RESUMEN
Nanomaterials are widely used in many fields for their unique physical and chemical properties and especially demonstrate irreplaceability in energy storage systems. In this paper, a novel composite of copper sulfide with hypha-like core-shell nano-structure is synthesized by in situ phase inversion method, which serves as high stability negative electrode materials of zinc-ion batteries (ZIBs). The unique structure facilitates efficient electron and ion transport, enhances the kinetics of electrochemical reactions, and effectively suppresses the undesired expansion and decomposition of transition metal compounds. As a result, the half battery exhibits high specific capacity (250.2 mAh g-1 at 0.1 A g-1), reliable rate performance, and cycle stability (98.3 mAh g-1 at 1 A g-1 after 500 cycles). Additionally, when assembled with ZnxMnO2 positive to form a full battery, it demonstrates good cycling capacity at an intermediate current density of 2 A g-1, while maintaining excellent structural stability over 5,000 cycles (61% retention).
RESUMEN
The electrolyte-wettability of electrode materials in liquid electrolytes plays a crucial role in electrochemical energy storage, conversion systems, and beyond relied on interface electrochemical process. However, most electrode materials do not have satisfactory electrolyte-wettability for possibly electrochemical reaction. In the last 30 years, there are a lot of literature have directed at exploiting methods to improve electrolyte-wettability of electrodes, understanding basic electrolyte-wettability mechanisms of electrode materials, exploring the effect of electrolyte-wettability on its electrochemical energy storage, conversion, and beyond performance. This review systematically and comprehensively evaluates the effect of electrolyte-wettability on electrochemical energy storage performance of the electrode materials used in supercapacitors, metal ion batteries, and metal-based batteries, electrochemical energy conversion performance of the electrode materials used in fuel cells and electrochemical water splitting systems, as well as capacitive deionization performance of the electrode materials used in capacitive deionization systems. Finally, the challenges in approaches for improving electrolyte-wettability of electrode materials, characterization techniques of electrolyte-wettability, as well as electrolyte-wettability of electrode materials applied in special environment and other electrochemical systems with electrodes and liquid electrolytes, which gives future possible directions for constructing interesting electrolyte-wettability to meet the demand of high electrochemical performance, are also discussed.
RESUMEN
With the development of flexible and wearable electronic devices, it is a new challenge for polymer hydrogel electrolytes to combine high mechanical flexibility and electrochemical performance into one membrane. In general, the high content of water in hydrogel electrolyte membranes always leads to poor mechanical strength, and limits their applications in flexible energy storage devices. In this work, based on the "salting out" phenomenon in Hofmeister effect, a kind of gelatin-based hydrogel electrolyte membrane is fabricated with high mechanical strength and ionic conductivity by soaking pre-gelated gelatin hydrogel in 2 m ZnSO4 aqueous. Among various gelatin-based electrolyte membranes, the gelatin-ZnSO4 electrolyte membrane delivers the "salting out" property of Hofmeister effect, which improves both the mechanical strength and electrochemical performance of gelatin-based electrolyte membranes. The breaking strength reaches 1.5 MPa. When applied to supercapacitors and zinc-ion batteries, it can sustain over 7500 and 9300 cycles for repeated charging and discharging processes. This study provides a very simple and universal method to prepare polymer hydrogel electrolytes with high strength, toughness, and stability, and its applications in flexible energy storage devices provide a new idea for the construction of secure and stable flexible and wearable electronic devices.
RESUMEN
The attapulgite@carbon/NiCo layered double hydroxide nanocomposites based on waste adsorbents are manufactured via simple and eco-friendly calcination and hydrothermal methods, by which they would be considerable electrode materials for advanced supercapacitors. To achieve sustainable development, the spent tetracycline-loaded attapulgite can act as a cost-effective available carbon source as well as a matrix material for carbon species and NiCo layered double hydroxide simultaneously. A controlled amount of attapulgite@carbon could be used to regulate the electrochemical properties of nanocomposites. The generated electrodes possess superior electrochemical properties with a specific capacitance of 2013.8 F g-1 at 0.5 A g-1, a retention rate of 87.7% at 5 A g-1, and a cyclic stability of 64.9% for 4000 cycles at 5 A g-1. Thus, the asymmetric supercapacitor device assembled with attapulgite@carbon/NiCo layered double hydroxide nanocomposites||active carbon shows a maximum capacitance of 231.3 F g-1 at 0.5 A g-1, with a preeminent energy density of 82.2 Wh kg-1 when its power density is 4318 W kg-1. This approach would contribute to the development of supercapacitors in an efficient and effective manner, as well as provide a feasible strategy for solving tetracycline pollution and recycling waste adsorbents to achieve sustainable development.