1.
Org Lett
; 26(22): 4637-4642, 2024 Jun 07.
Artículo
en Inglés
| MEDLINE
| ID: mdl-38805214
RESUMEN
Here we report an efficient route for synthesizing strigolactones (SLs) and their derivatives. Our method relies on a palladium-catalyzed oxidative carbonylation/carbocyclization/carbonylation/alkoxylation cascade reaction, which involves the formation of three new C-C bonds and a new C-O bond while cleaving one C(sp3)-H bond in a single step. With our versatile synthetic strategy, both naturally occurring and artificial SLs were prepared.