Electrochemical synthesis of multilayered PEDOT/PEDOT-SH/Au nanocomposites for electrochemical sensing of nitrite.

A multilayered film of poly(3,4-ethylenedioxythiophene)/poly(thiomethyl 3,4- ethylenedioxythiophene)/gold nanoparticle (PEDOT/PEDOT-SH/Au) nanocomposites was successfully synthesized on indium tin oxide (ITO) and glassy carbon electrode (GCE) via an electrochemical technique. The structure and morphology of the composite was characterized by FT-IR, UV-vis, EDS, XPS, and SEM analyses. The prepared multilayered PEDOT/PEDOT-SH/Au nanocomposite was used for the electrochemical catalytic oxidation of nitrite by amperometry. The results showed that the microstructures of PEDOT/PEDOT-SH/Au nanocomposites are not strongly dependent on the substrate. Fibrous PEDOT as hard template absorbed EDOT-SH on it to form porous PEDOT/PEDOT-SH. Porous structure had the advantages of large specific surface area and high porosity for nitrite ion adsorption. The thiol group in PEDOT/PEDOT-SH stabilized Au nanoparticles (NPs) effectively through Au-S bond and allowed Au NPs to have high dispersion and excellent electrocatalytic activity. The PEDOT/PEDOT-SH/Au composite prepared on GCE had a good performance in its electrochemical response to nitrite ions. PEDOT/PEDOT-SH/Au/GCE displayed a low oxidation potential (0.74 V), a fast response time (< 3 s), a low detection limit (0.051 µM), two linear ranges (0.15-1 mM and 1-16 mM), good sensitivity (0.301 µA µM-1 cm-2 and 0.133 µA µM-1 cm-2) with good reproducibility, stability, and selectivity. Graphical abstract Schematic representation of the preparation process of the nitrite ion electrochemical sensor.

Self-assembly of pendant functional groups grafted PEDOT as paracetamol detection material.

In this paper, pendant functional group grafted EDOTs, such as EDOTCH2NH2, EDOTCH2OH and EDOTCH2SH, were selected as monomers for the preparation of their respective polymers via a common chemical oxidative polymerization method in the absence of CTAB by varying the [monomer]/[oxidant] ratios. The self-assembly mechanism of the polymers was systematically studied by discussing the hydrogen bonding effect, acidity and electron-donating ability, as well as the chain initiation and chain growth of the chemically oxidated polymerized monomers. These functional group grafted PEDOTs were applied to the electrochemical determination of paracetamol (PAR) to further investigate the effect of the pendant functional groups (-SH, -OH, -NH2) on the electrochemical sensing behaviour of the polymers. The results indicated that the hydrogen bonding effect of the pendant functional groups was vital to the self-assembly of the polymer chains, and the PEDOTs with -OH and -SH groups had a tendency to self-assemble into a spherical structure, while the PEDOT with an -NH2 group exhibited a fibrous structure. The electrochemical response of PEDOTs with functional groups was better than that that of PEDOT alone, and the highest electrochemical response was observed in PEDOT with an -SH group ([monomer]/[oxidant] = 1 : 8).