Synthesis of 2,3-Dihydrobenzofurans via a Photochemical Gold-Mediated Atom Transfer Radical Addition Reaction.

A light-mediated cyclization reaction initiated by an atom transfer radical addition (ATRA) of haloalkanes onto alkenes was exploited for the synthesis of functionalized dihydrobenzofurans. Initial investigation indicated that the dimeric gold catalyst [Au2(µ-dppm)2Cl2] can effectively be used for intermolecular ATRA reactions. Further, the reactivity was applied in a cascade-like cyclization for the preparation of dihydrobenzofuran derivatives. With the presented photochemical approach, the functionalization can be achieved directly from ortho-allylphenols in yields of up to 96% under mild conditions.

Ultrafast Exciton Dynamics in the Atomically Thin van der Waals Magnet CrSBr.

Among atomically thin semiconductors, CrSBr stands out as both its bulk and monolayer forms host tightly bound, quasi-one-dimensional excitons in a magnetic environment. Despite its pivotal importance for solid-state research, the exciton lifetime has remained unknown. While terahertz polarization probing can directly trace all excitons, independently of interband selection rules, the corresponding large far-field foci substantially exceed the lateral sample dimensions. Here, we combine terahertz polarization spectroscopy with near-field microscopy to reveal a femtosecond decay of paramagnetic excitons in a monolayer of CrSBr, which is 30 times shorter than the bulk lifetime. We unveil low-energy fingerprints of bound and unbound electron-hole pairs in bulk CrSBr and extract the nonequilibrium dielectric function of the monolayer in a model-free manner. Our results demonstrate the first direct access to the ultrafast dielectric response of quasi-one-dimensional excitons in CrSBr, potentially advancing the development of quantum devices based on ultrathin van der Waals magnets.

Mobile Trions in Electrically Tunable 2D Hybrid Perovskites.

2D hybrid perovskites are currently in the spotlight of material research for light-harvesting and -emitting applications. It remains extremely challenging, however, to externally control their optical response due to the difficulties of introducing electrical doping. Here, an approach of interfacing ultrathin sheets of perovskites with few-layer graphene and hexagonal boron nitride into gate-tunable, hybrid heterostructures, is demonstrated. It allows for bipolar, continuous tuning of light emission and absorption in 2D perovskites by electrically injecting carriers to densities as high as 1012  cm-2 . This reveals the emergence of both negatively and positively charged excitons, or trions, with binding energies up to 46 meV, among the highest measured for 2D systems. Trions are shown to dominate light emission and propagate with mobilities reaching 200 cm2 V-1 s-1 at elevated temperatures. The findings introduce the physics of interacting mixtures of optical and electrical excitations to the broad family of 2D inorganic-organic nanostructures. The presented strategy to electrically control the optical response of 2D perovskites highlights it as a promising material platform toward electrically modulated light-emitters, externally guided charged exciton currents, and exciton transistors based on layered, hybrid semiconductors.