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1.
ACS Appl Mater Interfaces ; 16(31): 40313-40325, 2024 Aug 07.
Artículo en Inglés | MEDLINE | ID: mdl-39052020

RESUMEN

Laser-induced graphene (LIG) has been emerging as a promising electrode material for supercapacitors due to its cost-effective and straightforward fabrication approach. However, LIG-based supercapacitors still face challenges with limited capacitance and stability. To overcome these limitations, in this work, we present a novel, cost-effective, and facile fabrication approach by integrating LIG materials with candle-soot nanoparticles. The composite electrode is fabricated by laser irradiation on a Kapton sheet to generate LIG material, followed by spray-coating with candle-soot nanoparticles and annealing. Materials characterization reveals that the annealing process enables a robust connection between the nanoparticles and the LIG materials and enhances nanoparticle graphitization. The prepared supercapacitor yields a maximum specific capacitance of 15.1 mF/cm2 at 0.1 mA/cm2, with a maximum energy density of 2.1 µWh/cm2 and a power density of 50 µW/cm2. Notably, the synergistic activity of candle soot and LIG surpasses the performances of previously reported LIG-based supercapacitors. Furthermore, the cyclic stability of the device demonstrates excellent capacitance retention of 80% and Coulombic efficiency of 100% over 10000 cycles.

2.
ACS Sens ; 8(9): 3320-3337, 2023 09 22.
Artículo en Inglés | MEDLINE | ID: mdl-37602443

RESUMEN

Due to miscellaneous toxic gases in the vicinity, there is a burgeoning need for advancement in the existing gas sensing technology not only for the survival of mankind but also for the industries based in various fields such as beverage, forestry, health care, environmental monitoring, agriculture, and military security. A gas sensor must be highly selective toward a specific gas in order to avoid incorrect signals while responding to nontarget gases. This may lead to complex scenarios depicting sensor defects, such as low selectivity and cross-sensitivity. Therefore, a multiplex gas sensor is required to address the problems of cross selectivity by combining different gas sensors, signal processing, and pattern recognition techniques along with the currently employed gas sensing technologies. The different sensing materials used in these sensor arrays will produce a unique response signal for developing a set of identifiers as the input that can be used to recognize a specific gas by its "fingerprint". This review provides a comprehensive review of chemiresistive-based multiplex gas sensors, including various fabrication strategies from expensive to low-cost techniques, advances in sensing materials, and a gist of various pattern recognition techniques used for both rigid and flexible gas sensor applications. Finally, the review assesses the current state-of-the-art in multiplex gas sensor technology and discusses various challenges for future research in this direction.


Asunto(s)
Agricultura , Materiales Inteligentes , Bebidas , Monitoreo del Ambiente , Gases
3.
Anal Methods ; 15(24): 2955-2963, 2023 Jun 22.
Artículo en Inglés | MEDLINE | ID: mdl-37309562

RESUMEN

The current work reports the development of an inexpensive real-time sensing module for uric acid detection on a simple, disposable paper substrate. Detection is based on a capacitive measurement system using functional ZnO hexagonal rods on pulse-electrodeposited Cu interdigitated electrodes (IDEs) over hydrophobic A4 paper. Both the prepared hydrophobic A4 paper and ZnO hexagonal rods are well characterized using field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), UV-visible spectrophotometry (UV-Vis), Raman spectroscopy, and contact angle measurement. Arduino IDE software is used to configure the Arduino Mega board to evaluate the change in the capacitance value and to display the corresponding uric acid concentration on a liquid crystal display (LCD) screen. The experimental result shows the linear relationship in the range of 0.1 mM-1 mM concentration of uric acid with a high sensitivity of 9.00 µF mM-1 cm-2 at 0.1 mM. The results indicate that the developed capacitance measurement unit can be employed for the early screening of uric acid in real samples for clinical applications. The reported proof-of-concept has huge potential towards the development of a disposable and inexpensive biosensor platform.

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