Improvement of Cs detection performance and formation of CsCl and Cs nanoparticles by tuning graphene oxide quantum dot-based nanocomposite.

A new nanocomposite was developed using functionalized graphene oxide quantum dots (GOQDs) with cesium green molecules for the first time. Although the cesium green molecule works effectively only in the solid-state, without water, and in basic conditions, the functionalized GOQDs with cesium green made the nanocomposite work well as a cesium (Cs) detector in mixed solution (distilled water/THF). The nanocomposite can be employed as a Cs detector in both acidic and basic conditions. The present study revealed that the nanocomposite of GOQDs with cesium green showed an enhanced photoluminescence in basic conditions, while the intensity of the photoluminescence in acidic conditions is the superposition of the photoluminescence of the corresponding components. The photoluminescence of the nanocomposite was quenched (turned OFF) after Cs treatment in basic conditions. On the other hand, in the acidic conditions it was found that the photoluminescence intensity of this nanocomposite was enhanced (turned ON) by the Cs addition in two different Cs concentrations, 0.06 mmol L-1 and 0.12 mmol L-1. In addition, the movement of the nanocomposite (after Cs addition) under the electron beams through TEM measurement was observed. The formation of CsCl and Cs nanoparticles was identified. Specifically, the Cs cluster occurrence is discussed by taking into account the mobility effect of the adatoms on the composite layer under electron beam irradiation.

Exploration of the Cs Trapping Phenomenon by Combining Graphene Oxide with α-K6P2W18O62 as Nanocomposite.

A graphene oxide-based α-K6P2W18O62 (Dawson-type polyoxometalate) nanocomposite was formed by using two types of graphene oxide (GO) samples with different C/O compositions. Herein, based on the interaction of GO, polyoxometalates (POMs), and their nanocomposites with the Cs cation, quantitative data have been provided to explicate the morphology and Cs adsorption character. The morphology of the GO-POM nanocomposites was characterized by using TEM and SEM imaging. These results show that the POM particle successfully interacted above the surface of GO. The imaging also captured many small black spots on the surface of the nanocomposite after Cs adsorption. Furthermore, ICP-AES, the PXRD pattern, IR spectra, and Raman spectra all emphasized that the Cs adsorption occurred. The adsorption occurred by an aggregation process. Furthermore, the difference in the C/O ratio in each GO sample indicated that the ratio has significantly influenced the character of the GO-POM nanocomposite for the Cs adsorption. It was shown that the oxidized zone (sp2/sp3 hybrid carbon) of each nanocomposite sample was enlarged by forming the nanocomposite compared to the corresponding original GO sample. The Cs adsorption performance was also influenced after forming a composite. The present study also exhibited the fact that the sharp and intense diffractions in the PXRD were significantly reduced after the Cs adsorption. The result highlights that the interlayer distance was changed after Cs adsorption in all nanocomposite samples. This has a good correlation with the Raman spectra in which the second-order peaks changed after Cs adsorption.