Estimation of microplastic emission and transfer into Tokyo Bay, Japan, using material flow analysis.

To reduce microplastic (MP) discharge into the aquatic environment, it is necessary to properly identify its sources and amounts. Here, specific MP sources, i.e., personal care products (PCPs), fibers from clothes, and tire-wear particles (TWPs) were focused, and MP generations from these sources in the Tokyo Bay watershed, Japan, were estimated based on statistical data on production and reported emission factors of the MP sources and executing considering uncertainty on the data. Potential annual MP emission into Tokyo Bay was estimated to be 10.2 ± 1.6, 38 ± 22, and 1500-1800 tons for PCPs, fibers, and TWPs, respectively. Emissions into Tokyo Bay by assuming MP density and diameter was estimated. For fiber, the fraction to potential emission was estimated at 1.0-2.8 %. This study contributes to determining potential discharge pathways. This will assist in the application of appropriate measures to reduce MP discharge into water bodies.

Ammonia/ammonium removal/recovery from wastewaters using bioelectrochemical systems (BES): A review.

This review updates the current research efforts on using BES to recover NH3/NH4+, highlighting the novel configurations and introducing the working principles and the applications of microbial fuel cell (MFC), microbial electrolysis cell (MEC), microbial desalination cell (MDC), and microbial electrosynthesis cell (MESC) for NH3/NH4+ removal/recovery. However, commonly studied BES processes for NH3/NH4+ removal/recovery are energy intensive with external aeration needed for NH3 stripping being the largest energy input. In such a process bipolar membranes used for yielding a local alkaline pool recovering NH3 is not cost-effective. This gives a chance to microbial electrosynthesis which turned out to be a potential alternative option to approach circular bioeconomy. Furtherly, the reactor volume and NH3/NH4+ removal/recovery efficiency has a weakly positive correlation, indicating that there might be other factors controlling the reactor performance that are yet to be investigated.

Increased nitrogen deposition contributes to plant biodiversity loss in Japan: Insights from long-term historical monitoring data.

Atmospheric deposition of reactive nitrogen compounds (Nrs) has been recognized as a threat to plant diversity in terrestrial ecosystems. As a first attempt to investigate the relationship between Nrs deposition and plant diversity loss in Japan, we collected and analyzed the available long-term nationwide monitoring data on annual Nrs deposition and plant (tree) species, and evaluated the relationship between Nrs deposition and plant species loss at corresponding sites. Analyses of the available data showed that the amount of Nrs deposited annually tended to decrease at two monitoring sites (Yusuhara, Hedomisaki) and increase at six monitoring sites across Japan (Rishiri, Sadoseki, Tokyo, Aichi, Oki, and Ogasawara) during the late 1980s to 2011, especially at Aichi (11.8-21.6 kgN·ha-1·yr-1), Tokyo (10.0-23.5 kgN·ha-1·yr-1), Oki (6.63-14.1 kgN·ha-1·yr-1), and Rishiri (4.52-7.82 kgN·ha-1·yr-1). Another long-term study, the Monitoring Sites 1000 Project, investigated the growth of tree species at 20 core sites across Japan during 2004-2012. The sites with higher potential plant diversity loss were close to those sites where Nrs deposition had markedly increased over the 20 years, such as Tokyo, Aichi, and Oki. Analyses of long-term monitoring data for tree species in the Tokyo University Forest in Aichi revealed that 22 of the 273 tree species (8.05%) disappeared during the period of 1990-2010, and twelve out of the 22 lost species were shrub species less than 5 m tall. Although our study obviously has some limitations in quantitatively presenting the relationship between the loss of plant diversity and increased atmospheric Nrs deposition in Japan, our findings provide evidence for this relationship based on analyses of historical nationwide monitoring data. These findings will be useful for establishing N critical loads for Japanese forests.

Predicting the acute ecotoxicity of chemical substances by machine learning using graph theory.

Accurate in silico predictions of chemical substance ecotoxicity has become an important issue in recent years. Most conventional methods, such as the Ecological Structure-Activity Relationship (ECOSAR) model, cluster chemical substances empirically based on structural information and then predict toxicity by employing a log P linear regression model. Due to empirical classification, the prediction accuracy does not improve even if new ecotoxicity test data are added. In addition, most of the conventional methods are not appropriate for predicting the ecotoxicity on inorganic and/or ionized compounds. Furthermore, a user faces difficulty in handling multiple Quantitative Structure-Activity Relationship (QSAR) formulas with one chemical substance. To overcome the flaws of the conventional methods, in this study a new method was developed that applied unsupervised machine learning and graph theory to predict acute ecotoxicity. The proposed machine learning technique is based on the large AIST-MeRAM ecotoxicity test dataset, a software program developed by the National Institute of Advanced Industry Science and Technology for Multi-purpose Ecological Risk Assessment and Management, and the Molecular ACCess System (MACCS) keys that vectorize a chemical structure to 166-bit binary information. The acute toxicity of fish, daphnids, and algae can be predicted with good accuracy, without requiring log P and linear regression models in existing methods. Results from the new method were cross-validated and compared with ECOSAR predictions and show that the new method provides better accuracy for a wider range of chemical substances, including inorganic and ionized compounds.

Flows, stocks, and emissions of DEHP products in Japan.

The usage of products containing Bis (2­ethylhexyl) Phthalate (DEHP) is widespread, mainly through the great variety of PVC products. However, DEHP has become a worldwide concern, due to the potential health and environmental risks it presents. In this study, material flow analysis and emission estimations for DEHP products in Japan, from 1948 to 2030, were performed. Moreover, an evaluation of the potentially damaging impacts on human health and the environment was completed through a lifecycle impact assessment approach. The analysis focused on three representative lifecycle phases - Production, Use and Treatment and Disposal. The peak flows of DEHP from Production to the Use phase were in 1996 with 285,300 tons for shipment and the stocks peaked in 2001 with 1,981,908 tons. Accordingly, in 2006 the peak of DEHP waste to the Treatment and disposal phase was 190,792 tons. The primary emissions were observed in the Use phase, due to the large stocks, with DEHP mostly being released to the pedosphere. The total emissions from the Use phase reached the maximum of 48,960 tons in 2000, whereas in the Production and Treatment and disposal phase it was 248 tons and 15 tons, respectively. Subsequently, concerning the evaluation of impacts, the damage to the human health was the most widespread impact, totaling 13,782 disability-adjusted life years (DALYs), compared with the damage to the ecosystems, with 0.12 species·year. Furthermore, the risk-risk tradeoffs between the lifecycle phases were clarified throughout the years.

Application of fuzzy c-means clustering to PRTR chemicals uncovering their release and toxicity characteristics.

Increasing manufacture and usage of chemicals have not been matched by the increase in our understanding of their risks. Pollutant release and transfer register (PRTR) is becoming a popular measure for collecting chemical data and enhancing the public right to know. However, these data are usually in high dimensionality which restricts their wider use. The present study partitions Japanese PRTR chemicals into five fuzzy clusters by fuzzy c-mean clustering (FCM) to explore the implicit information. Each chemical with membership degrees belongs to each cluster. Cluster I features high releases from non-listed industries and the household sector and high environmental toxicity. Cluster II is characterized by high reported releases and transfers from 24 listed industries above the threshold, mutagenicity, and high environmental toxicity. Chemicals in cluster III have characteristics of high releases from non-listed industries and low toxicity. Cluster IV is characterized by high reported releases and transfers from 24 listed industries above the threshold and extremely high environmental toxicity. Cluster V is characterized by low releases yet mutagenicity and high carcinogenicity. Chemicals with the highest membership degree were identified as representatives for each cluster. For the highest membership degree, half of the chemicals have a value higher than 0.74. If we look at both the highest and the second highest membership degrees simultaneously, about 94% of the chemicals have a value higher than 0.5. FCM can serve as an approach to uncover the implicit information of highly complex chemical dataset, which subsequently supports the strategy development for efficient and effective chemical management.

Decabromodiphenyl Ether (DecaBDE) in Electrical and Electronic Equipment in Japan: Stock, Emission, and Substitution Evaluation.

DecaBDE has been widely used as flame retardant in electrical and electronic equipment (EEE). It has recently been listed in Annex A of the Stockholm Convention. The time series flow, stock, and emission of DecaBDE in EEE in Japan were quantified. On this basis, a risk/risk trade-off analysis of substituting DecaBDE with triphenyl phosphate (TPhP) that is one possible phosphorus-based alternative was conducted. The stock of DecaBDE reached a maximum of ∼42 000 t in 1995. Even though the demand flow was negligible in 2030, the stock was modeled to be still ∼470 t. The outflow of DecaBDE, from the use phase to the disposal phase, peaked at ∼4500 t/yr. in 2001. The DecaBDE emission to atmosphere was mainly derived from the production phase before 1990. The use phase became the largest contributor to the total emission from 1995 to 2000. Whereas the disposal phase dominated the total emission from 2000 onward. In the substitution analysis, a trade-off between human and ecological health effect was revealed in case of replacing DecaBDE with TPhP. This study attempted to give an overall picture of DecaBDE application at national level providing insights into relevant environmental policy making.

Flow, stock, and impact assessment of refrigerants in the Japanese household air conditioner sector.

Refrigerants provide society with great benefits while have the potential to cause adverse effects on the environment and human health. The present study estimated time-dependent flows and stocks and assessed the effects of refrigerants (R-22, R-410a, and R-32) in household air conditioners in Japan. It was found that stock of R-22 and R-410a peaked at 49,147t in 2000 and 55,994t in 2017, respectively. The largest flow of R-22 and R-410a to waste phase occurred at 3417t/yr. in 2005 and 4011t/yr. in 2023, respectively. The total global warming potential (GWP) due to refrigerant emissions increased from 3.6kt CO2 eq. in 1952 to 6999kt CO2 eq. in 2019, and then decreased to 5314kt CO2 eq. in 2030. The ozone depletion potential (ODP) peaked at 141t CFC-11 eq. in 2002. When substituting R-410a for R-22, the ODP decreased 50% while the GDP increased 8%. When substituting R-32 for R-410a, there was no effect on the ODP while the GDP decreased 6%. The human health damage due to the global warming effect of refrigerant emission was much higher than that due to the ozone depleting effect. The refrigerant emission in use and waste management phases dominated the human health damage. The dynamic estimation not only allows us to evaluate the performance of past policies but also supports the future sustainable management associated with the health effects of refrigerants.

Application of Life Cycle Assessment on Electronic Waste Management: A Review.

Electronic waste is a rich source of both valuable materials and toxic substances. Management of electronic waste is one of the biggest challenges of current worldwide concern. As an effective and prevailing environmental management tool, life cycle assessment can evaluate the environmental performance of electronic waste management activities. Quite a few scientific literatures reporting life cycle assessment of electronic waste management with significant outcomes have been recently published. This paper reviewed the trends, characteristics, research gaps, and challenges of these studies providing detailed information for practitioners involved in electronic waste management. The results showed that life cycle assessment studies were most carried out in Europe, followed by Asia and North America. The research subject of the studies mainly includes monitors, waste printed circuit boards, mobile phones, computers, printers, batteries, toys, dishwashers, and light-emitting diodes. CML was the most widely used life cycle impact assessment method in life cycle assessment studies on electronic waste management, followed by EI99. Furthermore, 40% of the reviewed studies combined with other environmental tools, including life cycle cost, material flow analysis, multi-criteria decision analysis, emergy analysis, and hazard assessment which came to more comprehensive conclusions from different aspects. The research gaps and challenges including uneven distribution of life cycle assessment studies, life cycle impact assessment methods selection, comparison of the results, and uncertainty of the life cycle assessment studies were examined. Although life cycle assessment of electronic waste management facing challenges, their results will play more and more important role in electronic waste management practices.

Waste management of printed wiring boards: a life cycle assessment of the metals recycling chain from liberation through refining.

Due to economic and societal reasons, informal activities including open burning, backyard recycling, and landfill are still the prevailing methods used for electronic waste treatment in developing countries. Great efforts have been made, especially in China, to promote formal approaches for electronic waste management by enacting laws, developing green recycling technologies, initiating pilot programs, etc. The formal recycling process can, however, engender environmental impact and resource consumption, although information on the environmental loads and resource consumption is currently limited. To quantitatively assess the environmental impact of the processes in a formal printed wiring board (PWB) recycling chain, life cycle assessment (LCA) was applied to a formal recycling chain that includes the steps from waste liberation through materials refining. The metal leaching in the refining stage was identified as a critical process, posing most of the environmental impact in the recycling chain. Global warming potential was the most significant environmental impact category after normalization and weighting, followed by fossil abiotic depletion potential, and marine aquatic eco-toxicity potential. Scenario modeling results showed that variations in the power source and chemical reagents consumption had the greatest influence on the environmental performance. The environmental impact from transportation used for PWB collection was also evaluated. The results were further compared to conventional primary metals production processes, highlighting the environmental benefit of metal recycling from waste PWBs. Optimizing the collection mode, increasing the precious metals recovery efficiency in the beneficiation stage and decreasing the chemical reagents consumption in the refining stage by effective materials liberation and separation are proposed as potential improvement strategies to make the recycling chain more environmentally friendly. The LCA results provide environmental information for the improvement of future integrated technologies and electronic waste management.

Computer simulation of the pneumatic separator in the pneumatic-electrostatic separation system for recycling waste printed circuit boards with electronic components.

Technologies could be integrated in different ways into automatic recycling lines for a certain kind of electronic waste according to practical requirements. In this study, a new kind of pneumatic separator with openings at the dust hooper was applied combing with electrostatic separation for recycling waste printed circuit boards. However, the flow pattern and the particles' movement behavior could not be obtained by experimental methods. To better control the separation quantity and the material size distribution, computational fluid dynamics was used to model the new pneumatic separator giving a detailed understanding of the mechanisms. Simulated results showed that the tangential velocity direction reversed with a relatively small value. Axial velocity exhibited two sharp decreases at the x axis. It is indicated that the bottom openings at the dust hopper resulted in an enormous change in the velocity profile. A new phenomenon that was named dusting was observed, which would mitigate the effect of particles with small diameter on the following electrostatic separation and avoid materials plugging caused by the waste printed circuit boards special properties effectively. The trapped materials were divided into seven grades. Experimental results showed that the mass fraction of grade 5, grade 6, and grade 7 materials were 27.54%, 15.23%, and 17.38%, respectively. Grade 1 particles' mass fraction was reduced by 80.30% compared with a traditional separator. Furthermore, the monocrystalline silicon content in silicon element in particles with a diameter of -0.091 mm was 18.9%, higher than that in the mixed materials. This study could serve as guidance for the future material flow control, automation control, waste recycling, and semiconductor storage medium destruction.

Disposal of waste computer hard disk drive: data destruction and resources recycling.

An increasing quantity of discarded computers is accompanied by a sharp increase in the number of hard disk drives to be eliminated. A waste hard disk drive is a special form of waste electrical and electronic equipment because it holds large amounts of information that is closely connected with its user. Therefore, the treatment of waste hard disk drives is an urgent issue in terms of data security, environmental protection and sustainable development. In the present study the degaussing method was adopted to destroy the residual data on the waste hard disk drives and the housing of the disks was used as an example to explore the coating removal process, which is the most important pretreatment for aluminium alloy recycling. The key operation points of the degaussing determined were: (1) keep the platter plate parallel with the magnetic field direction; and (2) the enlargement of magnetic field intensity B and action time t can lead to a significant upgrade in the degaussing effect. The coating removal experiment indicated that heating the waste hard disk drives housing at a temperature of 400 °C for 24 min was the optimum condition. A novel integrated technique for the treatment of waste hard disk drives is proposed herein. This technique offers the possibility of destroying residual data, recycling the recovered resources and disposing of the disks in an environmentally friendly manner.

Management strategies on the industrialization road of state-of-the-art technologies for e-waste recycling: the case study of electrostatic separation--a review.

Electronic waste (e-waste) management is pressing as global production has increased significantly in the past few years and is rising continuously at a fast rate. Many countries are facing hazardous e-waste mountains, most of which are disposed of by backyard recyclers, creating serious threats to public health and ecosystems. Industrialization of state-of-the-art recycling technologies is imperative to enhance the comprehensive utilization of resources and to protect the environment. This article aims to provide an overview of management strategies solving the crucial problems during the process of industrialization. A typical case study of electrostatic separation for recycling waste printed circuit boards was discussed in terms of parameters optimization, materials flow control, noise assessment, risk assessment, economic evaluation and social benefits analysis. The comprehensive view provided by the review could be helpful to the progress of the e-waste recycling industry.

Risks in the physical recovery system of waste refrigerator cabinets and the controlling measure.

Environmental information in physical recovery system of waste refrigerator cabinets was provided in this paper. The system included closed shearing, activated carbon adsorption (ACA), air current separation, magnetic separation, and eddy current separation. Exposures of CFC-11, heavy metals, and noise emitted from the system were assessed. Abundant CFC-11 (>510 mg/m³) was detected in crusher cavity. However, due to the employment of ACA, little CFC-11 (<9.5 mg/m³) could be detected out the recovery system. Heavy metals were detected in the air of workshop (TSP: Cu ≤ 4.91 µg/m³, Pb ≤ 3.17 µg/m³, PM10: Cu ≤ 2.1 µg/m³, Pb ≤ 1.3 µg/m³). Assessment results indicated the concentrations of heavy metals in air were safe for workers. Copper (25.8 mg/kg) and lead (19.5 mg/kg) were found in ground dust of the workshop and the concentrations were safe for soils. Noise level (98.2 dB(A)) of crushing process could cause disease and hearing impairment to workers. For controlling noise, acoustic hood was designed to reduce the noise level to 69.7 dB(A).The above information was of assistance to the industrialization of physical process for recovering waste refrigerator cabinets on environmental protection. Meanwhile, it contributed to the knowledge of environmental information of physical technology for recovering e-waste.

Electrostatic separation for recycling conductors, semiconductors, and nonconductors from electronic waste.

Electrostatic separation has been widely used to separate conductors and nonconductors for recycling e-waste. However, the components of e-waste are complex, which can be classified as conductors, semiconductors, and nonconductors according to their conducting properties. In this work, we made a novel attempt to recover the mixtures containing conductors (copper), semiconductors (extrinsic silicon), and nonconductors (woven glass reinforced resin) by electrostatic separation. The results of binary mixtures separation show that the separation of conductor and nonconductor, semiconductor and nonconductor need a higher voltage level while the separation of conductor and semiconductor needs a higher roll speed. Furthermore, the semiconductor separation efficiency is more sensitive to the high voltage level and the roll speed than the conductor separation efficiency. An integrated process was proposed for the multiple mixtures separation. The separation efficiency of conductors and semiconductors can reach 82.5% and 88%, respectively. This study contributes to the efficient recycling of valuable resources from e-waste.

Environmental friendly crush-magnetic separation technology for recycling metal-plated plastics from end-of-life vehicles.

Metal-plated plastics (MPP), which are important from the standpoint of aesthetics or even performance, are increasingly employed in a wide variety of situations in the automotive industry. Serious environmental problems will be caused if they are not treated appropriately. Therefore, recycling of MPP is an important subject not only for resource recycling but also for environmental protection. This work represents a novel attempt to deal with the MPP. A self-designed hammer crusher was used to liberate coatings from the plastic substrate. The size distribution of particles was analyzed and described by the Rosin-Rammler function model. The optimum retaining time of materials in the crusher is 3 min. By this time, the liberation rate of the materials can reach 87.3%. When the density of the suspension is 31,250 g/m(3), the performance of liberation is the best. Two-step magnetic separation was adopted to avoid excessive crushing and to guarantee the quality of products. Concerning both the separation efficiency and grade of products, the optimum rotational speed of the magnetic separator is 50-70 rpm. On the basis of the above studies about the liberating and separating behavior of the materials, a continuous recycling system (the technology of crush-magnetic separation) is developed. This recycling system provides a feasible method for recycling MPP efficiently, economically, and environmentally.

Assessment of noise and heavy metals (Cr, Cu, Cd, Pb) in the ambience of the production line for recycling waste printed circuit boards.

The crush-pneumatic separation-corona electrostatic separation production line provides a feasible method for industrialization of waste printed circuit boards (PCBs) recycling. To determine the potential environmental contamination in the automatic line workshop, noise and heavy metals (Cr, Cu, Cd, Pb) in the ambience of the production line have been evaluated in this paper. The mean noise level in the workshop has been reduced from 96.4 to 79.3 dB since the engineering noise control measures were employed. Noise whose frequency ranged from 500 to 1000 Hz is controlled effectively. The mass concentrations of TSP and PM(10) in the workshop are 282.6 and 202.0 µg/m(3), respectively. Pb (1.40 µg/m(3)) and Cu (1.22 µg/m(3)) are the most enriched metals in TSP samples followed by Cr (0.17 µg/m(3)) and Cd (0.028 µg/m(3)). The concentrations of Cu, Pb, Cr, and Cd in PM(10) are 0.88, 0.56, 0.12, and 0.88 µg/m(3), respectively. Among the four metals, Cr and Pb are released into the ambience of the automatic line more easily in the crush and separation process. Health risk assessment shows that noncancerous effects might be possible for Pb (HI = 1.45), and noncancerous effects are unlikely for Cr, Cu, and Cd. The carcinogenic risks for Cr and Cd are 3.29 × 10(-8) and 1.61 × 10(-9), respectively. It indicates that carcinogenic risks on workers are relatively light in the workshop. These findings suggest that this technology is advanced from the perspective of environmental protection in the waste PCBs recycling industry.