1.
Chem Commun (Camb)
; 57(88): 11705-11708, 2021 Nov 04.
Artículo
en Inglés
| MEDLINE
| ID: mdl-34693408
RESUMEN
A series of iridium hydride complexes featuring dihydrogen bonding are presented and shown to undergo rapid H+/H- exchange (1240 s-1 at 25 °C). We demonstrate that the H+/H- exchange rate can be modified by post-synthetic modification at a remote site using BH3, Zn(C6F5)2, and [Me3O][BF4]. This route provides a complementary strategy to traditional methods that rely on pre-metalation modifications to a metal's primary sphere.