterojunction between {001} and {101} facets, are contributive to the spatial separation of the photogenerated electron-hole pairs. Thanks to their cooperative and synergistic effect, the as-prepared composite photocatalyst exhibits a promoted yield of CH4 and CH3OH, which is over threefold of pristine TiO2 nanosheets films. The conjecture of the mechanism that selective formation of multijunction structure maximizes the separation and transfer efficiency of photogenerated charge carriers is proved by the photoelectrochemical analysis. This work not only successfully achieves an efficient multijunction photocatalyst by ingenious design but also provides insight into the mechanism of the performance enhancement.

A metabolomic investigation into the effects of temperature on Streptococcus agalactiae from Nile tilapia (Oreochromis niloticus) based on UPLC-MS/MS.

Streptococcosis caused by Streptococcus agalactiae is one of the most serious diseases in farmed tilapia, and temperature is one of the most important environmental factors related to its outbreak. To elucidate the influence of temperature variation on the pathogen from a metabolic perspective, the global metabolomics of 2 pathogenic strains of S. agalactiae from sick tilapia were analyzed at 35°C and 25°C using ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) combined with pattern recognition approaches and pathway analysis. The result showed that the metabolic status of S. agalactiae was extensively affected by its culture temperature. Based on the results of metabolites contributing to these differences, a large number of nucleotides and their ramifications were markedly elevated at 35°C. Various energy substances, components of the cell wall and substances associated with stress regulation such as glyceraldehyde 3-phosphate, pyroglutamic acid, glutamate, d-Alanyl-d-alanine, glycerophosphocholine, dephospho-CoA, and oxidized glutathione increased when the strains were cultured at 35°C. Additionally, a general decrease in various precursors of capsule, antigen, and virulence protein formation were detected including mannose, maltotriose, N-acetyl-d-glucosamine 6-phosphate, uracil, proline, and citrulline. These metabolic changes indicated that metabolic activity decreased, while adaptive ability to environment and pathogenicity to host increased at high temperature. This study is the first to determine the metabolomic responses of S. agalactiae to temperature, and the results are useful to reveal its pathogenic mechanism and find effective disease control.

Hierarchically macro-mesoporous Pt/γ-Al2O3 composite microspheres for efficient formaldehyde oxidation at room temperature.

Room temperature catalytic oxidation by noble metals is considered to be the most promising strategy for the removal of HCHO, which is one of the major indoor air pollutants. Hierarchically macro-mesoporous structured Pt/γ-Al2O3 hollow spheres with open and accessible pores were synthesized and used for catalytic oxidative decomposition of HCHO at room temperature. The prepared composite hollow spheres showed higher catalytic activity than the conventional nanoparticle supports, which is mainly due to their hierarchical macro-mesoporous structure facilitating diffusion of reactants and products, and the high dispersion of accessible catalytic Pt nanoparticles. This work may contribute to the development of hierarchically structured materials and high-performance catalysts for indoor air purification and related catalytic processes.

Characteristics of hemolytic activity induced by skin secretions of the frog Kaloula pulchra hainana

Background: Previous works had shown that scorpion venom induced neurotransmitter elevation and an inflammatory response associated with various anatomo-pathological modifications. The most dangerous scorpions species in Algeria responsible for these effects are Androctonus australis hector (Aah) and Androctonus amoreuxi (Aam). Results: Comparison of the physiopathological effects induced by the two venoms showed differences in the kinetic of cytokine release and in lung injury. The lung edema was only observed in response to Aah venom and it was correlated with cell infiltration. In order to better understand the involved mechanism in inflammatory response, we used two antagonists, atropine (non-selective muscarinic antagonist) and propranolol (ß adrenergic antagonist), which lead to a decrease of cell infiltration but has no effect on edema forming. Conclusion: These results suggest another pathway in the development of lung injury following envenomation with Aam or Aah venom.(AU)

Characteristics of hemolytic activity induced by skin secretions of the frog Kaloula pulchra hainana

The hemolytic activity of skin secretions obtained by stimulating the frog Kaloula pulchra hainana with diethyl ether was tested using human, cattle, rabbit, and chicken erythrocytes. The skin secretions had a significant concentration-dependent hemolytic effect on erythrocytes. The hemolytic activity of the skin secretions was studied in the presence of osmotic protectants (polyethylene glycols and carbohydrates), cations (Mg2+, Ca2+, Ba2+, Cu2+, and K+), or antioxidants (ascorbic acid, reduced glutathione, and cysteine). Results Depending on their molecular mass, osmotic protectants effectively inhibited hemolysis. The inhibition of skin hemolysis was observed after treatment with polyethylene glycols (1000, 3400, and 6000 Da). Among divalent cations, only 1 mM Cu2+ markedly inhibited hemolytic activity. Antioxidant compounds slightly reduced the hemolytic activity. Conclusions The results suggested that skin secretions of K. pulchra hainana induce a pore-forming mechanism to form pores with a diameter of 1.36-2.0 nm rather than causing oxidative damage to the erythrocyte membrane.

Characteristics of hemolytic activity induced by skin secretions of the frog Kaloula pulchra hainana.

BACKGROUND: The hemolytic activity of skin secretions obtained by stimulating the frog Kaloula pulchra hainana with diethyl ether was tested using human, cattle, rabbit, and chicken erythrocytes. The skin secretions had a significant concentration-dependent hemolytic effect on erythrocytes. The hemolytic activity of the skin secretions was studied in the presence of osmotic protectants (polyethylene glycols and carbohydrates), cations (Mg2+, Ca2+, Ba2+, Cu2+, and K+), or antioxidants (ascorbic acid, reduced glutathione, and cysteine). RESULTS: Depending on their molecular mass, osmotic protectants effectively inhibited hemolysis. The inhibition of skin hemolysis was observed after treatment with polyethylene glycols (1000, 3400, and 6000 Da). Among divalent cations, only 1 mM Cu2+ markedly inhibited hemolytic activity. Antioxidant compounds slightly reduced the hemolytic activity. CONCLUSIONS: The results suggested that skin secretions of K. pulchra hainana induce a pore-forming mechanism to form pores with a diameter of 1.36-2.0 nm rather than causing oxidative damage to the erythrocyte membrane.