Recent Increased Loading of Carbonaceous Pollution from Biomass Burning in the Baltic Sea.

Black carbon (BC), spheroidal carbonaceous particles (SCP), and polycyclic aromatic hydrocarbons (PAH) are carbonaceous pollutants affecting the climate, environment, and human health. International regulations limit their emissions, and the present emissions are followed by monitoring programs. However, the monitoring programs have limited spatio-temporal coverage and only span the last decades. We can extend the knowledge of historical emission rates by measuring pollution levels in radiometrically dated marine and lacustrine sediment sequences. Here we present measurements of BC, SCP, and PAH from a sediment sequence sampled in the Öresund strait, between Denmark and Sweden and dated back to CE 1850. Our data show a massive increase in the burial rates of all measured pollutants starting in the 1940s. The pollution deposition peaked in the 1970-1980s and declined through the 1990s. However, the declining trend was reversed in the 2000s. Source appointment of PAHs shows a relatively higher contribution of emissions from wood-burning since CE 2000. This coincides with a change towards the increased use of biomass for both municipal and regional energy production in Scandinavia. Our results demonstrate that changes in energy production have caused changes in the delivery of carbonaceous pollution to marine environments. The increase in particle emissions from wood burning is potentially posing a future environmental and health risk.

Climate- and gateway-driven cooling of Late Eocene to earliest Oligocene sea surface temperatures in the North Sea Basin.

During the late Eocene, the Earth's climate experienced several transient temperature fluctuations including the Vonhof cooling event (C16n.1n; ~35.8 Ma) hitherto known mainly from the southern oceans. Here we reconstruct sea-surface temperatures (SST) and provide δ18O and δ13C foraminiferal records for the late Eocene and earliest Oligocene in the North Sea Basin. Our data reveal two main perturbations: (1), an abrupt brief cooling of ~4.5 °C dated to ~35.8 Ma and synchronous with the Vonhof cooling, which thus may be a global event, and (2) a gradual nearly 10 °C temperature fall starting at 36.1 Ma and culminating near the Eocene-Oligocene transition at ~33.9 Ma. The late Priabonian temperature trend in the North Sea shows some resemblance IODP Site U1404 from the North Atlantic, offshore Newfoundland; and is in contrast to the more abrupt change observed in the deep-sea δ18O records from the southern oceans. The cooling in the North Sea is large compared to the pattern seen in the North Atlantic record. This difference may be influenced by a late Eocene closure of the warm gateways connecting the North Sea with the Atlantic and Tethys oceans.

Reappraisal of hydrocarbon biomarkers in Archean rocks.

Hopanes and steranes found in Archean rocks have been presented as key evidence supporting the early rise of oxygenic photosynthesis and eukaryotes, but the syngeneity of these hydrocarbon biomarkers is controversial. To resolve this debate, we performed a multilaboratory study of new cores from the Pilbara Craton, Australia, that were drilled and sampled using unprecedented hydrocarbon-clean protocols. Hopanes and steranes in rock extracts and hydropyrolysates from these new cores were typically at or below our femtogram detection limit, but when they were detectable, they had total hopane (<37.9 pg per gram of rock) and total sterane (<32.9 pg per gram of rock) concentrations comparable to those measured in blanks and negative control samples. In contrast, hopanes and steranes measured in the exteriors of conventionally drilled and curated rocks of stratigraphic equivalence reach concentrations of 389.5 pg per gram of rock and 1,039 pg per gram of rock, respectively. Polycyclic aromatic hydrocarbons and diamondoids, which exceed blank concentrations, exhibit individual concentrations up to 80 ng per gram of rock in rock extracts and up to 1,000 ng per gram of rock in hydropyrolysates from the ultraclean cores. These results demonstrate that previously studied Archean samples host mixtures of biomarker contaminants and indigenous overmature hydrocarbons. Therefore, existing lipid biomarker evidence cannot be invoked to support the emergence of oxygenic photosynthesis and eukaryotes by ∼ 2.7 billion years ago. Although suitable Proterozoic rocks exist, no currently known Archean strata lie within the appropriate thermal maturity window for syngenetic hydrocarbon biomarker preservation, so future exploration for Archean biomarkers should screen for rocks with milder thermal histories.